The effect of π-π stacking interaction of the indole ring with the coordinated phenoxyl radical in a nickel()-salen type complex. Comparison with the corresponding Cu() complex

In order to gain new insights into the effect of the π-π stacking interaction of the indole ring with the phenoxyl radical moiety as seen in the active form of galactose oxidase, we have prepared Ni( ii ) complexes of a methoxy substituted salen-type ligand containing a pendent indole ring on the di...

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Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2019-08, Vol.48 (32), p.126-1269
Hauptverfasser:	Oshita, Hiromi, Suzuki, Takashi, Kawashima, Kyohei, Abe, Hitoshi, Tani, Fumito, Mori, Seiji, Yajima, Tatsuo, Shimazaki, Yuichi
Format:	Artikel
Sprache:	eng
Schlagworte:	Chelates Coordination Copper Crystal structure Crystallography Electronic structure Electrons Galactose Nickel Oxidation Stacking Structural analysis
Online-Zugang:	Volltext
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