Catalytic Conversion of Glucose into 5-Hydroxymethyl Furfural Over Cu–Cr/ZSM-5 Zeolite
Cu–Cr/ZSM-5 zeolite catalyst is successfully synthesized by loading Cu and Cr ions in the ZSM-5 zeolite particles using ion-exchange method. The as-obtained zeolite shows impressive efficiency when applied to the transformation reaction of glucose into 5-hydroxymethyl furfural (HMF). Technical condi...
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| Veröffentlicht in: | Catalysis letters 2020, Vol.150 (1), p.170-177 |
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| creator | Chung, Nguyen Hoang Oanh, Vo Thi Thoa, Luong Kim Hoang, Phan Huy |
| description | Cu–Cr/ZSM-5 zeolite catalyst is successfully synthesized by loading Cu and Cr ions in the ZSM-5 zeolite particles using ion-exchange method. The as-obtained zeolite shows impressive efficiency when applied to the transformation reaction of glucose into 5-hydroxymethyl furfural (HMF). Technical conditions that influence HMF yield including solvent, catalyst dosage, reaction temperature, and reaction time are investigated. According to the results, suitable conditions leading to the highest yield of HMF of 50.4% are established. The synthesized Cu–Cr/ZSM-5 catalyst shows promising performance and can be considered as a potential catalyst for direct conversion of glucose to HMF. Biomass materials other than glucose might be of interest for further investigations.
Graphic Abstract
Cu–Cr/ZSM-5 zeolite catalyst was prepared and applied for conversion of glucose to 5-hydroxymethyl furfural (HMF). |
| doi_str_mv | 10.1007/s10562-019-02922-4 |
| format | Article |
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Graphic Abstract
Cu–Cr/ZSM-5 zeolite catalyst was prepared and applied for conversion of glucose to 5-hydroxymethyl furfural (HMF).</description><identifier>ISSN: 1011-372X</identifier><identifier>EISSN: 1572-879X</identifier><identifier>DOI: 10.1007/s10562-019-02922-4</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Catalysis ; Catalysts ; Catalytic converters ; Chemical synthesis ; Chemistry ; Chemistry and Materials Science ; Chromium ; Copper ; Dextrose ; Direct conversion ; Glucose ; Hydroxymethylfurfural ; Industrial Chemistry/Chemical Engineering ; Ion exchange ; Organometallic Chemistry ; Physical Chemistry ; Reaction time ; Zeolites</subject><ispartof>Catalysis letters, 2020, Vol.150 (1), p.170-177</ispartof><rights>Springer Science+Business Media, LLC, part of Springer Nature 2019</rights><rights>COPYRIGHT 2020 Springer</rights><rights>Catalysis Letters is a copyright of Springer, (2019). All Rights Reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c457t-4fc12a7377303303a5fd1bb21089041660fa8ecaae8ddbc5732790bc9a2772143</citedby><cites>FETCH-LOGICAL-c457t-4fc12a7377303303a5fd1bb21089041660fa8ecaae8ddbc5732790bc9a2772143</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10562-019-02922-4$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10562-019-02922-4$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Chung, Nguyen Hoang</creatorcontrib><creatorcontrib>Oanh, Vo Thi</creatorcontrib><creatorcontrib>Thoa, Luong Kim</creatorcontrib><creatorcontrib>Hoang, Phan Huy</creatorcontrib><title>Catalytic Conversion of Glucose into 5-Hydroxymethyl Furfural Over Cu–Cr/ZSM-5 Zeolite</title><title>Catalysis letters</title><addtitle>Catal Lett</addtitle><description>Cu–Cr/ZSM-5 zeolite catalyst is successfully synthesized by loading Cu and Cr ions in the ZSM-5 zeolite particles using ion-exchange method. The as-obtained zeolite shows impressive efficiency when applied to the transformation reaction of glucose into 5-hydroxymethyl furfural (HMF). Technical conditions that influence HMF yield including solvent, catalyst dosage, reaction temperature, and reaction time are investigated. According to the results, suitable conditions leading to the highest yield of HMF of 50.4% are established. The synthesized Cu–Cr/ZSM-5 catalyst shows promising performance and can be considered as a potential catalyst for direct conversion of glucose to HMF. Biomass materials other than glucose might be of interest for further investigations.
Graphic Abstract
Cu–Cr/ZSM-5 zeolite catalyst was prepared and applied for conversion of glucose to 5-hydroxymethyl furfural (HMF).</description><subject>Catalysis</subject><subject>Catalysts</subject><subject>Catalytic converters</subject><subject>Chemical synthesis</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chromium</subject><subject>Copper</subject><subject>Dextrose</subject><subject>Direct conversion</subject><subject>Glucose</subject><subject>Hydroxymethylfurfural</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Ion exchange</subject><subject>Organometallic Chemistry</subject><subject>Physical Chemistry</subject><subject>Reaction time</subject><subject>Zeolites</subject><issn>1011-372X</issn><issn>1572-879X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNp9kctqGzEUhoeSQnPpC3Ql6KoLOUea0chamiE3SDHELZhshKyRXIXxyJU0xbPrO-QN8yRV4kIwhCCBhPi-czj6i-ILgQkB4OeRAKspBiIwUEEprj4Ux4RxiqdcLI_yHQjBJafLT8VJjA8AIDgRx8WyUUl1Y3IaNb7_Y0J0vkfeoqtu0D4a5PrkEcPXYxv8btyY9Gvs0OUQ7BBUh-bZQM3w9PexCef3i--YoXvjO5fMWfHRqi6az__P0-Ln5cWP5hrfzq9umtkt1hXjCVdWE6p4yXkJZd6K2ZasVpTAVEBF6hqsmhqtlJm27UozXlIuYKWFopxTUpWnxdd93W3wvwcTk3zwQ-hzS0lpnb-CVQxeqbXqjHS99SkovXFRy1mde_GqEnWmJm9QebVm47TvjXX5_UD4diBkJpldWqshRnmzuDtk6Z7VwccYjJXb4DYqjJKAfA5R7kOUOUT5EqJ8nq7cSzHD_dqE1-nesf4BKzGcow</recordid><startdate>2020</startdate><enddate>2020</enddate><creator>Chung, Nguyen Hoang</creator><creator>Oanh, Vo Thi</creator><creator>Thoa, Luong Kim</creator><creator>Hoang, Phan Huy</creator><general>Springer US</general><general>Springer</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>ISR</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope></search><sort><creationdate>2020</creationdate><title>Catalytic Conversion of Glucose into 5-Hydroxymethyl Furfural Over Cu–Cr/ZSM-5 Zeolite</title><author>Chung, Nguyen Hoang ; Oanh, Vo Thi ; Thoa, Luong Kim ; Hoang, Phan Huy</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c457t-4fc12a7377303303a5fd1bb21089041660fa8ecaae8ddbc5732790bc9a2772143</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Catalysis</topic><topic>Catalysts</topic><topic>Catalytic converters</topic><topic>Chemical synthesis</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Chromium</topic><topic>Copper</topic><topic>Dextrose</topic><topic>Direct conversion</topic><topic>Glucose</topic><topic>Hydroxymethylfurfural</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Ion exchange</topic><topic>Organometallic Chemistry</topic><topic>Physical Chemistry</topic><topic>Reaction time</topic><topic>Zeolites</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Chung, Nguyen Hoang</creatorcontrib><creatorcontrib>Oanh, Vo Thi</creatorcontrib><creatorcontrib>Thoa, Luong Kim</creatorcontrib><creatorcontrib>Hoang, Phan Huy</creatorcontrib><collection>CrossRef</collection><collection>Gale In Context: Science</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><jtitle>Catalysis letters</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Chung, Nguyen Hoang</au><au>Oanh, Vo Thi</au><au>Thoa, Luong Kim</au><au>Hoang, Phan Huy</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Catalytic Conversion of Glucose into 5-Hydroxymethyl Furfural Over Cu–Cr/ZSM-5 Zeolite</atitle><jtitle>Catalysis letters</jtitle><stitle>Catal Lett</stitle><date>2020</date><risdate>2020</risdate><volume>150</volume><issue>1</issue><spage>170</spage><epage>177</epage><pages>170-177</pages><issn>1011-372X</issn><eissn>1572-879X</eissn><abstract>Cu–Cr/ZSM-5 zeolite catalyst is successfully synthesized by loading Cu and Cr ions in the ZSM-5 zeolite particles using ion-exchange method. The as-obtained zeolite shows impressive efficiency when applied to the transformation reaction of glucose into 5-hydroxymethyl furfural (HMF). Technical conditions that influence HMF yield including solvent, catalyst dosage, reaction temperature, and reaction time are investigated. According to the results, suitable conditions leading to the highest yield of HMF of 50.4% are established. The synthesized Cu–Cr/ZSM-5 catalyst shows promising performance and can be considered as a potential catalyst for direct conversion of glucose to HMF. Biomass materials other than glucose might be of interest for further investigations.
Graphic Abstract
Cu–Cr/ZSM-5 zeolite catalyst was prepared and applied for conversion of glucose to 5-hydroxymethyl furfural (HMF).</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10562-019-02922-4</doi><tpages>8</tpages></addata></record> |
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| subjects | Catalysis Catalysts Catalytic converters Chemical synthesis Chemistry Chemistry and Materials Science Chromium Copper Dextrose Direct conversion Glucose Hydroxymethylfurfural Industrial Chemistry/Chemical Engineering Ion exchange Organometallic Chemistry Physical Chemistry Reaction time Zeolites |
| title | Catalytic Conversion of Glucose into 5-Hydroxymethyl Furfural Over Cu–Cr/ZSM-5 Zeolite |
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