Specific Features of Thermochemically Initiated Radical Copolymerization of Mixtures of Methacrylic Monomers in the Presence of Dissolved Polyvinyl Butyral
Thermochemically initiated radical copolymerization of a mixture of di(1-methacryloxy-3-chloropropoxy-2-)methylphosphonate (FOM-II) and 2-hydroxypropyl methacrylate in the bulk in the presence of 1–10 wt % dissolved polyvinyl butyral was studied. The process is characterized by two and more self-acc...
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| Veröffentlicht in: | Russian journal of applied chemistry 2019-06, Vol.92 (6), p.787-795 |
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| container_title | Russian journal of applied chemistry |
| container_volume | 92 |
| creator | Novakov, I. A. Vaniev, M. A. Borisov, S. V. Sidorenko, N. V. Kochnov, A. B. Bakhtina, G. D. |
| description | Thermochemically initiated radical copolymerization of a mixture of di(1-methacryloxy-3-chloropropoxy-2-)methylphosphonate (FOM-II) and 2-hydroxypropyl methacrylate in the bulk in the presence of 1–10 wt % dissolved polyvinyl butyral was studied. The process is characterized by two and more self-acceleration periods. This is associated with specific features of FOM-II polymerization transformations and with the presence of polyvinyl butyral macromolecules capable of association with methacrylic monomer molecules in the polymerizing system. |
| doi_str_mv | 10.1134/S1070427219060089 |
| format | Article |
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This is associated with specific features of FOM-II polymerization transformations and with the presence of polyvinyl butyral macromolecules capable of association with methacrylic monomer molecules in the polymerizing system.</description><identifier>ISSN: 1070-4272</identifier><identifier>EISSN: 1608-3296</identifier><identifier>DOI: 10.1134/S1070427219060089</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Acceleration ; Chemical industry ; Chemistry ; Chemistry and Materials Science ; Chemistry/Food Science ; Copolymerization ; Hydroxypropyl methacrylate ; Industrial Chemistry/Chemical Engineering ; Macromolecular Compounds and Polymeric Materials ; Macromolecules ; Monomers ; Polymerization ; Polyvinyl acetal resins ; Polyvinyl butyral</subject><ispartof>Russian journal of applied chemistry, 2019-06, Vol.92 (6), p.787-795</ispartof><rights>Pleiades Publishing, Ltd. 2019</rights><rights>Copyright Springer Nature B.V. 2019</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c353t-38b4c3d2a845b8fe5083a7aeb07795dfc6fb02cbc291f5e8104f4bd02d4295e33</citedby><cites>FETCH-LOGICAL-c353t-38b4c3d2a845b8fe5083a7aeb07795dfc6fb02cbc291f5e8104f4bd02d4295e33</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S1070427219060089$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S1070427219060089$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Novakov, I. 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This is associated with specific features of FOM-II polymerization transformations and with the presence of polyvinyl butyral macromolecules capable of association with methacrylic monomer molecules in the polymerizing system.</description><subject>Acceleration</subject><subject>Chemical industry</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chemistry/Food Science</subject><subject>Copolymerization</subject><subject>Hydroxypropyl methacrylate</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Macromolecular Compounds and Polymeric Materials</subject><subject>Macromolecules</subject><subject>Monomers</subject><subject>Polymerization</subject><subject>Polyvinyl acetal resins</subject><subject>Polyvinyl butyral</subject><issn>1070-4272</issn><issn>1608-3296</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNp1kclOxDAMhisEEusDcIvEueAs3Y4wMIDECMRyrtLUYYI6zZBkEOVVeFlSDYID4mTL_v7PByfJIYVjSrk4eaBQgGAFoxXkAGW1kezQHMqUsyrfjH1cp-N-O9n1_gUAqjwvd5LPhyUqo40iU5Rh5dATq8njHN3CqjkujJJdN5Dr3gQjA7bkXrbjjEzs0nbDAp35kMHYfozNzPuPYoZhLpUbuqie2d5G0hPTkzBHchcZ7BWO3Lnx3nZv0XwXfW-mHzpytgqDk91-sqVl5_Hgu-4lT9OLx8lVenN7eT05vUkVz3hIedkIxVsmS5E1pcYMSi4LiQ0URZW1WuW6AaYaxSqqMywpCC2aFlgrWJUh53vJ0dq7dPZ1hT7UL3bl-niyZiyvQAAtRKTomlLOeu9Q10tnFtINNYV6_EH95wcxw9YZH9n-Gd2v-f_QF1CKjBA</recordid><startdate>20190601</startdate><enddate>20190601</enddate><creator>Novakov, I. 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| subjects | Acceleration Chemical industry Chemistry Chemistry and Materials Science Chemistry/Food Science Copolymerization Hydroxypropyl methacrylate Industrial Chemistry/Chemical Engineering Macromolecular Compounds and Polymeric Materials Macromolecules Monomers Polymerization Polyvinyl acetal resins Polyvinyl butyral |
| title | Specific Features of Thermochemically Initiated Radical Copolymerization of Mixtures of Methacrylic Monomers in the Presence of Dissolved Polyvinyl Butyral |
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