Rhodium‐Catalyzed Asymmetric [2+2+2] Cycloaddition Reactions of 1,6‐Enynes and Oxabenzonorbornadienes

The asymmetric [2+2+2] cycloaddition reactions of 1,6‐enynes and oxabenzonorbornadienes was accomplished by using the complex of [Rh(COD)2]BF4 and (R)‐Xyl‐P‐Phos as chiral catalyst. A range of 1,6‐enynes and oxabenzonorbornadienes were well tolerated in the cycloaddition reaction, which afforded var...

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Veröffentlicht in:	Advanced synthesis & catalysis 2019-08, Vol.361 (15), p.3543-3547
Hauptverfasser:	Ni, Jianxiao, Chen, Jingchao, Zhou, Yongyun, Wang, Gaowei, Li, Sida, He, Zhenxiu, Sun, Weiqing, Fan, Baomin
Format:	Artikel
Sprache:	eng
Schlagworte:	(R)-Xyl-P-Phos 1,6-enynes [Rh(COD)2]BF4 Asymmetry Chemical reactions Cycloaddition oxabenzonorbornadiene Rhodium
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