BaTh2Fe4As4(N0.7O0.3)2: An iron-based superconductor stabilized by inter-block-layer charge transfer

摘要本文基于结构设计、 采用高温固相反应, 首次合成了电子掺杂“12442”型超导体BaTh2Fe4As4(N0.7O0.3)2. 研究发现, “BaFe2As2”和 “ThFeAsN0.7O0.3”块层间的电荷转移是稳定该目标化合物的必要条件. 霍尔测量证实该化合物主要为电子型导电. 电阻、 直流磁化率和比热测量的综合结果表明, 样品在22 K 呈现体超导电性....

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Veröffentlicht in:Science China materials 2019-09, Vol.62 (9), p.1357-1362
Hauptverfasser: Shao, Ye-Ting, Wang, Zhi-Cheng, Li, Bai-Zhuo, Wu, Si-Qi, Wu, Ji-Feng, Ren, Zhi, Qiu, Su-Wen, Rao, Can, Wang, Cao, Cao, Guang-Han
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container_end_page 1362
container_issue 9
container_start_page 1357
container_title Science China materials
container_volume 62
creator Shao, Ye-Ting
Wang, Zhi-Cheng
Li, Bai-Zhuo
Wu, Si-Qi
Wu, Ji-Feng
Ren, Zhi
Qiu, Su-Wen
Rao, Can
Wang, Cao
Cao, Guang-Han
description 摘要本文基于结构设计、 采用高温固相反应, 首次合成了电子掺杂“12442”型超导体BaTh2Fe4As4(N0.7O0.3)2. 研究发现, “BaFe2As2”和 “ThFeAsN0.7O0.3”块层间的电荷转移是稳定该目标化合物的必要条件. 霍尔测量证实该化合物主要为电子型导电. 电阻、 直流磁化率和比热测量的综合结果表明, 样品在22 K 呈现体超导电性.
doi_str_mv 10.1007/s40843-019-9438-7
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subjects Charge transfer
Chemistry and Materials Science
Chemistry/Food Science
Letters
Materials Science
title BaTh2Fe4As4(N0.7O0.3)2: An iron-based superconductor stabilized by inter-block-layer charge transfer
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