Unravelling the Mechanism and Selectivity of the NHC‐catalyzed Three‐Membered Ring‐Opening/Fluorination of Epoxy Enals: A DFT Study

Regio‐ and stereo‐divergent construction of carbon‐fluorine bond remains a challenge in fluorine chemistry, especially reactions involving fluorination at the α‐position of a carbonyl group. Herein, we present a detailed study for predicting the origins of regio‐ and stereo‐selectivity for organocat...

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Veröffentlicht in:	ChemCatChem 2019-06, Vol.11 (12), p.2919-2925
Hauptverfasser:	Wang, Yang, Qu, Ling‐Bo, Lan, Yu, Wei, Donghui
Format:	Artikel
Sprache:	eng
Schlagworte:	Carbon Carbonyl groups Carbonyls Density functional theory DFT Fluorination Fluorine Organic chemistry Origins Reaction Mechanism Regioselectivity Ring-Opening Selectivity Stereoselectivity
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