Catalyst‐Controlled Chemodivergent Annulation to Indolo/Pyrrolo‐Fused Diazepine and Quinoxaline

Catalyst‐controlled chemodivergent annulation between o‐indolo anilines and diazo compounds has explored for the synthesis of indolo‐fused diazepine and quinoxaline. Under the Rh(III) catalyst, reaction proceeded through the free amine assisted C2−H activation followed by amidation leading to the di...

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Veröffentlicht in:	Advanced synthesis & catalysis 2019-06, Vol.361 (12), p.2916-2925
Hauptverfasser:	Dhole, Sandip, Chiu, Wei‐Jung, Sun, Chung‐Ming
Format:	Artikel
Sprache:	eng
Schlagworte:	Catalysis Catalyst-controlled Catalysts Chemical reactions Chemodivergent Annulation Indolo/Pyrrolo-Fused Diazepine and Quinoxaline Metallography Modular construction Organic chemistry Quinoxalines Ruthenium
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