Terminal Diazirines Enable Reverse Polarization Transfer from 15N2 Singlets

Diazirine moieties are chemically stable and have been incorporated into biomolecules without impediment of biological activity. The 15N2 labeled diazirines are appealing motifs for hyperpolarization supporting relaxation protected states with long‐lived lifetimes. The (‐CH15N2) diazirine groups inv...

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Veröffentlicht in:	Angewandte Chemie International Edition 2019-08, Vol.58 (32), p.11118-11124
Hauptverfasser:	Zhang, Guannan, Colell, Johannes F. P., Glachet, Thomas, Lindale, Jacob R., Reboul, Vincent, Theis, Thomas, Warren, Warren S.
Format:	Artikel
Sprache:	eng
Schlagworte:	Biological activity Biomolecules Hyperpolarization imaging agents NMR spectroscopy Organic chemistry Polarization polarization transfer Relaxation time singlet states
Online-Zugang:	Volltext
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