Synthesis of Bio Jet Fuel from Crude Palm Oil by HEFA (Hydroprocessed Esters and Fatty Acids) Using Ni-Mo Catalyst Supported by Rice Husk Ash-Based SiO2
Bio jet fuel becomes one of the feasible solutions for jet fuel inadequate supply in Indonesia. However, study in this field by far has been limited. In this study, bio jet fuel was synthesized from Crude Palm Oil (CPO) by Hydroprocessed Esters and Fatty Acid (HEFA) facilitated by Ni-Mo/SiO2 catalys...
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| Veröffentlicht in: | Materials science forum 2019-07, Vol.964, p.193-198 |
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| creator | Mumtazy, Muhammad Ridlo Zanata, Mabrur Tri Wulan Amelia, Sekar Kurniawansyah, Firman Roesyadi, Achmad |
| description | Bio jet fuel becomes one of the feasible solutions for jet fuel inadequate supply in Indonesia. However, study in this field by far has been limited. In this study, bio jet fuel was synthesized from Crude Palm Oil (CPO) by Hydroprocessed Esters and Fatty Acid (HEFA) facilitated by Ni-Mo/SiO2 catalyst, in which the support was derived from rice husk ash. The study focused on investigating the influence of catalyst-CPO mass ratio and temperature of the catalytic process. Experimental works consisted of silica-based catalyst preparation via impregnation method, followed by sample assessments. Catalytic reactions were conducted at 20-50 bars, with temperature of reaction 300°C and 400°C. Catalyst performance were evaluated from crystallinity, composition, and activity in the reaction. Catalyst characterization shows an amorphous structured with high dispersion of Ni-Mo in rice husk ash have been produced. The HEFA process successfully obtained bio jet fuel (C10-C15 hydrocarbons) with yield and selectivity of 45.17% and 45.46%, respectively. Overall, a systematic approach shows rice husk ash has potential to be developed as a catalyst support for bio jet fuel production from crude palm oil. |
| doi_str_mv | 10.4028/www.scientific.net/MSF.964.193 |
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However, study in this field by far has been limited. In this study, bio jet fuel was synthesized from Crude Palm Oil (CPO) by Hydroprocessed Esters and Fatty Acid (HEFA) facilitated by Ni-Mo/SiO2 catalyst, in which the support was derived from rice husk ash. The study focused on investigating the influence of catalyst-CPO mass ratio and temperature of the catalytic process. Experimental works consisted of silica-based catalyst preparation via impregnation method, followed by sample assessments. Catalytic reactions were conducted at 20-50 bars, with temperature of reaction 300°C and 400°C. Catalyst performance were evaluated from crystallinity, composition, and activity in the reaction. Catalyst characterization shows an amorphous structured with high dispersion of Ni-Mo in rice husk ash have been produced. The HEFA process successfully obtained bio jet fuel (C10-C15 hydrocarbons) with yield and selectivity of 45.17% and 45.46%, respectively. Overall, a systematic approach shows rice husk ash has potential to be developed as a catalyst support for bio jet fuel production from crude palm oil.</description><identifier>ISSN: 0255-5476</identifier><identifier>ISSN: 1662-9752</identifier><identifier>EISSN: 1662-9752</identifier><identifier>DOI: 10.4028/www.scientific.net/MSF.964.193</identifier><language>eng</language><publisher>Pfaffikon: Trans Tech Publications Ltd</publisher><subject>Ashes ; Catalysis ; Catalysts ; Crude oil ; Esters ; Fatty acids ; Feasibility studies ; Fuel production ; Jet engine fuels ; Molybdenum ; Nickel ; Palm oil ; Selectivity ; Silicon dioxide ; Vegetable oils</subject><ispartof>Materials science forum, 2019-07, Vol.964, p.193-198</ispartof><rights>2019 Trans Tech Publications Ltd</rights><rights>Copyright Trans Tech Publications Ltd. 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However, study in this field by far has been limited. In this study, bio jet fuel was synthesized from Crude Palm Oil (CPO) by Hydroprocessed Esters and Fatty Acid (HEFA) facilitated by Ni-Mo/SiO2 catalyst, in which the support was derived from rice husk ash. The study focused on investigating the influence of catalyst-CPO mass ratio and temperature of the catalytic process. Experimental works consisted of silica-based catalyst preparation via impregnation method, followed by sample assessments. Catalytic reactions were conducted at 20-50 bars, with temperature of reaction 300°C and 400°C. Catalyst performance were evaluated from crystallinity, composition, and activity in the reaction. Catalyst characterization shows an amorphous structured with high dispersion of Ni-Mo in rice husk ash have been produced. The HEFA process successfully obtained bio jet fuel (C10-C15 hydrocarbons) with yield and selectivity of 45.17% and 45.46%, respectively. Overall, a systematic approach shows rice husk ash has potential to be developed as a catalyst support for bio jet fuel production from crude palm oil.</description><subject>Ashes</subject><subject>Catalysis</subject><subject>Catalysts</subject><subject>Crude oil</subject><subject>Esters</subject><subject>Fatty acids</subject><subject>Feasibility studies</subject><subject>Fuel production</subject><subject>Jet engine fuels</subject><subject>Molybdenum</subject><subject>Nickel</subject><subject>Palm oil</subject><subject>Selectivity</subject><subject>Silicon dioxide</subject><subject>Vegetable oils</subject><issn>0255-5476</issn><issn>1662-9752</issn><issn>1662-9752</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><sourceid>GNUQQ</sourceid><recordid>eNqNkcGO0zAQhiMEEmXhHUZCQnBI1nacpL4gulVDF-1SRNmz5Tpj6iWNu7ajKm_C4-JVV9orp7n88_2a-bLsAyUFJ2x-eTqdiqAtDtEaq4sB4-Xtti1EzQsqyhfZjNY1y0VTsZfZjLCqyive1K-zNyHcE1LSOa1n2d_tNMQ9BhvAGbiyDr5hhHbEHox3B1j6sUP4ofoDbGwPuwnWq3YBH9dT593RO40hYAerENEHUEMHrYpxgoW2XfgEd8EOv-G7zW8dLFVU_RQibMfj0fmY1hLup9UI6zH8gUXY51fqkba1G_Y2e2VUH_Dd07zI7trVr-U6v9l8vV4ubnLNGlrmjSnFfNdwnHeCCdRCmZ3oGm2oblCQ2hjkgpuG0V2ZFogqleg017WuOFYEy4vs_ZmbjnkYMUR570Y_pErJWM05Y4ywlPp8TmnvQvBo5NHbg_KTpEQ-2pDJhny2IZMNmWzIZEMmGwnw5QyIXg3pWXr_3POfiH_4_Zub</recordid><startdate>20190701</startdate><enddate>20190701</enddate><creator>Mumtazy, Muhammad Ridlo</creator><creator>Zanata, Mabrur</creator><creator>Tri Wulan Amelia, Sekar</creator><creator>Kurniawansyah, Firman</creator><creator>Roesyadi, Achmad</creator><general>Trans Tech Publications Ltd</general><scope>AAYXX</scope><scope>CITATION</scope><scope>3V.</scope><scope>7SR</scope><scope>7XB</scope><scope>88I</scope><scope>8BQ</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>8FK</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>GNUQQ</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>M2P</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>Q9U</scope></search><sort><creationdate>20190701</creationdate><title>Synthesis of Bio Jet Fuel from Crude Palm Oil by HEFA (Hydroprocessed Esters and Fatty Acids) Using Ni-Mo Catalyst Supported by Rice Husk Ash-Based SiO2</title><author>Mumtazy, Muhammad Ridlo ; Zanata, Mabrur ; Tri Wulan Amelia, Sekar ; Kurniawansyah, Firman ; Roesyadi, Achmad</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c2713-7f398b74e8d929ec9afb9d7cf1c7e906ffe494f721b32710a3a9dc4c6c54e50e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Ashes</topic><topic>Catalysis</topic><topic>Catalysts</topic><topic>Crude oil</topic><topic>Esters</topic><topic>Fatty acids</topic><topic>Feasibility studies</topic><topic>Fuel production</topic><topic>Jet engine fuels</topic><topic>Molybdenum</topic><topic>Nickel</topic><topic>Palm oil</topic><topic>Selectivity</topic><topic>Silicon dioxide</topic><topic>Vegetable oils</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Mumtazy, Muhammad Ridlo</creatorcontrib><creatorcontrib>Zanata, Mabrur</creatorcontrib><creatorcontrib>Tri Wulan Amelia, Sekar</creatorcontrib><creatorcontrib>Kurniawansyah, Firman</creatorcontrib><creatorcontrib>Roesyadi, Achmad</creatorcontrib><collection>CrossRef</collection><collection>ProQuest Central (Corporate)</collection><collection>Engineered Materials Abstracts</collection><collection>ProQuest Central (purchase pre-March 2016)</collection><collection>Science Database (Alumni Edition)</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>ProQuest Central (Alumni) (purchase pre-March 2016)</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>ProQuest Central Student</collection><collection>SciTech Premium Collection</collection><collection>Materials Research Database</collection><collection>Materials Science Database</collection><collection>Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>ProQuest Central Basic</collection><jtitle>Materials science forum</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Mumtazy, Muhammad Ridlo</au><au>Zanata, Mabrur</au><au>Tri Wulan Amelia, Sekar</au><au>Kurniawansyah, Firman</au><au>Roesyadi, Achmad</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis of Bio Jet Fuel from Crude Palm Oil by HEFA (Hydroprocessed Esters and Fatty Acids) Using Ni-Mo Catalyst Supported by Rice Husk Ash-Based SiO2</atitle><jtitle>Materials science forum</jtitle><date>2019-07-01</date><risdate>2019</risdate><volume>964</volume><spage>193</spage><epage>198</epage><pages>193-198</pages><issn>0255-5476</issn><issn>1662-9752</issn><eissn>1662-9752</eissn><abstract>Bio jet fuel becomes one of the feasible solutions for jet fuel inadequate supply in Indonesia. However, study in this field by far has been limited. In this study, bio jet fuel was synthesized from Crude Palm Oil (CPO) by Hydroprocessed Esters and Fatty Acid (HEFA) facilitated by Ni-Mo/SiO2 catalyst, in which the support was derived from rice husk ash. The study focused on investigating the influence of catalyst-CPO mass ratio and temperature of the catalytic process. Experimental works consisted of silica-based catalyst preparation via impregnation method, followed by sample assessments. Catalytic reactions were conducted at 20-50 bars, with temperature of reaction 300°C and 400°C. Catalyst performance were evaluated from crystallinity, composition, and activity in the reaction. Catalyst characterization shows an amorphous structured with high dispersion of Ni-Mo in rice husk ash have been produced. The HEFA process successfully obtained bio jet fuel (C10-C15 hydrocarbons) with yield and selectivity of 45.17% and 45.46%, respectively. Overall, a systematic approach shows rice husk ash has potential to be developed as a catalyst support for bio jet fuel production from crude palm oil.</abstract><cop>Pfaffikon</cop><pub>Trans Tech Publications Ltd</pub><doi>10.4028/www.scientific.net/MSF.964.193</doi><tpages>6</tpages></addata></record> |
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| subjects | Ashes Catalysis Catalysts Crude oil Esters Fatty acids Feasibility studies Fuel production Jet engine fuels Molybdenum Nickel Palm oil Selectivity Silicon dioxide Vegetable oils |
| title | Synthesis of Bio Jet Fuel from Crude Palm Oil by HEFA (Hydroprocessed Esters and Fatty Acids) Using Ni-Mo Catalyst Supported by Rice Husk Ash-Based SiO2 |
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