Charge-discharge behavior of Li-O2 cell with viologen as redox catalyst: influence of cationic charge
The high theoretical energy density of lithium-air batteries has attracted the attention of many researchers as this system is expected to fulfill the demands radically from all sectors. Unfortunately, the issues such as deposition of undesirable discharge in the cathode, formation of lithium dendri...
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| Veröffentlicht in: | Ionics 2019-08, Vol.25 (8), p.3837-3845 |
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| creator | Natarajan, Angulakshmi Murugavel, Kathiresan Madasamy, Kanagaraj Suriyakumar, Shruti Illayaraja, N. Anupriya, N. Christy, Maria Nahm, K. S. Zhou, Yingke Stephan, A. Manuel |
| description | The high theoretical energy density of lithium-air batteries has attracted the attention of many researchers as this system is expected to fulfill the demands radically from all sectors. Unfortunately, the issues such as deposition of undesirable discharge in the cathode, formation of lithium dendrites, and decomposition of electrolytes hamper it from commercialization. In the present work, viologens carrying different positive charges were synthesized and used as a catalyst in the carbon-assisted air cathode for the first time, and its cycling performance was analyzed. The lithium air cell with monomeric viologen offered highest discharge capacity and the deposition of Li
2
O
2
in the cycled cathode was confirmed by XRD and FT-IR analyses. |
| doi_str_mv | 10.1007/s11581-019-02955-0 |
| format | Article |
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2
O
2
in the cycled cathode was confirmed by XRD and FT-IR analyses.</description><identifier>ISSN: 0947-7047</identifier><identifier>EISSN: 1862-0760</identifier><identifier>DOI: 10.1007/s11581-019-02955-0</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Batteries ; Catalysis ; Catalysts ; Cathodes ; Chemical synthesis ; Chemistry ; Chemistry and Materials Science ; Commercialization ; Condensed Matter Physics ; Deposition ; Discharge ; Electrochemistry ; Electrolytes ; Energy Storage ; Flux density ; Lithium ; Metal air batteries ; Optical and Electronic Materials ; Original Paper ; Renewable and Green Energy</subject><ispartof>Ionics, 2019-08, Vol.25 (8), p.3837-3845</ispartof><rights>Springer-Verlag GmbH Germany, part of Springer Nature 2019</rights><rights>Copyright Springer Nature B.V. 2019</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c2340-3678d7dabb1c9f29349c42c30af86698e4f7e04bec28f8d80625ab91e1eb7e953</citedby><cites>FETCH-LOGICAL-c2340-3678d7dabb1c9f29349c42c30af86698e4f7e04bec28f8d80625ab91e1eb7e953</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11581-019-02955-0$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s11581-019-02955-0$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Natarajan, Angulakshmi</creatorcontrib><creatorcontrib>Murugavel, Kathiresan</creatorcontrib><creatorcontrib>Madasamy, Kanagaraj</creatorcontrib><creatorcontrib>Suriyakumar, Shruti</creatorcontrib><creatorcontrib>Illayaraja, N.</creatorcontrib><creatorcontrib>Anupriya, N.</creatorcontrib><creatorcontrib>Christy, Maria</creatorcontrib><creatorcontrib>Nahm, K. S.</creatorcontrib><creatorcontrib>Zhou, Yingke</creatorcontrib><creatorcontrib>Stephan, A. Manuel</creatorcontrib><title>Charge-discharge behavior of Li-O2 cell with viologen as redox catalyst: influence of cationic charge</title><title>Ionics</title><addtitle>Ionics</addtitle><description>The high theoretical energy density of lithium-air batteries has attracted the attention of many researchers as this system is expected to fulfill the demands radically from all sectors. Unfortunately, the issues such as deposition of undesirable discharge in the cathode, formation of lithium dendrites, and decomposition of electrolytes hamper it from commercialization. In the present work, viologens carrying different positive charges were synthesized and used as a catalyst in the carbon-assisted air cathode for the first time, and its cycling performance was analyzed. The lithium air cell with monomeric viologen offered highest discharge capacity and the deposition of Li
2
O
2
in the cycled cathode was confirmed by XRD and FT-IR analyses.</description><subject>Batteries</subject><subject>Catalysis</subject><subject>Catalysts</subject><subject>Cathodes</subject><subject>Chemical synthesis</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Commercialization</subject><subject>Condensed Matter Physics</subject><subject>Deposition</subject><subject>Discharge</subject><subject>Electrochemistry</subject><subject>Electrolytes</subject><subject>Energy Storage</subject><subject>Flux density</subject><subject>Lithium</subject><subject>Metal air batteries</subject><subject>Optical and Electronic Materials</subject><subject>Original Paper</subject><subject>Renewable and Green Energy</subject><issn>0947-7047</issn><issn>1862-0760</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNp9kE1LAzEQhoMoWKt_wFPAc3SSzSYbb1L8gkIveg7Z7KRNWXdr0vrx7912BW-eZhje5x14CLnkcM0B9E3mvKw4A24YCFOWDI7IhFdKMNAKjskEjNRMg9Sn5CznNYBSXOgJwdnKpSWyJmZ_2GiNK_cR-0T7QOeRLQT12Lb0M25XdLi3_RI76jJN2PRf1Luta7_z9pbGLrQ77DzuweEc-y56Opaek5Pg2owXv3NKXh_uX2ZPbL54fJ7dzZkXhQRWKF01unF1zb0JwhTSeCl8AS5USpkKZdAIskYvqlA1FShRutpw5FhrNGUxJVdj7yb17zvMW7vud6kbXlohlODcCCmHlBhTPvU5Jwx2k-KbS9-Wg93rtKNOO-i0B50WBqgYoTyEuyWmv-p_qB9tanfu</recordid><startdate>20190801</startdate><enddate>20190801</enddate><creator>Natarajan, Angulakshmi</creator><creator>Murugavel, Kathiresan</creator><creator>Madasamy, Kanagaraj</creator><creator>Suriyakumar, Shruti</creator><creator>Illayaraja, N.</creator><creator>Anupriya, N.</creator><creator>Christy, Maria</creator><creator>Nahm, K. 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In the present work, viologens carrying different positive charges were synthesized and used as a catalyst in the carbon-assisted air cathode for the first time, and its cycling performance was analyzed. The lithium air cell with monomeric viologen offered highest discharge capacity and the deposition of Li
2
O
2
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| language | eng |
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| subjects | Batteries Catalysis Catalysts Cathodes Chemical synthesis Chemistry Chemistry and Materials Science Commercialization Condensed Matter Physics Deposition Discharge Electrochemistry Electrolytes Energy Storage Flux density Lithium Metal air batteries Optical and Electronic Materials Original Paper Renewable and Green Energy |
| title | Charge-discharge behavior of Li-O2 cell with viologen as redox catalyst: influence of cationic charge |
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