Experimental petrology of peridotites, including effects of water and carbon on melting in the Earth’s upper mantle
For over 50 years, the use of high-pressure piston/cylinder apparatus combined with an increasing diversity of microbeam analytical techniques has enabled the study of mantle peridotite compositions and of magmas derived by melting in the upper mantle. The experimental studies have been guided by th...
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description | For over 50 years, the use of high-pressure piston/cylinder apparatus combined with an increasing diversity of microbeam analytical techniques has enabled the study of mantle peridotite compositions and of magmas derived by melting in the upper mantle. The experimental studies have been guided by the petrology and geochemistry of peridotites from diverse settings and by the remarkable range of mantle-derived magma types. Recent experimental study using FTIR spectroscopy to monitor water content of minerals has shown that fertile lherzolite (MORB-source upper mantle) at ~1,000 °C can store ~200 ppm H
2
O in defect sites in nominally anhydrous minerals (olivine, pyroxenes, garnet and spinel). Water in excess of 200 ppm stabilizes amphibole (pargasite) at
P
3 GPa, water in excess of 200 ppm appears as an aqueous vapour phase and this depresses the temperature of the upper mantle solidus. Provided the uppermost mantle (lithosphere) has H
2
O 500 ppm H
2
O) overlying the ‘depleted’ MORB source (~200 ppm H
2
O). From the study of primitive MOR picrites, the modern mantle potential temperature for MORB petrogenesis is ~1,430 °C. The intersection of the 1,430 °C adiabat with the vapour-saturated lherzolite solidus at ~230 km suggests that upwelling beneath mid-ocean ridges begins around this depth. In
intraplate
volcanism, diapiric upwelling begins from shallower depths and lower temperatures within the asthenosphere and the upwelling lherzolite is enriched in water, carbonate and incompatible elements. Magmas including olivine melilitites, olivine nephelinites, basanites, alkali picrites and tholeiitic picrites are consequences of increasing melt fraction and decreasing pressure at melt segregation. Major element, trace element and isotopic characteristics of island chain or ‘hot-spot’ magmas show that they sample geochemically distinct co |
doi_str_mv | 10.1007/s00269-014-0729-2 |
format | Article |
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2
O in defect sites in nominally anhydrous minerals (olivine, pyroxenes, garnet and spinel). Water in excess of 200 ppm stabilizes amphibole (pargasite) at
P
< 3 GPa up to the lherzolite solidus. However, at
P
> 3 GPa, water in excess of 200 ppm appears as an aqueous vapour phase and this depresses the temperature of the upper mantle solidus. Provided the uppermost mantle (lithosphere) has H
2
O < 4,000 ppm, the mantle solidus has a distinctive
P
,
T
shape. The temperature of the
vapour
-
undersaturated
or
dehydration solidus
is approximately constant at 1,100 °C at pressures up to ~3 GPa and then decreases sharply to ~1,010 °C. The strongly negative d
T
/d
P
of the vapour-undersaturated solidus of fertile lherzolite from 2.8 to 3 GPa provides the basis for understanding the lithosphere/asthenosphere boundary. Through upward migration of near-solidus hydrous silicate melt, the asthenosphere becomes geochemically zoned with the ‘enriched’ intraplate basalt source (>500 ppm H
2
O) overlying the ‘depleted’ MORB source (~200 ppm H
2
O). From the study of primitive MOR picrites, the modern mantle potential temperature for MORB petrogenesis is ~1,430 °C. The intersection of the 1,430 °C adiabat with the vapour-saturated lherzolite solidus at ~230 km suggests that upwelling beneath mid-ocean ridges begins around this depth. In
intraplate
volcanism, diapiric upwelling begins from shallower depths and lower temperatures within the asthenosphere and the upwelling lherzolite is enriched in water, carbonate and incompatible elements. Magmas including olivine melilitites, olivine nephelinites, basanites, alkali picrites and tholeiitic picrites are consequences of increasing melt fraction and decreasing pressure at melt segregation. Major element, trace element and isotopic characteristics of island chain or ‘hot-spot’ magmas show that they sample geochemically distinct components in the upper mantle, differing from MORB sources. There is no evidence for
higher-temperature
‘hot-spot’ magmas, relative to primitive MORB, but there is evidence for higher water, CO
2
and incompatible element contents. The distinctive geochemical signatures of ‘hot-spot’ magmas and their ‘fixed’ position and long-lived activity relative to plate movement are attributed to melt components derived from melting at interfaces between old, oxidised subducted slabs (suspended beneath or within the deeper asthenosphere) and ambient, reduced mantle. In convergent margin volcanism, the inverted temperature gradients inferred for the mantle wedge above the subducting lithosphere introduce further complexity which can be explored by overlaying the phase relations of appropriate mantle and crustal lithologies. Water and carbonate derived from the subducted slab play significant roles, magmas are relatively oxidised, and distinctive primary magmas such as boninites, adakites and island arc ankaramites provide evidence for fluxing of melting in refractory harzburgite to lherzolite by slab-derived hydrous adakitic melt and by wedge-derived carbonatite.</description><identifier>ISSN: 0342-1791</identifier><identifier>EISSN: 1432-2021</identifier><identifier>DOI: 10.1007/s00269-014-0729-2</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Asthenosphere ; Basalt ; Carbon dioxide ; Crystallography and Scattering Methods ; Cylinders ; Dehydration ; Earth and Environmental Science ; Earth mantle ; Earth Sciences ; Fluxing ; Geochemistry ; High temperature ; Hot spots (geology) ; Island arcs ; Lithosphere ; Low temperature ; Magma ; Melting ; Microbeams ; Mid-ocean ridges ; Migration ; Mineral Resources ; Mineralogy ; Minerals ; Moisture content ; Olivine ; Original Paper ; Peridotite ; Petrogenesis ; Petrology ; Slabs ; Solidus ; Temperature ; Temperature gradients ; Trace elements ; Upper mantle ; Upwelling ; Vapor phases ; Water content ; Water monitoring ; Wedges</subject><ispartof>Physics and chemistry of minerals, 2015-02, Vol.42 (2), p.95-122</ispartof><rights>Springer-Verlag Berlin Heidelberg 2015</rights><rights>Physics and Chemistry of Minerals is a copyright of Springer, (2015). All Rights Reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a405t-dbec25c081ea34abba7ff1291b8fd0dc1d7f1047de13fbc9af592e27f779b4023</citedby><cites>FETCH-LOGICAL-a405t-dbec25c081ea34abba7ff1291b8fd0dc1d7f1047de13fbc9af592e27f779b4023</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s00269-014-0729-2$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s00269-014-0729-2$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Green, David H.</creatorcontrib><title>Experimental petrology of peridotites, including effects of water and carbon on melting in the Earth’s upper mantle</title><title>Physics and chemistry of minerals</title><addtitle>Phys Chem Minerals</addtitle><description>For over 50 years, the use of high-pressure piston/cylinder apparatus combined with an increasing diversity of microbeam analytical techniques has enabled the study of mantle peridotite compositions and of magmas derived by melting in the upper mantle. The experimental studies have been guided by the petrology and geochemistry of peridotites from diverse settings and by the remarkable range of mantle-derived magma types. Recent experimental study using FTIR spectroscopy to monitor water content of minerals has shown that fertile lherzolite (MORB-source upper mantle) at ~1,000 °C can store ~200 ppm H
2
O in defect sites in nominally anhydrous minerals (olivine, pyroxenes, garnet and spinel). Water in excess of 200 ppm stabilizes amphibole (pargasite) at
P
< 3 GPa up to the lherzolite solidus. However, at
P
> 3 GPa, water in excess of 200 ppm appears as an aqueous vapour phase and this depresses the temperature of the upper mantle solidus. Provided the uppermost mantle (lithosphere) has H
2
O < 4,000 ppm, the mantle solidus has a distinctive
P
,
T
shape. The temperature of the
vapour
-
undersaturated
or
dehydration solidus
is approximately constant at 1,100 °C at pressures up to ~3 GPa and then decreases sharply to ~1,010 °C. The strongly negative d
T
/d
P
of the vapour-undersaturated solidus of fertile lherzolite from 2.8 to 3 GPa provides the basis for understanding the lithosphere/asthenosphere boundary. Through upward migration of near-solidus hydrous silicate melt, the asthenosphere becomes geochemically zoned with the ‘enriched’ intraplate basalt source (>500 ppm H
2
O) overlying the ‘depleted’ MORB source (~200 ppm H
2
O). From the study of primitive MOR picrites, the modern mantle potential temperature for MORB petrogenesis is ~1,430 °C. The intersection of the 1,430 °C adiabat with the vapour-saturated lherzolite solidus at ~230 km suggests that upwelling beneath mid-ocean ridges begins around this depth. In
intraplate
volcanism, diapiric upwelling begins from shallower depths and lower temperatures within the asthenosphere and the upwelling lherzolite is enriched in water, carbonate and incompatible elements. Magmas including olivine melilitites, olivine nephelinites, basanites, alkali picrites and tholeiitic picrites are consequences of increasing melt fraction and decreasing pressure at melt segregation. Major element, trace element and isotopic characteristics of island chain or ‘hot-spot’ magmas show that they sample geochemically distinct components in the upper mantle, differing from MORB sources. There is no evidence for
higher-temperature
‘hot-spot’ magmas, relative to primitive MORB, but there is evidence for higher water, CO
2
and incompatible element contents. The distinctive geochemical signatures of ‘hot-spot’ magmas and their ‘fixed’ position and long-lived activity relative to plate movement are attributed to melt components derived from melting at interfaces between old, oxidised subducted slabs (suspended beneath or within the deeper asthenosphere) and ambient, reduced mantle. In convergent margin volcanism, the inverted temperature gradients inferred for the mantle wedge above the subducting lithosphere introduce further complexity which can be explored by overlaying the phase relations of appropriate mantle and crustal lithologies. Water and carbonate derived from the subducted slab play significant roles, magmas are relatively oxidised, and distinctive primary magmas such as boninites, adakites and island arc ankaramites provide evidence for fluxing of melting in refractory harzburgite to lherzolite by slab-derived hydrous adakitic melt and by wedge-derived carbonatite.</description><subject>Asthenosphere</subject><subject>Basalt</subject><subject>Carbon dioxide</subject><subject>Crystallography and Scattering Methods</subject><subject>Cylinders</subject><subject>Dehydration</subject><subject>Earth and Environmental Science</subject><subject>Earth mantle</subject><subject>Earth Sciences</subject><subject>Fluxing</subject><subject>Geochemistry</subject><subject>High temperature</subject><subject>Hot spots (geology)</subject><subject>Island arcs</subject><subject>Lithosphere</subject><subject>Low temperature</subject><subject>Magma</subject><subject>Melting</subject><subject>Microbeams</subject><subject>Mid-ocean ridges</subject><subject>Migration</subject><subject>Mineral Resources</subject><subject>Mineralogy</subject><subject>Minerals</subject><subject>Moisture content</subject><subject>Olivine</subject><subject>Original Paper</subject><subject>Peridotite</subject><subject>Petrogenesis</subject><subject>Petrology</subject><subject>Slabs</subject><subject>Solidus</subject><subject>Temperature</subject><subject>Temperature gradients</subject><subject>Trace elements</subject><subject>Upper mantle</subject><subject>Upwelling</subject><subject>Vapor phases</subject><subject>Water content</subject><subject>Water monitoring</subject><subject>Wedges</subject><issn>0342-1791</issn><issn>1432-2021</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNp1kM9KAzEQh4MoWKsP4C3g1egku9t0j1LqHyh40XPIbibtlm12TbJob76Gr-eTmKWCJ2FgYPh-v4GPkEsONxxA3gYAMSsZ8JyBFCUTR2TC80wwAYIfkwlkuWBclvyUnIWwhQRmspiQYfnRo2926KJuaY_Rd2233tPO0vFuuthEDNe0cXU7mMatKVqLdQwj8a4jeqqdobX2Vedomh22ccQaR-MG6VL7uPn-_Ap06FMh3WkXWzwnJ1a3AS9-95S83i9fFo9s9fzwtLhbMZ1DEZmpsBZFDXOOOst1VWlpLRclr-bWgKm5kZZDLg3yzFZ1qW1RChTSSllWOYhsSq4Ovb3v3gYMUW27wbv0UgkxEyDnMisSxQ9U7bsQPFrVJyPa7xUHNdpVB7sqSVOjXTU2i0MmJNat0f81_x_6AT8ugCI</recordid><startdate>20150201</startdate><enddate>20150201</enddate><creator>Green, David H.</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>BHPHI</scope><scope>BKSAR</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>PCBAR</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope></search><sort><creationdate>20150201</creationdate><title>Experimental petrology of peridotites, including effects of water and carbon on melting in the Earth’s upper mantle</title><author>Green, David H.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a405t-dbec25c081ea34abba7ff1291b8fd0dc1d7f1047de13fbc9af592e27f779b4023</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><topic>Asthenosphere</topic><topic>Basalt</topic><topic>Carbon dioxide</topic><topic>Crystallography and Scattering Methods</topic><topic>Cylinders</topic><topic>Dehydration</topic><topic>Earth and Environmental Science</topic><topic>Earth mantle</topic><topic>Earth Sciences</topic><topic>Fluxing</topic><topic>Geochemistry</topic><topic>High temperature</topic><topic>Hot spots (geology)</topic><topic>Island arcs</topic><topic>Lithosphere</topic><topic>Low temperature</topic><topic>Magma</topic><topic>Melting</topic><topic>Microbeams</topic><topic>Mid-ocean ridges</topic><topic>Migration</topic><topic>Mineral Resources</topic><topic>Mineralogy</topic><topic>Minerals</topic><topic>Moisture content</topic><topic>Olivine</topic><topic>Original Paper</topic><topic>Peridotite</topic><topic>Petrogenesis</topic><topic>Petrology</topic><topic>Slabs</topic><topic>Solidus</topic><topic>Temperature</topic><topic>Temperature gradients</topic><topic>Trace elements</topic><topic>Upper mantle</topic><topic>Upwelling</topic><topic>Vapor phases</topic><topic>Water content</topic><topic>Water monitoring</topic><topic>Wedges</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Green, David H.</creatorcontrib><collection>CrossRef</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>Natural Science Collection</collection><collection>Earth, Atmospheric & Aquatic Science Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>Earth, Atmospheric & Aquatic Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><jtitle>Physics and chemistry of minerals</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Green, David H.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Experimental petrology of peridotites, including effects of water and carbon on melting in the Earth’s upper mantle</atitle><jtitle>Physics and chemistry of minerals</jtitle><stitle>Phys Chem Minerals</stitle><date>2015-02-01</date><risdate>2015</risdate><volume>42</volume><issue>2</issue><spage>95</spage><epage>122</epage><pages>95-122</pages><issn>0342-1791</issn><eissn>1432-2021</eissn><abstract>For over 50 years, the use of high-pressure piston/cylinder apparatus combined with an increasing diversity of microbeam analytical techniques has enabled the study of mantle peridotite compositions and of magmas derived by melting in the upper mantle. The experimental studies have been guided by the petrology and geochemistry of peridotites from diverse settings and by the remarkable range of mantle-derived magma types. Recent experimental study using FTIR spectroscopy to monitor water content of minerals has shown that fertile lherzolite (MORB-source upper mantle) at ~1,000 °C can store ~200 ppm H
2
O in defect sites in nominally anhydrous minerals (olivine, pyroxenes, garnet and spinel). Water in excess of 200 ppm stabilizes amphibole (pargasite) at
P
< 3 GPa up to the lherzolite solidus. However, at
P
> 3 GPa, water in excess of 200 ppm appears as an aqueous vapour phase and this depresses the temperature of the upper mantle solidus. Provided the uppermost mantle (lithosphere) has H
2
O < 4,000 ppm, the mantle solidus has a distinctive
P
,
T
shape. The temperature of the
vapour
-
undersaturated
or
dehydration solidus
is approximately constant at 1,100 °C at pressures up to ~3 GPa and then decreases sharply to ~1,010 °C. The strongly negative d
T
/d
P
of the vapour-undersaturated solidus of fertile lherzolite from 2.8 to 3 GPa provides the basis for understanding the lithosphere/asthenosphere boundary. Through upward migration of near-solidus hydrous silicate melt, the asthenosphere becomes geochemically zoned with the ‘enriched’ intraplate basalt source (>500 ppm H
2
O) overlying the ‘depleted’ MORB source (~200 ppm H
2
O). From the study of primitive MOR picrites, the modern mantle potential temperature for MORB petrogenesis is ~1,430 °C. The intersection of the 1,430 °C adiabat with the vapour-saturated lherzolite solidus at ~230 km suggests that upwelling beneath mid-ocean ridges begins around this depth. In
intraplate
volcanism, diapiric upwelling begins from shallower depths and lower temperatures within the asthenosphere and the upwelling lherzolite is enriched in water, carbonate and incompatible elements. Magmas including olivine melilitites, olivine nephelinites, basanites, alkali picrites and tholeiitic picrites are consequences of increasing melt fraction and decreasing pressure at melt segregation. Major element, trace element and isotopic characteristics of island chain or ‘hot-spot’ magmas show that they sample geochemically distinct components in the upper mantle, differing from MORB sources. There is no evidence for
higher-temperature
‘hot-spot’ magmas, relative to primitive MORB, but there is evidence for higher water, CO
2
and incompatible element contents. The distinctive geochemical signatures of ‘hot-spot’ magmas and their ‘fixed’ position and long-lived activity relative to plate movement are attributed to melt components derived from melting at interfaces between old, oxidised subducted slabs (suspended beneath or within the deeper asthenosphere) and ambient, reduced mantle. In convergent margin volcanism, the inverted temperature gradients inferred for the mantle wedge above the subducting lithosphere introduce further complexity which can be explored by overlaying the phase relations of appropriate mantle and crustal lithologies. Water and carbonate derived from the subducted slab play significant roles, magmas are relatively oxidised, and distinctive primary magmas such as boninites, adakites and island arc ankaramites provide evidence for fluxing of melting in refractory harzburgite to lherzolite by slab-derived hydrous adakitic melt and by wedge-derived carbonatite.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s00269-014-0729-2</doi><tpages>28</tpages></addata></record> |
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subjects | Asthenosphere Basalt Carbon dioxide Crystallography and Scattering Methods Cylinders Dehydration Earth and Environmental Science Earth mantle Earth Sciences Fluxing Geochemistry High temperature Hot spots (geology) Island arcs Lithosphere Low temperature Magma Melting Microbeams Mid-ocean ridges Migration Mineral Resources Mineralogy Minerals Moisture content Olivine Original Paper Peridotite Petrogenesis Petrology Slabs Solidus Temperature Temperature gradients Trace elements Upper mantle Upwelling Vapor phases Water content Water monitoring Wedges |
title | Experimental petrology of peridotites, including effects of water and carbon on melting in the Earth’s upper mantle |
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