Flow and structure development behavior of bar soaps containing synthetic detergent
Many bar soaps are processed using continuous processing technologies, including single and twin screw extrusion. However, in spite of the industrial importance of the extrusion-based processing of bar soaps the rheological behavior of bar soaps is poorly understood. Here, the shear viscosity and th...
Gespeichert in:
| Veröffentlicht in: | Rheologica acta 2004-08, Vol.43 (4), p.396-405 |
|---|---|
| Hauptverfasser: | , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 405 |
|---|---|
| container_issue | 4 |
| container_start_page | 396 |
| container_title | Rheologica acta |
| container_volume | 43 |
| creator | KALYON, Dilhan M GEVGILILI, Halil YAZICI, Rahmi POST, Albert J MCFANN, Gregory J |
| description | Many bar soaps are processed using continuous processing technologies, including single and twin screw extrusion. However, in spite of the industrial importance of the extrusion-based processing of bar soaps the rheological behavior of bar soaps is poorly understood. Here, the shear viscosity and the formation of gross surface irregularities upon extrusion of the bar soap were investigated using steady torsional, rectangular slit, and capillary flows. Furthermore, the structure development aspects were investigated using wide-angle X-ray diffraction and scanning electron microscopy. It is revealed that the flow and deformation behavior of bar soaps is complicated by the ubiquitous presence of wall slip, viscoplasticity, gross surface irregularities, and various structuring aspects. The orientation of crystallites and the shear stress dependent fracture of a crystalline component of the formulation at the wall during flow were identified as some of the contributing effects to the development of the structure of the bar soap during flow and deformation. |
| doi_str_mv | 10.1007/s00397-004-0357-8 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2262016728</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2262016728</sourcerecordid><originalsourceid>FETCH-LOGICAL-c338t-d0ed47d9093ab8f76c4ba3517862b0c8326493061acc091bd0d4c7119a5444dc3</originalsourceid><addsrcrecordid>eNpFkE1LAzEQhoMoWD9-gLeAeIxONslm9yjFqlDwoJ5DNsm2W7abNclW-u9NacHTHOZ93mEehO4oPFIA-RQBWC0JACfAhCTVGZpRzgShoqjO0SyvBeGC0kt0FeMGgMpSFjP0uej9L9aDxTGFyaQpOGzdzvV-3Loh4cat9a7zAfsWNzrg6PUYsfFD0t3QDSsc90Nau9SZjCUXVhm6QRet7qO7Pc1r9L14-Zq_keXH6_v8eUkMY1UiFpzl0tZQM91UrSwNbzQTVFZl0YCpWFHymkFJtTFQ08aC5UZSWmvBObeGXaP7Y-8Y_M_kYlIbP4Uhn1RFURZA84dVTtFjygQfY3CtGkO31WGvKKiDO3V0p7I7dXCnDszDqVlHo_s26MF08R8UtcwGBfsDTwluyA</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2262016728</pqid></control><display><type>article</type><title>Flow and structure development behavior of bar soaps containing synthetic detergent</title><source>Springer Nature - Complete Springer Journals</source><creator>KALYON, Dilhan M ; GEVGILILI, Halil ; YAZICI, Rahmi ; POST, Albert J ; MCFANN, Gregory J</creator><creatorcontrib>KALYON, Dilhan M ; GEVGILILI, Halil ; YAZICI, Rahmi ; POST, Albert J ; MCFANN, Gregory J</creatorcontrib><description>Many bar soaps are processed using continuous processing technologies, including single and twin screw extrusion. However, in spite of the industrial importance of the extrusion-based processing of bar soaps the rheological behavior of bar soaps is poorly understood. Here, the shear viscosity and the formation of gross surface irregularities upon extrusion of the bar soap were investigated using steady torsional, rectangular slit, and capillary flows. Furthermore, the structure development aspects were investigated using wide-angle X-ray diffraction and scanning electron microscopy. It is revealed that the flow and deformation behavior of bar soaps is complicated by the ubiquitous presence of wall slip, viscoplasticity, gross surface irregularities, and various structuring aspects. The orientation of crystallites and the shear stress dependent fracture of a crystalline component of the formulation at the wall during flow were identified as some of the contributing effects to the development of the structure of the bar soap during flow and deformation.</description><identifier>ISSN: 0035-4511</identifier><identifier>EISSN: 1435-1528</identifier><identifier>DOI: 10.1007/s00397-004-0357-8</identifier><identifier>CODEN: RHEAAK</identifier><language>eng</language><publisher>Berlin: Springer</publisher><subject>Applied sciences ; Capillary flow ; Chemical industry and chemicals ; Continuous extrusion ; Cosmetics, toiletries ; Crystallites ; Deformation ; Exact sciences and technology ; Irregularities ; Rheological properties ; Scanning electron microscopy ; Shear stress ; Shear viscosity ; Soaps ; Viscoplasticity ; Viscosity ; Wall slip ; Washing products. Cosmetics and toiletries. Perfumes</subject><ispartof>Rheologica acta, 2004-08, Vol.43 (4), p.396-405</ispartof><rights>2004 INIST-CNRS</rights><rights>Rheologica Acta is a copyright of Springer, (2004). All Rights Reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c338t-d0ed47d9093ab8f76c4ba3517862b0c8326493061acc091bd0d4c7119a5444dc3</citedby></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27903,27904</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=15970015$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>KALYON, Dilhan M</creatorcontrib><creatorcontrib>GEVGILILI, Halil</creatorcontrib><creatorcontrib>YAZICI, Rahmi</creatorcontrib><creatorcontrib>POST, Albert J</creatorcontrib><creatorcontrib>MCFANN, Gregory J</creatorcontrib><title>Flow and structure development behavior of bar soaps containing synthetic detergent</title><title>Rheologica acta</title><description>Many bar soaps are processed using continuous processing technologies, including single and twin screw extrusion. However, in spite of the industrial importance of the extrusion-based processing of bar soaps the rheological behavior of bar soaps is poorly understood. Here, the shear viscosity and the formation of gross surface irregularities upon extrusion of the bar soap were investigated using steady torsional, rectangular slit, and capillary flows. Furthermore, the structure development aspects were investigated using wide-angle X-ray diffraction and scanning electron microscopy. It is revealed that the flow and deformation behavior of bar soaps is complicated by the ubiquitous presence of wall slip, viscoplasticity, gross surface irregularities, and various structuring aspects. The orientation of crystallites and the shear stress dependent fracture of a crystalline component of the formulation at the wall during flow were identified as some of the contributing effects to the development of the structure of the bar soap during flow and deformation.</description><subject>Applied sciences</subject><subject>Capillary flow</subject><subject>Chemical industry and chemicals</subject><subject>Continuous extrusion</subject><subject>Cosmetics, toiletries</subject><subject>Crystallites</subject><subject>Deformation</subject><subject>Exact sciences and technology</subject><subject>Irregularities</subject><subject>Rheological properties</subject><subject>Scanning electron microscopy</subject><subject>Shear stress</subject><subject>Shear viscosity</subject><subject>Soaps</subject><subject>Viscoplasticity</subject><subject>Viscosity</subject><subject>Wall slip</subject><subject>Washing products. Cosmetics and toiletries. Perfumes</subject><issn>0035-4511</issn><issn>1435-1528</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2004</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNpFkE1LAzEQhoMoWD9-gLeAeIxONslm9yjFqlDwoJ5DNsm2W7abNclW-u9NacHTHOZ93mEehO4oPFIA-RQBWC0JACfAhCTVGZpRzgShoqjO0SyvBeGC0kt0FeMGgMpSFjP0uej9L9aDxTGFyaQpOGzdzvV-3Loh4cat9a7zAfsWNzrg6PUYsfFD0t3QDSsc90Nau9SZjCUXVhm6QRet7qO7Pc1r9L14-Zq_keXH6_v8eUkMY1UiFpzl0tZQM91UrSwNbzQTVFZl0YCpWFHymkFJtTFQ08aC5UZSWmvBObeGXaP7Y-8Y_M_kYlIbP4Uhn1RFURZA84dVTtFjygQfY3CtGkO31WGvKKiDO3V0p7I7dXCnDszDqVlHo_s26MF08R8UtcwGBfsDTwluyA</recordid><startdate>20040801</startdate><enddate>20040801</enddate><creator>KALYON, Dilhan M</creator><creator>GEVGILILI, Halil</creator><creator>YAZICI, Rahmi</creator><creator>POST, Albert J</creator><creator>MCFANN, Gregory J</creator><general>Springer</general><general>Springer Nature B.V</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>L6V</scope><scope>M7S</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>PTHSS</scope></search><sort><creationdate>20040801</creationdate><title>Flow and structure development behavior of bar soaps containing synthetic detergent</title><author>KALYON, Dilhan M ; GEVGILILI, Halil ; YAZICI, Rahmi ; POST, Albert J ; MCFANN, Gregory J</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c338t-d0ed47d9093ab8f76c4ba3517862b0c8326493061acc091bd0d4c7119a5444dc3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2004</creationdate><topic>Applied sciences</topic><topic>Capillary flow</topic><topic>Chemical industry and chemicals</topic><topic>Continuous extrusion</topic><topic>Cosmetics, toiletries</topic><topic>Crystallites</topic><topic>Deformation</topic><topic>Exact sciences and technology</topic><topic>Irregularities</topic><topic>Rheological properties</topic><topic>Scanning electron microscopy</topic><topic>Shear stress</topic><topic>Shear viscosity</topic><topic>Soaps</topic><topic>Viscoplasticity</topic><topic>Viscosity</topic><topic>Wall slip</topic><topic>Washing products. Cosmetics and toiletries. Perfumes</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>KALYON, Dilhan M</creatorcontrib><creatorcontrib>GEVGILILI, Halil</creatorcontrib><creatorcontrib>YAZICI, Rahmi</creatorcontrib><creatorcontrib>POST, Albert J</creatorcontrib><creatorcontrib>MCFANN, Gregory J</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>ProQuest Engineering Collection</collection><collection>Engineering Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>Engineering Collection</collection><jtitle>Rheologica acta</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>KALYON, Dilhan M</au><au>GEVGILILI, Halil</au><au>YAZICI, Rahmi</au><au>POST, Albert J</au><au>MCFANN, Gregory J</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Flow and structure development behavior of bar soaps containing synthetic detergent</atitle><jtitle>Rheologica acta</jtitle><date>2004-08-01</date><risdate>2004</risdate><volume>43</volume><issue>4</issue><spage>396</spage><epage>405</epage><pages>396-405</pages><issn>0035-4511</issn><eissn>1435-1528</eissn><coden>RHEAAK</coden><abstract>Many bar soaps are processed using continuous processing technologies, including single and twin screw extrusion. However, in spite of the industrial importance of the extrusion-based processing of bar soaps the rheological behavior of bar soaps is poorly understood. Here, the shear viscosity and the formation of gross surface irregularities upon extrusion of the bar soap were investigated using steady torsional, rectangular slit, and capillary flows. Furthermore, the structure development aspects were investigated using wide-angle X-ray diffraction and scanning electron microscopy. It is revealed that the flow and deformation behavior of bar soaps is complicated by the ubiquitous presence of wall slip, viscoplasticity, gross surface irregularities, and various structuring aspects. The orientation of crystallites and the shear stress dependent fracture of a crystalline component of the formulation at the wall during flow were identified as some of the contributing effects to the development of the structure of the bar soap during flow and deformation.</abstract><cop>Berlin</cop><pub>Springer</pub><doi>10.1007/s00397-004-0357-8</doi><tpages>10</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0035-4511 |
| ispartof | Rheologica acta, 2004-08, Vol.43 (4), p.396-405 |
| issn | 0035-4511 1435-1528 |
| language | eng |
| recordid | cdi_proquest_journals_2262016728 |
| source | Springer Nature - Complete Springer Journals |
| subjects | Applied sciences Capillary flow Chemical industry and chemicals Continuous extrusion Cosmetics, toiletries Crystallites Deformation Exact sciences and technology Irregularities Rheological properties Scanning electron microscopy Shear stress Shear viscosity Soaps Viscoplasticity Viscosity Wall slip Washing products. Cosmetics and toiletries. Perfumes |
| title | Flow and structure development behavior of bar soaps containing synthetic detergent |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-21T18%3A36%3A52IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Flow%20and%20structure%20development%20behavior%20of%20bar%20soaps%20containing%20synthetic%20detergent&rft.jtitle=Rheologica%20acta&rft.au=KALYON,%20Dilhan%20M&rft.date=2004-08-01&rft.volume=43&rft.issue=4&rft.spage=396&rft.epage=405&rft.pages=396-405&rft.issn=0035-4511&rft.eissn=1435-1528&rft.coden=RHEAAK&rft_id=info:doi/10.1007/s00397-004-0357-8&rft_dat=%3Cproquest_cross%3E2262016728%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2262016728&rft_id=info:pmid/&rfr_iscdi=true |