Wall slip phenomena in concentrated ionic liquid-based magnetorheological fluids
Ionic liquids (ILs) have been recently proposed as carrier for magnetorheological (MR) fluids. Their special properties, such as very low vapor pressure and high thermal stability, make ILs highly suitable dispersion media to increase the broad range of technological applications that magnetorheolog...
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description | Ionic liquids (ILs) have been recently proposed as carrier for magnetorheological (MR) fluids. Their special properties, such as very low vapor pressure and high thermal stability, make ILs highly suitable dispersion media to increase the broad range of technological applications that magnetorheological fluids already have. It has been just reported that using ILs as carriers in MR fluids an improvement in the colloidal stability and suspension redispersibility is obtained. In this work, the magnetorheological behavior of highly concentrated suspensions in ILs is studied. Two kinds of suspensions were analyzed: using an ionic liquid of low conductivity and a mineral oil as carriers. In both cases, silica-coated iron microparticles were used as solid phase, being the solid volume concentration of 50% vol. A complete magnetorheological analysis focused on the wall slip phenomenon was performed. Steady-state and oscillatory experiments were carried out. In order to study wall slip effects, all experiments were performed with a plate–plate system, using both smooth and rough measuring surfaces. A significant effect of wall slip was observed when the experiments were performed using smooth surfaces. The novelty of this paper is mainly based on (1) the use of an ionic liquid as carrier to prepare magnetic suspensions, and (2) the analysis of wall slip phenomena in MR fluids with a particle content close to the maximum packing fraction. |
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G.</creator><creatorcontrib>Gómez-Ramírez, Ana ; López-López, Modesto Torcuato ; González-Caballero, Fernando ; Durán, Juan D. G.</creatorcontrib><description>Ionic liquids (ILs) have been recently proposed as carrier for magnetorheological (MR) fluids. Their special properties, such as very low vapor pressure and high thermal stability, make ILs highly suitable dispersion media to increase the broad range of technological applications that magnetorheological fluids already have. It has been just reported that using ILs as carriers in MR fluids an improvement in the colloidal stability and suspension redispersibility is obtained. In this work, the magnetorheological behavior of highly concentrated suspensions in ILs is studied. Two kinds of suspensions were analyzed: using an ionic liquid of low conductivity and a mineral oil as carriers. In both cases, silica-coated iron microparticles were used as solid phase, being the solid volume concentration of 50% vol. A complete magnetorheological analysis focused on the wall slip phenomenon was performed. Steady-state and oscillatory experiments were carried out. In order to study wall slip effects, all experiments were performed with a plate–plate system, using both smooth and rough measuring surfaces. A significant effect of wall slip was observed when the experiments were performed using smooth surfaces. The novelty of this paper is mainly based on (1) the use of an ionic liquid as carrier to prepare magnetic suspensions, and (2) the analysis of wall slip phenomena in MR fluids with a particle content close to the maximum packing fraction.</description><identifier>ISSN: 0035-4511</identifier><identifier>EISSN: 1435-1528</identifier><identifier>DOI: 10.1007/s00397-012-0639-5</identifier><identifier>CODEN: RHEAAK</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer-Verlag</publisher><subject>Characterization and Evaluation of Materials ; Chemistry and Materials Science ; Complex Fluids and Microfluidics ; Cross-disciplinary physics: materials science; rheology ; Electro- and magnetorheological fluids ; Exact sciences and technology ; Experiments ; Food Science ; Ionic liquids ; Ions ; Low conductivity ; Magnetic levitation ; Magnetic properties ; Magnetorheological fluids ; Material types ; Materials Science ; Mechanical Engineering ; Microparticles ; Mineral oils ; Original Contribution ; Physics ; Polymer Sciences ; Rheology ; Silicon dioxide ; Soft and Granular Matter ; Solid phases ; Solvents ; Thermal stability ; Vapor pressure ; Wall slip</subject><ispartof>Rheologica acta, 2012-09, Vol.51 (9), p.793-803</ispartof><rights>Springer-Verlag 2012</rights><rights>2015 INIST-CNRS</rights><rights>Rheologica Acta is a copyright of Springer, (2012). 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G.</creatorcontrib><title>Wall slip phenomena in concentrated ionic liquid-based magnetorheological fluids</title><title>Rheologica acta</title><addtitle>Rheol Acta</addtitle><description>Ionic liquids (ILs) have been recently proposed as carrier for magnetorheological (MR) fluids. Their special properties, such as very low vapor pressure and high thermal stability, make ILs highly suitable dispersion media to increase the broad range of technological applications that magnetorheological fluids already have. It has been just reported that using ILs as carriers in MR fluids an improvement in the colloidal stability and suspension redispersibility is obtained. In this work, the magnetorheological behavior of highly concentrated suspensions in ILs is studied. Two kinds of suspensions were analyzed: using an ionic liquid of low conductivity and a mineral oil as carriers. In both cases, silica-coated iron microparticles were used as solid phase, being the solid volume concentration of 50% vol. A complete magnetorheological analysis focused on the wall slip phenomenon was performed. Steady-state and oscillatory experiments were carried out. In order to study wall slip effects, all experiments were performed with a plate–plate system, using both smooth and rough measuring surfaces. A significant effect of wall slip was observed when the experiments were performed using smooth surfaces. 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G.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c389t-88137e529b657e550463de75367abf7beff9c493b35e28e04c96b2847b46d1ce3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2012</creationdate><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry and Materials Science</topic><topic>Complex Fluids and Microfluidics</topic><topic>Cross-disciplinary physics: materials science; rheology</topic><topic>Electro- and magnetorheological fluids</topic><topic>Exact sciences and technology</topic><topic>Experiments</topic><topic>Food Science</topic><topic>Ionic liquids</topic><topic>Ions</topic><topic>Low conductivity</topic><topic>Magnetic levitation</topic><topic>Magnetic properties</topic><topic>Magnetorheological fluids</topic><topic>Material types</topic><topic>Materials Science</topic><topic>Mechanical Engineering</topic><topic>Microparticles</topic><topic>Mineral oils</topic><topic>Original Contribution</topic><topic>Physics</topic><topic>Polymer Sciences</topic><topic>Rheology</topic><topic>Silicon dioxide</topic><topic>Soft and Granular Matter</topic><topic>Solid phases</topic><topic>Solvents</topic><topic>Thermal stability</topic><topic>Vapor pressure</topic><topic>Wall slip</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Gómez-Ramírez, Ana</creatorcontrib><creatorcontrib>López-López, Modesto Torcuato</creatorcontrib><creatorcontrib>González-Caballero, Fernando</creatorcontrib><creatorcontrib>Durán, Juan D. 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G.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Wall slip phenomena in concentrated ionic liquid-based magnetorheological fluids</atitle><jtitle>Rheologica acta</jtitle><stitle>Rheol Acta</stitle><date>2012-09-01</date><risdate>2012</risdate><volume>51</volume><issue>9</issue><spage>793</spage><epage>803</epage><pages>793-803</pages><issn>0035-4511</issn><eissn>1435-1528</eissn><coden>RHEAAK</coden><abstract>Ionic liquids (ILs) have been recently proposed as carrier for magnetorheological (MR) fluids. Their special properties, such as very low vapor pressure and high thermal stability, make ILs highly suitable dispersion media to increase the broad range of technological applications that magnetorheological fluids already have. It has been just reported that using ILs as carriers in MR fluids an improvement in the colloidal stability and suspension redispersibility is obtained. In this work, the magnetorheological behavior of highly concentrated suspensions in ILs is studied. Two kinds of suspensions were analyzed: using an ionic liquid of low conductivity and a mineral oil as carriers. In both cases, silica-coated iron microparticles were used as solid phase, being the solid volume concentration of 50% vol. A complete magnetorheological analysis focused on the wall slip phenomenon was performed. Steady-state and oscillatory experiments were carried out. In order to study wall slip effects, all experiments were performed with a plate–plate system, using both smooth and rough measuring surfaces. A significant effect of wall slip was observed when the experiments were performed using smooth surfaces. 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subjects | Characterization and Evaluation of Materials Chemistry and Materials Science Complex Fluids and Microfluidics Cross-disciplinary physics: materials science rheology Electro- and magnetorheological fluids Exact sciences and technology Experiments Food Science Ionic liquids Ions Low conductivity Magnetic levitation Magnetic properties Magnetorheological fluids Material types Materials Science Mechanical Engineering Microparticles Mineral oils Original Contribution Physics Polymer Sciences Rheology Silicon dioxide Soft and Granular Matter Solid phases Solvents Thermal stability Vapor pressure Wall slip |
title | Wall slip phenomena in concentrated ionic liquid-based magnetorheological fluids |
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