Modelling and characterisation of diluted and concentrated water-in-crude oil emulsions: comparison with classical behaviour
Water-in-oil type emulsions can be formed during the crude oil production process. The presence of natural surfactants in oil (asphaltenes, resins) and mechanical stirring (piping/well system) produce emulsions, the stability and rheological behaviour of which depend mainly on the chemical compositi...
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| Veröffentlicht in: | Rheologica acta 2008-05, Vol.47 (4), p.417-424 |
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| creator | Quintero, Carlos Gerardo Noïk, Christine Dalmazzone, Christine Grossiord, Jean-Louis |
| description | Water-in-oil type emulsions can be formed during the crude oil production process. The presence of natural surfactants in oil (asphaltenes, resins) and mechanical stirring (piping/well system) produce emulsions, the stability and rheological behaviour of which depend mainly on the chemical composition of the oil and the internal phase concentration. In this work, water (brine 8 g NaCl/cm
3
) in oil (crude oil) emulsions were prepared and characterised by varying the internal phase concentration (5–80%). Rheological properties are discussed according to the composition of the oil and the temperature of the system. Relative viscosity was modelled following the classical models of Mooney and Krieger and Dougherty, but the best-fitting model for the experimental results was found with an exponential type equation between relative viscosity and volume fraction, as proposed by Richardson. Moreover, we observed that the plastic behaviour determined through the yield stress determination depended not only on the internal phase concentration but also on the temperature. Quantitative analysis of the emulsions’ viscoelastic parameters (storage and loss modulus) was made. In the case of concentrated emulsions (containing over 70% of internal phase), Princen’s theory of the high internal phase ratio emulsions (HIPRES) was verified. |
| doi_str_mv | 10.1007/s00397-008-0262-7 |
| format | Article |
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3
) in oil (crude oil) emulsions were prepared and characterised by varying the internal phase concentration (5–80%). Rheological properties are discussed according to the composition of the oil and the temperature of the system. Relative viscosity was modelled following the classical models of Mooney and Krieger and Dougherty, but the best-fitting model for the experimental results was found with an exponential type equation between relative viscosity and volume fraction, as proposed by Richardson. Moreover, we observed that the plastic behaviour determined through the yield stress determination depended not only on the internal phase concentration but also on the temperature. Quantitative analysis of the emulsions’ viscoelastic parameters (storage and loss modulus) was made. In the case of concentrated emulsions (containing over 70% of internal phase), Princen’s theory of the high internal phase ratio emulsions (HIPRES) was verified.</description><identifier>ISSN: 0035-4511</identifier><identifier>EISSN: 1435-1528</identifier><identifier>DOI: 10.1007/s00397-008-0262-7</identifier><identifier>CODEN: RHEAAK</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer-Verlag</publisher><subject>Applied sciences ; Asphaltenes ; Characterization and Evaluation of Materials ; Chemical composition ; Chemistry and Materials Science ; Complex Fluids and Microfluidics ; Constitution and properties of crude oils, shale oils, natural gas and bitumens. Analysis and characteristics ; Crude oil ; Crude oil, natural gas and petroleum products ; Emulsions ; Energy ; Exact sciences and technology ; Food Science ; Fuels ; Loss modulus ; Materials Science ; Mechanical Engineering ; Organic chemistry ; Original Contribution ; Phase ratio ; Piping ; Polymer Sciences ; Quantitative analysis ; Rheological properties ; Rheology ; Saline water ; Soft and Granular Matter ; Viscoelasticity ; Viscosity ; Yield stress</subject><ispartof>Rheologica acta, 2008-05, Vol.47 (4), p.417-424</ispartof><rights>Springer-Verlag 2008</rights><rights>2008 INIST-CNRS</rights><rights>Rheologica Acta is a copyright of Springer, (2008). All Rights Reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c383t-6ab79394c3a82dcf31d875d7d18ae521daaaf9872fa16eb835363ce49e47489d3</citedby><cites>FETCH-LOGICAL-c383t-6ab79394c3a82dcf31d875d7d18ae521daaaf9872fa16eb835363ce49e47489d3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s00397-008-0262-7$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s00397-008-0262-7$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=20337103$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Quintero, Carlos Gerardo</creatorcontrib><creatorcontrib>Noïk, Christine</creatorcontrib><creatorcontrib>Dalmazzone, Christine</creatorcontrib><creatorcontrib>Grossiord, Jean-Louis</creatorcontrib><title>Modelling and characterisation of diluted and concentrated water-in-crude oil emulsions: comparison with classical behaviour</title><title>Rheologica acta</title><addtitle>Rheol Acta</addtitle><description>Water-in-oil type emulsions can be formed during the crude oil production process. The presence of natural surfactants in oil (asphaltenes, resins) and mechanical stirring (piping/well system) produce emulsions, the stability and rheological behaviour of which depend mainly on the chemical composition of the oil and the internal phase concentration. In this work, water (brine 8 g NaCl/cm
3
) in oil (crude oil) emulsions were prepared and characterised by varying the internal phase concentration (5–80%). Rheological properties are discussed according to the composition of the oil and the temperature of the system. Relative viscosity was modelled following the classical models of Mooney and Krieger and Dougherty, but the best-fitting model for the experimental results was found with an exponential type equation between relative viscosity and volume fraction, as proposed by Richardson. Moreover, we observed that the plastic behaviour determined through the yield stress determination depended not only on the internal phase concentration but also on the temperature. Quantitative analysis of the emulsions’ viscoelastic parameters (storage and loss modulus) was made. In the case of concentrated emulsions (containing over 70% of internal phase), Princen’s theory of the high internal phase ratio emulsions (HIPRES) was verified.</description><subject>Applied sciences</subject><subject>Asphaltenes</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemical composition</subject><subject>Chemistry and Materials Science</subject><subject>Complex Fluids and Microfluidics</subject><subject>Constitution and properties of crude oils, shale oils, natural gas and bitumens. Analysis and characteristics</subject><subject>Crude oil</subject><subject>Crude oil, natural gas and petroleum products</subject><subject>Emulsions</subject><subject>Energy</subject><subject>Exact sciences and technology</subject><subject>Food Science</subject><subject>Fuels</subject><subject>Loss modulus</subject><subject>Materials Science</subject><subject>Mechanical Engineering</subject><subject>Organic chemistry</subject><subject>Original Contribution</subject><subject>Phase ratio</subject><subject>Piping</subject><subject>Polymer Sciences</subject><subject>Quantitative analysis</subject><subject>Rheological properties</subject><subject>Rheology</subject><subject>Saline water</subject><subject>Soft and Granular Matter</subject><subject>Viscoelasticity</subject><subject>Viscosity</subject><subject>Yield stress</subject><issn>0035-4511</issn><issn>1435-1528</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2008</creationdate><recordtype>article</recordtype><sourceid>BENPR</sourceid><recordid>eNp1kEtLAzEUhYMoWKs_wF1AXEbzmJlk3EnxBRU3ug63SaZNmWZqMmMR_PGmjOjKTQI553z35iB0zugVo1ReJ0pFLQmlilBecSIP0IQVoiSs5OoQTbJckqJk7BidpLSmlMlK8gn6eu6sa1sflhiCxWYFEUzvok_Q-y7grsHWt0Pv7Kh3wbjQR9g_7PIZiQ_ExME63PkWu83QppxLN9m62ULmZMjO9ytsWkjJG2jxwq3gw3dDPEVHDbTJnf3cU_R2f_c6eyTzl4en2e2cGKFETypYyFrUhRGguDWNYFbJ0krLFLiSMwsATa0kb4BVbqFEKSphXFG7QhaqtmKKLkbuNnbvg0u9XufpIY_UPJeVSyuYyC42ukzsUoqu0dvoNxA_NaN6X7IeS9bZr_cla5kzlz9kSPlrTYRgfPoNciqEZHTP5qMvZSksXfzb4H_4NyCljo4</recordid><startdate>20080501</startdate><enddate>20080501</enddate><creator>Quintero, Carlos Gerardo</creator><creator>Noïk, Christine</creator><creator>Dalmazzone, Christine</creator><creator>Grossiord, Jean-Louis</creator><general>Springer-Verlag</general><general>Springer</general><general>Springer Nature B.V</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>L6V</scope><scope>M7S</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>PTHSS</scope></search><sort><creationdate>20080501</creationdate><title>Modelling and characterisation of diluted and concentrated water-in-crude oil emulsions: comparison with classical behaviour</title><author>Quintero, Carlos Gerardo ; Noïk, Christine ; Dalmazzone, Christine ; Grossiord, Jean-Louis</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c383t-6ab79394c3a82dcf31d875d7d18ae521daaaf9872fa16eb835363ce49e47489d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2008</creationdate><topic>Applied sciences</topic><topic>Asphaltenes</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemical composition</topic><topic>Chemistry and Materials Science</topic><topic>Complex Fluids and Microfluidics</topic><topic>Constitution and properties of crude oils, shale oils, natural gas and bitumens. Analysis and characteristics</topic><topic>Crude oil</topic><topic>Crude oil, natural gas and petroleum products</topic><topic>Emulsions</topic><topic>Energy</topic><topic>Exact sciences and technology</topic><topic>Food Science</topic><topic>Fuels</topic><topic>Loss modulus</topic><topic>Materials Science</topic><topic>Mechanical Engineering</topic><topic>Organic chemistry</topic><topic>Original Contribution</topic><topic>Phase ratio</topic><topic>Piping</topic><topic>Polymer Sciences</topic><topic>Quantitative analysis</topic><topic>Rheological properties</topic><topic>Rheology</topic><topic>Saline water</topic><topic>Soft and Granular Matter</topic><topic>Viscoelasticity</topic><topic>Viscosity</topic><topic>Yield stress</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Quintero, Carlos Gerardo</creatorcontrib><creatorcontrib>Noïk, Christine</creatorcontrib><creatorcontrib>Dalmazzone, Christine</creatorcontrib><creatorcontrib>Grossiord, Jean-Louis</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>ProQuest Engineering Collection</collection><collection>Engineering Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>Engineering Collection</collection><jtitle>Rheologica acta</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Quintero, Carlos Gerardo</au><au>Noïk, Christine</au><au>Dalmazzone, Christine</au><au>Grossiord, Jean-Louis</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Modelling and characterisation of diluted and concentrated water-in-crude oil emulsions: comparison with classical behaviour</atitle><jtitle>Rheologica acta</jtitle><stitle>Rheol Acta</stitle><date>2008-05-01</date><risdate>2008</risdate><volume>47</volume><issue>4</issue><spage>417</spage><epage>424</epage><pages>417-424</pages><issn>0035-4511</issn><eissn>1435-1528</eissn><coden>RHEAAK</coden><abstract>Water-in-oil type emulsions can be formed during the crude oil production process. The presence of natural surfactants in oil (asphaltenes, resins) and mechanical stirring (piping/well system) produce emulsions, the stability and rheological behaviour of which depend mainly on the chemical composition of the oil and the internal phase concentration. In this work, water (brine 8 g NaCl/cm
3
) in oil (crude oil) emulsions were prepared and characterised by varying the internal phase concentration (5–80%). Rheological properties are discussed according to the composition of the oil and the temperature of the system. Relative viscosity was modelled following the classical models of Mooney and Krieger and Dougherty, but the best-fitting model for the experimental results was found with an exponential type equation between relative viscosity and volume fraction, as proposed by Richardson. Moreover, we observed that the plastic behaviour determined through the yield stress determination depended not only on the internal phase concentration but also on the temperature. Quantitative analysis of the emulsions’ viscoelastic parameters (storage and loss modulus) was made. In the case of concentrated emulsions (containing over 70% of internal phase), Princen’s theory of the high internal phase ratio emulsions (HIPRES) was verified.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer-Verlag</pub><doi>10.1007/s00397-008-0262-7</doi><tpages>8</tpages></addata></record> |
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| subjects | Applied sciences Asphaltenes Characterization and Evaluation of Materials Chemical composition Chemistry and Materials Science Complex Fluids and Microfluidics Constitution and properties of crude oils, shale oils, natural gas and bitumens. Analysis and characteristics Crude oil Crude oil, natural gas and petroleum products Emulsions Energy Exact sciences and technology Food Science Fuels Loss modulus Materials Science Mechanical Engineering Organic chemistry Original Contribution Phase ratio Piping Polymer Sciences Quantitative analysis Rheological properties Rheology Saline water Soft and Granular Matter Viscoelasticity Viscosity Yield stress |
| title | Modelling and characterisation of diluted and concentrated water-in-crude oil emulsions: comparison with classical behaviour |
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