Viscoelasticity and morphology of polystyrene-block-poly[ethylene-co-(ethylene-propylene)]-block-polystyrene tri-block copolymer/paraffinic oil blends. 1. Effect of oil content
We have investigated the microdomain structure and viscoelastic properties of polystyrene- block -poly(ethylene-co-(ethylene-propylene)- block -polystyrene copolymer (SEEPS-1)/paraffinic oil (Oil-1) blends. The SAXS results revealed that, with increasing oil content, the structures change from a lam...
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| Veröffentlicht in: | Rheologica acta 2016-04, Vol.55 (4), p.293-301 |
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| creator | Aoki, Yuji Takahashi, Ryohei Nishitsuji, Shotaro Ishigami, Akira Koda, Tomonori Nishioka, Akihiro |
| description | We have investigated the microdomain structure and viscoelastic properties of polystyrene-
block
-poly(ethylene-co-(ethylene-propylene)-
block
-polystyrene copolymer (SEEPS-1)/paraffinic oil (Oil-1) blends. The SAXS results revealed that, with increasing oil content, the structures change from a lammelar microdomain for SEEPS-1/Oil-1 = 100/0 to a hexagonally packed cylindrical microdomain for SEEPS-1/Oil-1 = 75/25 blend, and furthermore change to a spherical microdomain packed in a cubic lattice for SEEPS-1/Oil-1 = 50/50 and 25/75 blends. SEEPS-1/Oil-1 = 100/0 and 75/25 blends held each same microdomain structure below 300 °C. In contrast, SEEPS-1/Oil-1 = 50/50 and 25/75 blends, respectively, exhibited order-disorder transition temperature (
T
ODT
) at 210–220 °C and 150–160 °C. Below
T
ODT
, the microdomain structures did not change. Corresponding to the SAXS observations, the viscoelastic responses showed that the dynamic storage modulus
G
′, respectively, is proportional to ω
1/2
, ω
1/4
∼ω
1/3
, and ω
0
at low frequencies for SEEPS-1/Oil-1 = 100/0, 75/25, and 50/50 and 25/75, indicating lamellar, cylindrical, and spherical microdomains The time-temperature superposition was applicable on the ordered state, and the activation energy obtained from the shift factors was roughly independent of blend composition (in other words, microdomain structure), suggesting that the viscoelastic responses are due to the presence of defects of long range order of microdomain structures. |
| doi_str_mv | 10.1007/s00397-016-0917-8 |
| format | Article |
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block
-poly(ethylene-co-(ethylene-propylene)-
block
-polystyrene copolymer (SEEPS-1)/paraffinic oil (Oil-1) blends. The SAXS results revealed that, with increasing oil content, the structures change from a lammelar microdomain for SEEPS-1/Oil-1 = 100/0 to a hexagonally packed cylindrical microdomain for SEEPS-1/Oil-1 = 75/25 blend, and furthermore change to a spherical microdomain packed in a cubic lattice for SEEPS-1/Oil-1 = 50/50 and 25/75 blends. SEEPS-1/Oil-1 = 100/0 and 75/25 blends held each same microdomain structure below 300 °C. In contrast, SEEPS-1/Oil-1 = 50/50 and 25/75 blends, respectively, exhibited order-disorder transition temperature (
T
ODT
) at 210–220 °C and 150–160 °C. Below
T
ODT
, the microdomain structures did not change. Corresponding to the SAXS observations, the viscoelastic responses showed that the dynamic storage modulus
G
′, respectively, is proportional to ω
1/2
, ω
1/4
∼ω
1/3
, and ω
0
at low frequencies for SEEPS-1/Oil-1 = 100/0, 75/25, and 50/50 and 25/75, indicating lamellar, cylindrical, and spherical microdomains The time-temperature superposition was applicable on the ordered state, and the activation energy obtained from the shift factors was roughly independent of blend composition (in other words, microdomain structure), suggesting that the viscoelastic responses are due to the presence of defects of long range order of microdomain structures.</description><identifier>ISSN: 0035-4511</identifier><identifier>EISSN: 1435-1528</identifier><identifier>DOI: 10.1007/s00397-016-0917-8</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Block copolymers ; Characterization and Evaluation of Materials ; Chemistry and Materials Science ; Complex Fluids and Microfluidics ; Cubic lattice ; Ethylene ; Food Science ; Long range order ; Materials Science ; Mechanical Engineering ; Morphology ; Order-disorder transformations ; Original Contribution ; Polymer blends ; Polymer Sciences ; Polystyrene resins ; Propylene ; Soft and Granular Matter ; Storage modulus ; Superposition (mathematics) ; Transition temperature ; Viscoelasticity</subject><ispartof>Rheologica acta, 2016-04, Vol.55 (4), p.293-301</ispartof><rights>Springer-Verlag Berlin Heidelberg 2016</rights><rights>Rheologica Acta is a copyright of Springer, (2016). All Rights Reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c353t-3ba7c16193a0569d0ea9796e930daea9f3d7e247363d3a455993e27935d0e1a23</citedby><cites>FETCH-LOGICAL-c353t-3ba7c16193a0569d0ea9796e930daea9f3d7e247363d3a455993e27935d0e1a23</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s00397-016-0917-8$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s00397-016-0917-8$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Aoki, Yuji</creatorcontrib><creatorcontrib>Takahashi, Ryohei</creatorcontrib><creatorcontrib>Nishitsuji, Shotaro</creatorcontrib><creatorcontrib>Ishigami, Akira</creatorcontrib><creatorcontrib>Koda, Tomonori</creatorcontrib><creatorcontrib>Nishioka, Akihiro</creatorcontrib><title>Viscoelasticity and morphology of polystyrene-block-poly[ethylene-co-(ethylene-propylene)]-block-polystyrene tri-block copolymer/paraffinic oil blends. 1. Effect of oil content</title><title>Rheologica acta</title><addtitle>Rheol Acta</addtitle><description>We have investigated the microdomain structure and viscoelastic properties of polystyrene-
block
-poly(ethylene-co-(ethylene-propylene)-
block
-polystyrene copolymer (SEEPS-1)/paraffinic oil (Oil-1) blends. The SAXS results revealed that, with increasing oil content, the structures change from a lammelar microdomain for SEEPS-1/Oil-1 = 100/0 to a hexagonally packed cylindrical microdomain for SEEPS-1/Oil-1 = 75/25 blend, and furthermore change to a spherical microdomain packed in a cubic lattice for SEEPS-1/Oil-1 = 50/50 and 25/75 blends. SEEPS-1/Oil-1 = 100/0 and 75/25 blends held each same microdomain structure below 300 °C. In contrast, SEEPS-1/Oil-1 = 50/50 and 25/75 blends, respectively, exhibited order-disorder transition temperature (
T
ODT
) at 210–220 °C and 150–160 °C. Below
T
ODT
, the microdomain structures did not change. Corresponding to the SAXS observations, the viscoelastic responses showed that the dynamic storage modulus
G
′, respectively, is proportional to ω
1/2
, ω
1/4
∼ω
1/3
, and ω
0
at low frequencies for SEEPS-1/Oil-1 = 100/0, 75/25, and 50/50 and 25/75, indicating lamellar, cylindrical, and spherical microdomains The time-temperature superposition was applicable on the ordered state, and the activation energy obtained from the shift factors was roughly independent of blend composition (in other words, microdomain structure), suggesting that the viscoelastic responses are due to the presence of defects of long range order of microdomain structures.</description><subject>Block copolymers</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry and Materials Science</subject><subject>Complex Fluids and Microfluidics</subject><subject>Cubic lattice</subject><subject>Ethylene</subject><subject>Food Science</subject><subject>Long range order</subject><subject>Materials Science</subject><subject>Mechanical Engineering</subject><subject>Morphology</subject><subject>Order-disorder transformations</subject><subject>Original Contribution</subject><subject>Polymer blends</subject><subject>Polymer Sciences</subject><subject>Polystyrene resins</subject><subject>Propylene</subject><subject>Soft and Granular Matter</subject><subject>Storage modulus</subject><subject>Superposition (mathematics)</subject><subject>Transition temperature</subject><subject>Viscoelasticity</subject><issn>0035-4511</issn><issn>1435-1528</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNp1UctOwzAQtBBIlMIHcLPEBQ5u_Yjj-oiq8pAqcQEuCFmu47QpaRxs95C_4hNxCAIuXNa7szNreweAc4InBGMxDRgzKRAmOcKSCDQ7ACOSMY4Ip7NDMEptjjJOyDE4CWGLMRG5oCPw8VwF42ytQ6xMFTuomwLunG83rnbrDroStq7uQuy8bSxa1c68oR55sXHT1T1mHLr8KVrv2q_s6vUP-VsOo68GFBrX4zvrp632uiyrpjLQVTVcJXERJpBM4KIsrYn9E_qGcU20TTwFR6Wugz37Psfg6WbxOL9Dy4fb-_n1EhnGWURspYUhOZFMY57LAlsthcytZLjQKS9ZISzNBMtZwXTGuZTMUiEZT1SiKRuDi2Fu-tH73oaotm7vm3SlojSnaYEpJhYZWMa7ELwtVeurnfadIlj1xqjBGJWMUb0xapY0dNCExG3W1v9O_l_0CdeblNM</recordid><startdate>20160401</startdate><enddate>20160401</enddate><creator>Aoki, Yuji</creator><creator>Takahashi, Ryohei</creator><creator>Nishitsuji, Shotaro</creator><creator>Ishigami, Akira</creator><creator>Koda, Tomonori</creator><creator>Nishioka, Akihiro</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>L6V</scope><scope>M7S</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>PTHSS</scope></search><sort><creationdate>20160401</creationdate><title>Viscoelasticity and morphology of polystyrene-block-poly[ethylene-co-(ethylene-propylene)]-block-polystyrene tri-block copolymer/paraffinic oil blends. 1. Effect of oil content</title><author>Aoki, Yuji ; Takahashi, Ryohei ; Nishitsuji, Shotaro ; Ishigami, Akira ; Koda, Tomonori ; Nishioka, Akihiro</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c353t-3ba7c16193a0569d0ea9796e930daea9f3d7e247363d3a455993e27935d0e1a23</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Block copolymers</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry and Materials Science</topic><topic>Complex Fluids and Microfluidics</topic><topic>Cubic lattice</topic><topic>Ethylene</topic><topic>Food Science</topic><topic>Long range order</topic><topic>Materials Science</topic><topic>Mechanical Engineering</topic><topic>Morphology</topic><topic>Order-disorder transformations</topic><topic>Original Contribution</topic><topic>Polymer blends</topic><topic>Polymer Sciences</topic><topic>Polystyrene resins</topic><topic>Propylene</topic><topic>Soft and Granular Matter</topic><topic>Storage modulus</topic><topic>Superposition (mathematics)</topic><topic>Transition temperature</topic><topic>Viscoelasticity</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Aoki, Yuji</creatorcontrib><creatorcontrib>Takahashi, Ryohei</creatorcontrib><creatorcontrib>Nishitsuji, Shotaro</creatorcontrib><creatorcontrib>Ishigami, Akira</creatorcontrib><creatorcontrib>Koda, Tomonori</creatorcontrib><creatorcontrib>Nishioka, Akihiro</creatorcontrib><collection>CrossRef</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>ProQuest Engineering Collection</collection><collection>Engineering Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>Engineering Collection</collection><jtitle>Rheologica acta</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Aoki, Yuji</au><au>Takahashi, Ryohei</au><au>Nishitsuji, Shotaro</au><au>Ishigami, Akira</au><au>Koda, Tomonori</au><au>Nishioka, Akihiro</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Viscoelasticity and morphology of polystyrene-block-poly[ethylene-co-(ethylene-propylene)]-block-polystyrene tri-block copolymer/paraffinic oil blends. 1. Effect of oil content</atitle><jtitle>Rheologica acta</jtitle><stitle>Rheol Acta</stitle><date>2016-04-01</date><risdate>2016</risdate><volume>55</volume><issue>4</issue><spage>293</spage><epage>301</epage><pages>293-301</pages><issn>0035-4511</issn><eissn>1435-1528</eissn><abstract>We have investigated the microdomain structure and viscoelastic properties of polystyrene-
block
-poly(ethylene-co-(ethylene-propylene)-
block
-polystyrene copolymer (SEEPS-1)/paraffinic oil (Oil-1) blends. The SAXS results revealed that, with increasing oil content, the structures change from a lammelar microdomain for SEEPS-1/Oil-1 = 100/0 to a hexagonally packed cylindrical microdomain for SEEPS-1/Oil-1 = 75/25 blend, and furthermore change to a spherical microdomain packed in a cubic lattice for SEEPS-1/Oil-1 = 50/50 and 25/75 blends. SEEPS-1/Oil-1 = 100/0 and 75/25 blends held each same microdomain structure below 300 °C. In contrast, SEEPS-1/Oil-1 = 50/50 and 25/75 blends, respectively, exhibited order-disorder transition temperature (
T
ODT
) at 210–220 °C and 150–160 °C. Below
T
ODT
, the microdomain structures did not change. Corresponding to the SAXS observations, the viscoelastic responses showed that the dynamic storage modulus
G
′, respectively, is proportional to ω
1/2
, ω
1/4
∼ω
1/3
, and ω
0
at low frequencies for SEEPS-1/Oil-1 = 100/0, 75/25, and 50/50 and 25/75, indicating lamellar, cylindrical, and spherical microdomains The time-temperature superposition was applicable on the ordered state, and the activation energy obtained from the shift factors was roughly independent of blend composition (in other words, microdomain structure), suggesting that the viscoelastic responses are due to the presence of defects of long range order of microdomain structures.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s00397-016-0917-8</doi><tpages>9</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0035-4511 |
| ispartof | Rheologica acta, 2016-04, Vol.55 (4), p.293-301 |
| issn | 0035-4511 1435-1528 |
| language | eng |
| recordid | cdi_proquest_journals_2262001262 |
| source | SpringerNature Journals |
| subjects | Block copolymers Characterization and Evaluation of Materials Chemistry and Materials Science Complex Fluids and Microfluidics Cubic lattice Ethylene Food Science Long range order Materials Science Mechanical Engineering Morphology Order-disorder transformations Original Contribution Polymer blends Polymer Sciences Polystyrene resins Propylene Soft and Granular Matter Storage modulus Superposition (mathematics) Transition temperature Viscoelasticity |
| title | Viscoelasticity and morphology of polystyrene-block-poly[ethylene-co-(ethylene-propylene)]-block-polystyrene tri-block copolymer/paraffinic oil blends. 1. Effect of oil content |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-04T05%3A31%3A03IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Viscoelasticity%20and%20morphology%20of%20polystyrene-block-poly%5Bethylene-co-(ethylene-propylene)%5D-block-polystyrene%20tri-block%20copolymer/paraffinic%20oil%20blends.%201.%20Effect%20of%20oil%20content&rft.jtitle=Rheologica%20acta&rft.au=Aoki,%20Yuji&rft.date=2016-04-01&rft.volume=55&rft.issue=4&rft.spage=293&rft.epage=301&rft.pages=293-301&rft.issn=0035-4511&rft.eissn=1435-1528&rft_id=info:doi/10.1007/s00397-016-0917-8&rft_dat=%3Cproquest_cross%3E2262001262%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2262001262&rft_id=info:pmid/&rfr_iscdi=true |