Phase behavior and effects of microstructure on viscoelastic properties of a series of polylactides and polylactide/poly(ε-caprolactone) copolymers

Dynamic viscoelastic measurements were combined with differential scanning calorimetry (DSC) and atomic force microscopy (AFM) analysis to investigate the rheology, phase structure, and morphology of poly( l -lactide) (PLLA), poly(ε-caprolactone) (PCL), poly( d , l -lactide) (PDLLA) with molar compo...

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Veröffentlicht in:	Rheologica acta 2014-11, Vol.53 (10-11), p.857-868
Hauptverfasser:	Ugartemendia, Jone M., Muñoz, Maria E., Sarasua, Jose R., Santamaria, Anton
Format:	Artikel
Sprache:	eng
Schlagworte:	Atomic force microscopy Chain entanglement Chains Characterization and Evaluation of Materials Chemistry and Materials Science Complex Fluids and Microfluidics Composition Copolymers Dependence Entanglement Food Science Loss modulus Materials Science Mechanical Engineering Medical devices Medical electronics Melting points Melts Microstructure Modulus of elasticity Morphology Original Contribution Polycaprolactone Polylactic acid Polymer Sciences Reptation Rheological properties Rheology Soft and Granular Matter Solid phases Superposition (mathematics) Thermal degradation Viscoelasticity
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