Investigation of the synergic effect of silver on the photodegradation behavior of copper chromite nanostructures

Pure copper chromite nanoparticles were prepared through an efficient route using copper nitrate and chromium nitrate. For the first time, various amino acids were employed as capping agents in the presence of propylene glycol and ethylene glycol in order to prepare these nanostructures. A number of...

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Veröffentlicht in:Journal of materials science. Materials in electronics 2019-08, Vol.30 (15), p.13994-14006
Hauptverfasser: Abbasi, Ali, Keihan, Amir Homayoun, Rahimi-Nasrabadi, Mehdi, Wysokowski, Marcin, Jesionowski, Teofil, Joseph, Yvonne, Ehrlich, Hermann, Sajadi, Seyed Milad Safar
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container_end_page 14006
container_issue 15
container_start_page 13994
container_title Journal of materials science. Materials in electronics
container_volume 30
creator Abbasi, Ali
Keihan, Amir Homayoun
Rahimi-Nasrabadi, Mehdi
Wysokowski, Marcin
Jesionowski, Teofil
Joseph, Yvonne
Ehrlich, Hermann
Sajadi, Seyed Milad Safar
description Pure copper chromite nanoparticles were prepared through an efficient route using copper nitrate and chromium nitrate. For the first time, various amino acids were employed as capping agents in the presence of propylene glycol and ethylene glycol in order to prepare these nanostructures. A number of experiments were performed to examine the effect of stabilization agents, alkaline agents and connecting agents on the shape, grain size and photodegradation behavior of CuCr 2 O 4 . The results showed that the type of stabilization agent and reducing agent creates numerous changes in terms of the size and photocatalytic performance of copper chromite. The effects of several factors, including the type of pollutant, grain size of CuCr 2 O 4 nanostructures, pH and dosage of dye, on the photocatalytic behavior of copper chromite nanostructure were evaluated. Solutions of methylene blue, methyl orange and rhodamine B were employed as model contaminants. The maximum photocatalytic activity of the CuCr 2 O 4 nanostructure was achieved for the rhodamine B contaminant under UV irradiation. When the CuCr 2 O 4 /Ag nanostructure was used instead of CuCr 2 O 4 nanoparticles, the photocatalytic activity during the degradation of rhodamine B increased from 76 to 91%.
doi_str_mv 10.1007/s10854-019-01750-x
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subjects Amino acids
Catalytic activity
Characterization and Evaluation of Materials
Chemistry and Materials Science
Chromite
Chromium
Contaminants
Copper
Dyes
Ethylene glycol
Grain size
Materials Science
Methylene blue
Nanoparticles
Nanostructure
Optical and Electronic Materials
Photocatalysis
Photodegradation
Propylene
Reducing agents
Rhodamine
Silver
Stabilization
Ultraviolet radiation
title Investigation of the synergic effect of silver on the photodegradation behavior of copper chromite nanostructures
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