Green, Efficient and Reusable Bis(imidazolium) Ionic Liquids Promoted Pd-Catalyzed Aqueous Suzuki Reaction for Organic Functional Materials

Glucopyranoside-substituted asymmetric bis(imidazolium) ionic liquids were used to promote environmentally friendly, efficient and reusable Pd-catalyzed Suzuki reaction between arylboronic acids and 2-bromofluorene, 2,7-dibromo-9,9′-dialkylfluorene. Over 30 carbazole-based fluorene core potential or...

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Veröffentlicht in:Catalysis letters 2018-09, Vol.148 (9), p.2696-2702
Hauptverfasser: Zhou, Zhonggao, Yuan, Yangyang, Xie, Yongrong, Li, Mei
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container_title Catalysis letters
container_volume 148
creator Zhou, Zhonggao
Yuan, Yangyang
Xie, Yongrong
Li, Mei
description Glucopyranoside-substituted asymmetric bis(imidazolium) ionic liquids were used to promote environmentally friendly, efficient and reusable Pd-catalyzed Suzuki reaction between arylboronic acids and 2-bromofluorene, 2,7-dibromo-9,9′-dialkylfluorene. Over 30 carbazole-based fluorene core potential organic functional materials were synthesized. In addition, recyclability of catalyst system was inspected on the Suzuki reaction observing nearly no loss in catalytic activity up to five cycles. Graphical Abstract Development of green, efficient and recycle glucopyranoside substituted bis(imidazolium) ILs promoted Pd-catalyzed aqueous Suzuki reaction for OFMs.
doi_str_mv 10.1007/s10562-018-2452-y
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subjects Carbazoles
Catalysis
Catalytic activity
Chemical reactions
Chemical synthesis
Chemistry
Chemistry and Materials Science
Functional materials
Industrial Chemistry/Chemical Engineering
Ionic liquids
Ions
LEDs
Organometallic Chemistry
Palladium
Physical Chemistry
Recyclability
Solvents
Substitutes
Substitution reactions
Sustainable development
title Green, Efficient and Reusable Bis(imidazolium) Ionic Liquids Promoted Pd-Catalyzed Aqueous Suzuki Reaction for Organic Functional Materials
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