Characteristics of thin cellulose ester films spin-coated from acetone and ethyl acetate solutions
Spin-coated films of cellulose acetate (CA), cellulose acetate propionate (CAP), cellulose acetate butyrate (CAB) and carboxymethylcellulose acetate butyrate (CMCAB) have been characterized by ellipsometry, atomic force microscopy (AFM) and contact angle measurements. The films were spin-coated onto...
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| Veröffentlicht in: | Cellulose (London) 2008-08, Vol.15 (4), p.527-535 |
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| creator | Amim, J. Jr Kosaka, P. M Petri, D. F. S |
| description | Spin-coated films of cellulose acetate (CA), cellulose acetate propionate (CAP), cellulose acetate butyrate (CAB) and carboxymethylcellulose acetate butyrate (CMCAB) have been characterized by ellipsometry, atomic force microscopy (AFM) and contact angle measurements. The films were spin-coated onto silicon wafers, a polar surface. Mean thickness values were determined by means of ellipsometry and AFM as a function of polymer concentration in solutions prepared either in acetone or in ethyl acetate (EA), both are good solvents for the cellulose esters. The results were discussed in the light of solvent evaporation rate and interaction energy between substrate and solvent. The effects of annealing and type of cellulose ester on film thickness, film morphology, surface roughness and surface wettability were also investigated. |
| doi_str_mv | 10.1007/s10570-008-9213-9 |
| format | Article |
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The effects of annealing and type of cellulose ester on film thickness, film morphology, surface roughness and surface wettability were also investigated.</description><identifier>ISSN: 0969-0239</identifier><identifier>EISSN: 1572-882X</identifier><identifier>DOI: 10.1007/s10570-008-9213-9</identifier><language>eng</language><publisher>Dordrecht: Dordrecht : Springer Netherlands</publisher><subject>Acetone ; Atomic force microscopy ; Bioorganic Chemistry ; Cellulose acetate ; Cellulose acetate butyrates ; Cellulose esters ; Cellulose propionates ; Ceramics ; Chemistry ; Chemistry and Materials Science ; Composites ; Contact angle ; Ellipsometry ; Esters ; Ethyl acetate ; Evaporation ; Evaporation rate ; Film thickness ; Glass ; Morphology ; Natural Materials ; Organic Chemistry ; Physical Chemistry ; Polymer Sciences ; Silicon wafers ; Solvents ; Spin coating ; Substrates ; Surface roughness ; Sustainable Development ; Thin films ; Wettability</subject><ispartof>Cellulose (London), 2008-08, Vol.15 (4), p.527-535</ispartof><rights>Springer Science+Business Media B.V. 2008</rights><rights>Cellulose is a copyright of Springer, (2008). All Rights Reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c406t-e8e2c4b8e91a734b85d6739594a185a5a8bc956c5e3f11045d57265a090f90403</citedby><cites>FETCH-LOGICAL-c406t-e8e2c4b8e91a734b85d6739594a185a5a8bc956c5e3f11045d57265a090f90403</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10570-008-9213-9$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10570-008-9213-9$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Amim, J. Jr</creatorcontrib><creatorcontrib>Kosaka, P. M</creatorcontrib><creatorcontrib>Petri, D. F. S</creatorcontrib><title>Characteristics of thin cellulose ester films spin-coated from acetone and ethyl acetate solutions</title><title>Cellulose (London)</title><addtitle>Cellulose</addtitle><description>Spin-coated films of cellulose acetate (CA), cellulose acetate propionate (CAP), cellulose acetate butyrate (CAB) and carboxymethylcellulose acetate butyrate (CMCAB) have been characterized by ellipsometry, atomic force microscopy (AFM) and contact angle measurements. The films were spin-coated onto silicon wafers, a polar surface. Mean thickness values were determined by means of ellipsometry and AFM as a function of polymer concentration in solutions prepared either in acetone or in ethyl acetate (EA), both are good solvents for the cellulose esters. The results were discussed in the light of solvent evaporation rate and interaction energy between substrate and solvent. The effects of annealing and type of cellulose ester on film thickness, film morphology, surface roughness and surface wettability were also investigated.</description><subject>Acetone</subject><subject>Atomic force microscopy</subject><subject>Bioorganic Chemistry</subject><subject>Cellulose acetate</subject><subject>Cellulose acetate butyrates</subject><subject>Cellulose esters</subject><subject>Cellulose propionates</subject><subject>Ceramics</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Composites</subject><subject>Contact angle</subject><subject>Ellipsometry</subject><subject>Esters</subject><subject>Ethyl acetate</subject><subject>Evaporation</subject><subject>Evaporation rate</subject><subject>Film thickness</subject><subject>Glass</subject><subject>Morphology</subject><subject>Natural Materials</subject><subject>Organic Chemistry</subject><subject>Physical Chemistry</subject><subject>Polymer Sciences</subject><subject>Silicon wafers</subject><subject>Solvents</subject><subject>Spin coating</subject><subject>Substrates</subject><subject>Surface roughness</subject><subject>Sustainable Development</subject><subject>Thin films</subject><subject>Wettability</subject><issn>0969-0239</issn><issn>1572-882X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2008</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNp9kE1LAzEQhoMoWKs_wJMBz9FJstlNjlL8goIHLXgLaZq0W7abmmQP_nvTruDN0wwz7zsfD0LXFO4oQHOfKIgGCIAkilFO1AmaUNEwIiX7PEUTULUiwLg6RxcpbQFANYxO0HK2MdHY7GKbcmsTDh7nTdtj67pu6EJy2KXSxb7tdgmnfdsTG0x2K-xj2GFjXQ69w6ZfYZc3392xUvo4hW7IbejTJTrzpkvu6jdO0eLp8WP2QuZvz6-zhzmxFdSZOOmYrZbSKWoaXhKxqhuuhKoMlcIII5dWidoKxz2lUIlVea8WBhR4BRXwKbod5-5j-BrK1XobhtiXlZoxoRQocVTRUWVjSCk6r_ex3Zn4rSnoA0o9otQFpT6g1Kp42OhJRduvXfyb_J_pZjR5E7RZF7568c6A8oIeJK8p_wFpwn_3</recordid><startdate>20080801</startdate><enddate>20080801</enddate><creator>Amim, J. 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S</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c406t-e8e2c4b8e91a734b85d6739594a185a5a8bc956c5e3f11045d57265a090f90403</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2008</creationdate><topic>Acetone</topic><topic>Atomic force microscopy</topic><topic>Bioorganic Chemistry</topic><topic>Cellulose acetate</topic><topic>Cellulose acetate butyrates</topic><topic>Cellulose esters</topic><topic>Cellulose propionates</topic><topic>Ceramics</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Composites</topic><topic>Contact angle</topic><topic>Ellipsometry</topic><topic>Esters</topic><topic>Ethyl acetate</topic><topic>Evaporation</topic><topic>Evaporation rate</topic><topic>Film thickness</topic><topic>Glass</topic><topic>Morphology</topic><topic>Natural Materials</topic><topic>Organic Chemistry</topic><topic>Physical Chemistry</topic><topic>Polymer Sciences</topic><topic>Silicon wafers</topic><topic>Solvents</topic><topic>Spin coating</topic><topic>Substrates</topic><topic>Surface roughness</topic><topic>Sustainable Development</topic><topic>Thin films</topic><topic>Wettability</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Amim, J. 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Jr</au><au>Kosaka, P. M</au><au>Petri, D. F. S</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Characteristics of thin cellulose ester films spin-coated from acetone and ethyl acetate solutions</atitle><jtitle>Cellulose (London)</jtitle><stitle>Cellulose</stitle><date>2008-08-01</date><risdate>2008</risdate><volume>15</volume><issue>4</issue><spage>527</spage><epage>535</epage><pages>527-535</pages><issn>0969-0239</issn><eissn>1572-882X</eissn><abstract>Spin-coated films of cellulose acetate (CA), cellulose acetate propionate (CAP), cellulose acetate butyrate (CAB) and carboxymethylcellulose acetate butyrate (CMCAB) have been characterized by ellipsometry, atomic force microscopy (AFM) and contact angle measurements. The films were spin-coated onto silicon wafers, a polar surface. 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| subjects | Acetone Atomic force microscopy Bioorganic Chemistry Cellulose acetate Cellulose acetate butyrates Cellulose esters Cellulose propionates Ceramics Chemistry Chemistry and Materials Science Composites Contact angle Ellipsometry Esters Ethyl acetate Evaporation Evaporation rate Film thickness Glass Morphology Natural Materials Organic Chemistry Physical Chemistry Polymer Sciences Silicon wafers Solvents Spin coating Substrates Surface roughness Sustainable Development Thin films Wettability |
| title | Characteristics of thin cellulose ester films spin-coated from acetone and ethyl acetate solutions |
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