Dynamic monitoring of thermally assisted assembly of colloidal crystals
The dynamic monitor is considerably valuable to thoroughly understand the self-assembly process and is beneficial for the effective control of ordered colloidal crystal. In this study, the three-dimensional ordered colloidal crystals are fabricated through thermally assisted self-assembly, which are...
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| Veröffentlicht in: | Journal of materials science 2017-07, Vol.52 (13), p.7883-7892 |
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| container_issue | 13 |
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| container_title | Journal of materials science |
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| creator | Liu, Fangfang Xiu, Jinghai Tang, Bingtao Zhao, Defeng Zhang, Shufen |
| description | The dynamic monitor is considerably valuable to thoroughly understand the self-assembly process and is beneficial for the effective control of ordered colloidal crystal. In this study, the three-dimensional ordered colloidal crystals are fabricated through thermally assisted self-assembly, which are in situ monitored by fiber-optic spectrometer and micro-digital technology. The assembly process occurs layer by layer from top to bottom. The evaporated water-dragged microspheres assemble into the final close-packing face-centered cubic arrangement. During self-assembly, water between microspheres is gradually replaced by air, resulting in the change of effective refractive index, as well as evident color change and blue shifting of wavelength peaks. The effect of self-assembly temperature (60, 70, 80, and 90 °C) and polystyrene microspheres concentration (4, 6, 8, and 10 wt%) are both investigated on the basis of dynamic monitoring of the thermally assisted assembly of colloidal crystal structural color. As confirmed, the emulsion of 10% mass fraction self-assembled at 70 °C can obtain a superior color film structure. |
| doi_str_mv | 10.1007/s10853-017-1061-2 |
| format | Article |
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In this study, the three-dimensional ordered colloidal crystals are fabricated through thermally assisted self-assembly, which are in situ monitored by fiber-optic spectrometer and micro-digital technology. The assembly process occurs layer by layer from top to bottom. The evaporated water-dragged microspheres assemble into the final close-packing face-centered cubic arrangement. During self-assembly, water between microspheres is gradually replaced by air, resulting in the change of effective refractive index, as well as evident color change and blue shifting of wavelength peaks. The effect of self-assembly temperature (60, 70, 80, and 90 °C) and polystyrene microspheres concentration (4, 6, 8, and 10 wt%) are both investigated on the basis of dynamic monitoring of the thermally assisted assembly of colloidal crystal structural color. As confirmed, the emulsion of 10% mass fraction self-assembled at 70 °C can obtain a superior color film structure.</description><identifier>ISSN: 0022-2461</identifier><identifier>EISSN: 1573-4803</identifier><identifier>DOI: 10.1007/s10853-017-1061-2</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Characterization and Evaluation of Materials ; Chemistry and Materials Science ; Classical Mechanics ; Colloiding ; Color ; Crystal structure ; Crystallography and Scattering Methods ; Fiber optics ; Materials Science ; Microspheres ; Monitoring ; Optical fibers ; Polymer Sciences ; Polymers ; Polystyrene resins ; Refractivity ; Self-assembly ; Solid Mechanics</subject><ispartof>Journal of materials science, 2017-07, Vol.52 (13), p.7883-7892</ispartof><rights>Springer Science+Business Media New York 2017</rights><rights>COPYRIGHT 2017 Springer</rights><rights>Journal of Materials Science is a copyright of Springer, (2017). 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In this study, the three-dimensional ordered colloidal crystals are fabricated through thermally assisted self-assembly, which are in situ monitored by fiber-optic spectrometer and micro-digital technology. The assembly process occurs layer by layer from top to bottom. The evaporated water-dragged microspheres assemble into the final close-packing face-centered cubic arrangement. During self-assembly, water between microspheres is gradually replaced by air, resulting in the change of effective refractive index, as well as evident color change and blue shifting of wavelength peaks. The effect of self-assembly temperature (60, 70, 80, and 90 °C) and polystyrene microspheres concentration (4, 6, 8, and 10 wt%) are both investigated on the basis of dynamic monitoring of the thermally assisted assembly of colloidal crystal structural color. As confirmed, the emulsion of 10% mass fraction self-assembled at 70 °C can obtain a superior color film structure.</description><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry and Materials Science</subject><subject>Classical Mechanics</subject><subject>Colloiding</subject><subject>Color</subject><subject>Crystal structure</subject><subject>Crystallography and Scattering Methods</subject><subject>Fiber optics</subject><subject>Materials Science</subject><subject>Microspheres</subject><subject>Monitoring</subject><subject>Optical fibers</subject><subject>Polymer Sciences</subject><subject>Polymers</subject><subject>Polystyrene resins</subject><subject>Refractivity</subject><subject>Self-assembly</subject><subject>Solid Mechanics</subject><issn>0022-2461</issn><issn>1573-4803</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><sourceid>BENPR</sourceid><recordid>eNp1kU1LwzAYx4MoOKcfwFvBk4fOJ8mStMcxdQoDwZdzyNJkdrTNTDKw396UCrKD5PCEJ79f3v4IXWOYYQBxFzAUjOaARY6B45ycoAlmgubzAugpmgAQkpM5x-foIoQdADBB8ASt7vtOtbXOWtfV0fm622bOZvHT-FY1TZ-pEOoQTTVMTLtJnbSsXdO4ulJNpn0fomrCJTqzqZir3zpFH48P78unfP2yel4u1rmmRRlzbitjtC43SlScAGwUs9iSqtSYMSM2vDRgaEE4CAyWk4IzCqqkDEiprBV0im7GfffefR1MiHLnDr5LR0pCWMlpMS9womYjtVWNkXVnXfRKp1GZ9FbXGVun_oIxKBlmlCfh9khITDTfcasOIcjnt9djFo-s9i4Eb6zc-7pVvpcY5BCGHMOQKQw5hCFJcsjohP3wxcb_Xft_6QdQ-osr</recordid><startdate>20170701</startdate><enddate>20170701</enddate><creator>Liu, Fangfang</creator><creator>Xiu, Jinghai</creator><creator>Tang, Bingtao</creator><creator>Zhao, Defeng</creator><creator>Zhang, Shufen</creator><general>Springer US</general><general>Springer</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>ISR</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>L6V</scope><scope>M7S</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>PTHSS</scope></search><sort><creationdate>20170701</creationdate><title>Dynamic monitoring of thermally assisted assembly of colloidal crystals</title><author>Liu, Fangfang ; Xiu, Jinghai ; Tang, Bingtao ; Zhao, Defeng ; Zhang, Shufen</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c389t-6fdeecc9ba7d6200ba5f1f2d9c155e7b69e0e38260710f6286530a935029aff73</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry and Materials Science</topic><topic>Classical Mechanics</topic><topic>Colloiding</topic><topic>Color</topic><topic>Crystal structure</topic><topic>Crystallography and Scattering Methods</topic><topic>Fiber optics</topic><topic>Materials Science</topic><topic>Microspheres</topic><topic>Monitoring</topic><topic>Optical fibers</topic><topic>Polymer Sciences</topic><topic>Polymers</topic><topic>Polystyrene resins</topic><topic>Refractivity</topic><topic>Self-assembly</topic><topic>Solid Mechanics</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Liu, Fangfang</creatorcontrib><creatorcontrib>Xiu, Jinghai</creatorcontrib><creatorcontrib>Tang, Bingtao</creatorcontrib><creatorcontrib>Zhao, Defeng</creatorcontrib><creatorcontrib>Zhang, Shufen</creatorcontrib><collection>CrossRef</collection><collection>Gale In Context: Science</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>ProQuest Engineering Collection</collection><collection>Engineering Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>Engineering Collection</collection><jtitle>Journal of materials science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Liu, Fangfang</au><au>Xiu, Jinghai</au><au>Tang, Bingtao</au><au>Zhao, Defeng</au><au>Zhang, Shufen</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Dynamic monitoring of thermally assisted assembly of colloidal crystals</atitle><jtitle>Journal of materials science</jtitle><stitle>J Mater Sci</stitle><date>2017-07-01</date><risdate>2017</risdate><volume>52</volume><issue>13</issue><spage>7883</spage><epage>7892</epage><pages>7883-7892</pages><issn>0022-2461</issn><eissn>1573-4803</eissn><abstract>The dynamic monitor is considerably valuable to thoroughly understand the self-assembly process and is beneficial for the effective control of ordered colloidal crystal. In this study, the three-dimensional ordered colloidal crystals are fabricated through thermally assisted self-assembly, which are in situ monitored by fiber-optic spectrometer and micro-digital technology. The assembly process occurs layer by layer from top to bottom. The evaporated water-dragged microspheres assemble into the final close-packing face-centered cubic arrangement. During self-assembly, water between microspheres is gradually replaced by air, resulting in the change of effective refractive index, as well as evident color change and blue shifting of wavelength peaks. The effect of self-assembly temperature (60, 70, 80, and 90 °C) and polystyrene microspheres concentration (4, 6, 8, and 10 wt%) are both investigated on the basis of dynamic monitoring of the thermally assisted assembly of colloidal crystal structural color. As confirmed, the emulsion of 10% mass fraction self-assembled at 70 °C can obtain a superior color film structure.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10853-017-1061-2</doi><tpages>10</tpages></addata></record> |
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| subjects | Characterization and Evaluation of Materials Chemistry and Materials Science Classical Mechanics Colloiding Color Crystal structure Crystallography and Scattering Methods Fiber optics Materials Science Microspheres Monitoring Optical fibers Polymer Sciences Polymers Polystyrene resins Refractivity Self-assembly Solid Mechanics |
| title | Dynamic monitoring of thermally assisted assembly of colloidal crystals |
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