Morphology, composition and electrochemistry of a nano-porous silicon versus bulk silicon anode for lithium-ion batteries
The volumetric energy density of today’s lithium-ion batteries is limited mostly by the graphitic carbon anode. Silicon is a promising replacement but its excessive volume expansion on lithiation limits its long-term cyclability performance. A nano-sized aluminium containing silicon, leached in acid...
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| Veröffentlicht in: | Journal of materials science 2017-04, Vol.52 (7), p.3670-3677 |
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| creator | Jiang, Tianchan Zhang, Ruibo Yin, Qiyue Zhou, Wenchao Dong, Zhixin Chernova, Natasha A. Wang, Qi Omenya, Fredrick Whittingham, M. Stanley |
| description | The volumetric energy density of today’s lithium-ion batteries is limited mostly by the graphitic carbon anode. Silicon is a promising replacement but its excessive volume expansion on lithiation limits its long-term cyclability performance. A nano-sized aluminium containing silicon, leached in acid, with a porous structure is shown to maintain its capacity higher than pure bulk silicon or nano-sized silicon by over 700 mAh/g. The capacity of leached silicon is maintained at 1400 mAh/g for more than 60 cycles. X-ray diffraction, scanning electron microscopy, transmission electron microscopy and nuclear magnetic resonance spectroscopy have been used to correlate the electrochemical performance with the materials' morphology and composition. |
| doi_str_mv | 10.1007/s10853-016-0599-8 |
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All Rights Reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c430t-1a48f942a14b65c72570b3e2a653e02267e0719b3ed96dc4265ede39849ee3403</citedby><cites>FETCH-LOGICAL-c430t-1a48f942a14b65c72570b3e2a653e02267e0719b3ed96dc4265ede39849ee3403</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10853-016-0599-8$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10853-016-0599-8$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Jiang, Tianchan</creatorcontrib><creatorcontrib>Zhang, Ruibo</creatorcontrib><creatorcontrib>Yin, Qiyue</creatorcontrib><creatorcontrib>Zhou, Wenchao</creatorcontrib><creatorcontrib>Dong, Zhixin</creatorcontrib><creatorcontrib>Chernova, Natasha A.</creatorcontrib><creatorcontrib>Wang, Qi</creatorcontrib><creatorcontrib>Omenya, Fredrick</creatorcontrib><creatorcontrib>Whittingham, M. Stanley</creatorcontrib><title>Morphology, composition and electrochemistry of a nano-porous silicon versus bulk silicon anode for lithium-ion batteries</title><title>Journal of materials science</title><addtitle>J Mater Sci</addtitle><description>The volumetric energy density of today’s lithium-ion batteries is limited mostly by the graphitic carbon anode. Silicon is a promising replacement but its excessive volume expansion on lithiation limits its long-term cyclability performance. A nano-sized aluminium containing silicon, leached in acid, with a porous structure is shown to maintain its capacity higher than pure bulk silicon or nano-sized silicon by over 700 mAh/g. The capacity of leached silicon is maintained at 1400 mAh/g for more than 60 cycles. X-ray diffraction, scanning electron microscopy, transmission electron microscopy and nuclear magnetic resonance spectroscopy have been used to correlate the electrochemical performance with the materials' morphology and composition.</description><subject>Aluminum</subject><subject>Anodes</subject><subject>Batteries</subject><subject>Batteries and Supercapacitors</subject><subject>Bulk density</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry and Materials Science</subject><subject>Classical Mechanics</subject><subject>Composition</subject><subject>Crystallography and Scattering Methods</subject><subject>Electrochemical analysis</subject><subject>Electrochemical reactions</subject><subject>Electrochemistry</subject><subject>Flux density</subject><subject>Lithium</subject><subject>Lithium-ion batteries</subject><subject>Materials Science</subject><subject>Microscopy</subject><subject>Morphology</subject><subject>NMR</subject><subject>Nuclear magnetic resonance</subject><subject>Nuclear magnetic resonance spectroscopy</subject><subject>Polymer Sciences</subject><subject>Porous silicon</subject><subject>Rechargeable batteries</subject><subject>Scanning electron microscopy</subject><subject>Silicon</subject><subject>Solid Mechanics</subject><subject>Transmission electron microscopy</subject><subject>X-ray diffraction</subject><issn>0022-2461</issn><issn>1573-4803</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNp1kV9LHDEUxUOp0FX7AfoW6JNgNP9n8ihSrWApVPscspk7u7GzkzHJiPvtm2VKiw8lDyGH37k3h4PQJ0YvGKXNZWa0VYJQpglVxpD2HVox1QgiWyreoxWlnBMuNfuAjnN-opSqhrMV2n-LadrGIW7259jH3RRzKCGO2I0dhgF8SdFvYRdySXsce-zw6MZIppjinHEOQ_CVfoGU63M9D7_-ahXrAPcx4SGUbZh35DB37UqBFCCfoqPeDRk-_rlP0M-bL4_XX8n999u766t74qWghTAn295I7phca-Ubrhq6FsCdVgJqKN0AbZipUmd05yXXCjoQppUGQEgqTtDnZe6U4vMMudinOKexrrScK6OFbLWp1MVCbdwANox9LMn5erqavaaBPlT9ShrRMCbbg-HsjaEyBV7Lxs0527uHH29ZtrA-xZwT9HZKYefS3jJqD_XZpT5b67OH-mxbPXzx5MqOG0j_vv1_029gN52r</recordid><startdate>20170401</startdate><enddate>20170401</enddate><creator>Jiang, Tianchan</creator><creator>Zhang, Ruibo</creator><creator>Yin, Qiyue</creator><creator>Zhou, Wenchao</creator><creator>Dong, Zhixin</creator><creator>Chernova, Natasha A.</creator><creator>Wang, Qi</creator><creator>Omenya, Fredrick</creator><creator>Whittingham, M. 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| subjects | Aluminum Anodes Batteries Batteries and Supercapacitors Bulk density Characterization and Evaluation of Materials Chemistry and Materials Science Classical Mechanics Composition Crystallography and Scattering Methods Electrochemical analysis Electrochemical reactions Electrochemistry Flux density Lithium Lithium-ion batteries Materials Science Microscopy Morphology NMR Nuclear magnetic resonance Nuclear magnetic resonance spectroscopy Polymer Sciences Porous silicon Rechargeable batteries Scanning electron microscopy Silicon Solid Mechanics Transmission electron microscopy X-ray diffraction |
| title | Morphology, composition and electrochemistry of a nano-porous silicon versus bulk silicon anode for lithium-ion batteries |
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