Influence of blending zwitterionic functionalized titanium nanotubes on flux and anti-fouling performance of polyamide nanofiltration membranes
Organic–inorganic hybrid membranes represent an efficient approach to construct membranes with both improved membrane flux and solute selectivity. Zwitterions bearing equimolar number of anions and cations in one monomer unit exhibit excellent anti-fouling characteristics. Based on the exceptional s...
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Veröffentlicht in: | Journal of materials science 2018-07, Vol.53 (14), p.10499-10512 |
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container_issue | 14 |
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container_title | Journal of materials science |
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creator | Wang, Chongbin Li, Zhiyuan Chen, Jianxin Zhong, Yunlong Ren, Liang Pu, Yunping Dong, Zhipeng Wu, Hong |
description | Organic–inorganic hybrid membranes represent an efficient approach to construct membranes with both improved membrane flux and solute selectivity. Zwitterions bearing equimolar number of anions and cations in one monomer unit exhibit excellent anti-fouling characteristics. Based on the exceptional separation performance of hybrid membrane and fouling resistance feature of zwitterions, a novel nanofiltration membrane was fabricated by incorporating zwitterionic functionalized titanium nanotubes (z-TNTs) into polyamide (PA) layer. The special tubular structure of z-TNTs can provide more and shorter internal channels to shorten flow lanes for water molecules. The zwitterionic functionalization on the titanium nanotubes surface improved not only the interfacial compatibility between nano-materials and polymer matrix but also the antifouling performance of membranes. The water flux of membrane prepared with z-TNTs was up to 220 L m
−2
h
−1
MPa
−1
while the Na
2
SO
4
rejection remained above 90%. The as-prepared z-TNTs/PA membrane exhibited improved anti-fouling property against protein with a notably reduced flux decline ratio. |
doi_str_mv | 10.1007/s10853-018-2288-2 |
format | Article |
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−2
h
−1
MPa
−1
while the Na
2
SO
4
rejection remained above 90%. The as-prepared z-TNTs/PA membrane exhibited improved anti-fouling property against protein with a notably reduced flux decline ratio.</description><identifier>ISSN: 0022-2461</identifier><identifier>EISSN: 1573-4803</identifier><identifier>DOI: 10.1007/s10853-018-2288-2</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Antifouling ; Characterization and Evaluation of Materials ; Chemistry and Materials Science ; Classical Mechanics ; Crystallography and Scattering Methods ; Flux ; Materials Science ; Membranes ; Nanofiltration ; Nanotubes ; Paths ; Polyamide resins ; Polyamides ; Polymer Sciences ; Polymers ; Selectivity ; Sodium sulfate ; Solid Mechanics ; Surface active agents ; Titanium ; Water chemistry ; Zwitterions</subject><ispartof>Journal of materials science, 2018-07, Vol.53 (14), p.10499-10512</ispartof><rights>Springer Science+Business Media, LLC, part of Springer Nature 2018</rights><rights>COPYRIGHT 2018 Springer</rights><rights>Journal of Materials Science is a copyright of Springer, (2018). All Rights Reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c426t-93d780a716aad583514deaf956ec6e7e7385281f9aefc0ab6d6334f0d03e27b23</citedby><cites>FETCH-LOGICAL-c426t-93d780a716aad583514deaf956ec6e7e7385281f9aefc0ab6d6334f0d03e27b23</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10853-018-2288-2$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10853-018-2288-2$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>315,781,785,27926,27927,41490,42559,51321</link.rule.ids></links><search><creatorcontrib>Wang, Chongbin</creatorcontrib><creatorcontrib>Li, Zhiyuan</creatorcontrib><creatorcontrib>Chen, Jianxin</creatorcontrib><creatorcontrib>Zhong, Yunlong</creatorcontrib><creatorcontrib>Ren, Liang</creatorcontrib><creatorcontrib>Pu, Yunping</creatorcontrib><creatorcontrib>Dong, Zhipeng</creatorcontrib><creatorcontrib>Wu, Hong</creatorcontrib><title>Influence of blending zwitterionic functionalized titanium nanotubes on flux and anti-fouling performance of polyamide nanofiltration membranes</title><title>Journal of materials science</title><addtitle>J Mater Sci</addtitle><description>Organic–inorganic hybrid membranes represent an efficient approach to construct membranes with both improved membrane flux and solute selectivity. Zwitterions bearing equimolar number of anions and cations in one monomer unit exhibit excellent anti-fouling characteristics. Based on the exceptional separation performance of hybrid membrane and fouling resistance feature of zwitterions, a novel nanofiltration membrane was fabricated by incorporating zwitterionic functionalized titanium nanotubes (z-TNTs) into polyamide (PA) layer. The special tubular structure of z-TNTs can provide more and shorter internal channels to shorten flow lanes for water molecules. The zwitterionic functionalization on the titanium nanotubes surface improved not only the interfacial compatibility between nano-materials and polymer matrix but also the antifouling performance of membranes. The water flux of membrane prepared with z-TNTs was up to 220 L m
−2
h
−1
MPa
−1
while the Na
2
SO
4
rejection remained above 90%. The as-prepared z-TNTs/PA membrane exhibited improved anti-fouling property against protein with a notably reduced flux decline ratio.</description><subject>Antifouling</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry and Materials Science</subject><subject>Classical Mechanics</subject><subject>Crystallography and Scattering Methods</subject><subject>Flux</subject><subject>Materials Science</subject><subject>Membranes</subject><subject>Nanofiltration</subject><subject>Nanotubes</subject><subject>Paths</subject><subject>Polyamide resins</subject><subject>Polyamides</subject><subject>Polymer Sciences</subject><subject>Polymers</subject><subject>Selectivity</subject><subject>Sodium sulfate</subject><subject>Solid Mechanics</subject><subject>Surface active agents</subject><subject>Titanium</subject><subject>Water chemistry</subject><subject>Zwitterions</subject><issn>0022-2461</issn><issn>1573-4803</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNp1kc1q3TAUhEVpoLdJH6A7QVddONWPJdnLENrkQiDQn7WQraOLgi3dSjJN8hJ95ch1oGQRhHS0-GaYwyD0kZJzSoj6kinpBG8I7RrGuvq8QTsqFG_ajvC3aEcIYw1rJX2H3ud8RwgRitEd-rsPblogjICjw8MEwfpwwI9_fCmQfAx-xG4JY6lfM_lHsLj4YoJfZhxMiGUZIOMYcHW5xybYeotvXFym1ecIycU0m2f_Y5wezOwt_NM6P5VkVmc8wzwkEyCfoRNnpgwfnucp-vXt68_L6-bm9mp_eXHTjC2Tpem5VR0xikpjrOi4oK0F43ohYZSgQPFOsI663oAbiRmklZy3jljCgamB8VP0afM9pvh7gVz0XVxSXTFrxkQveUukqtT5Rh3MBNoHF2vgsR4Lsx9jgLoC6AvBVcv7npMq-PxCUJkC9-Vglpz1_sf3lyzd2DHFnBM4fUx-NulBU6LXUvVWqq6l6rVUvcZmmyZXNhwg_Y_9uugJ8lmnmg</recordid><startdate>20180701</startdate><enddate>20180701</enddate><creator>Wang, Chongbin</creator><creator>Li, Zhiyuan</creator><creator>Chen, Jianxin</creator><creator>Zhong, Yunlong</creator><creator>Ren, Liang</creator><creator>Pu, Yunping</creator><creator>Dong, Zhipeng</creator><creator>Wu, Hong</creator><general>Springer US</general><general>Springer</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>ISR</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>L6V</scope><scope>M7S</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>PTHSS</scope></search><sort><creationdate>20180701</creationdate><title>Influence of blending zwitterionic functionalized titanium nanotubes on flux and anti-fouling performance of polyamide nanofiltration membranes</title><author>Wang, Chongbin ; Li, Zhiyuan ; Chen, Jianxin ; Zhong, Yunlong ; Ren, Liang ; Pu, Yunping ; Dong, Zhipeng ; Wu, Hong</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c426t-93d780a716aad583514deaf956ec6e7e7385281f9aefc0ab6d6334f0d03e27b23</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Antifouling</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry and Materials Science</topic><topic>Classical Mechanics</topic><topic>Crystallography and Scattering Methods</topic><topic>Flux</topic><topic>Materials Science</topic><topic>Membranes</topic><topic>Nanofiltration</topic><topic>Nanotubes</topic><topic>Paths</topic><topic>Polyamide resins</topic><topic>Polyamides</topic><topic>Polymer Sciences</topic><topic>Polymers</topic><topic>Selectivity</topic><topic>Sodium sulfate</topic><topic>Solid Mechanics</topic><topic>Surface active agents</topic><topic>Titanium</topic><topic>Water chemistry</topic><topic>Zwitterions</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Wang, Chongbin</creatorcontrib><creatorcontrib>Li, Zhiyuan</creatorcontrib><creatorcontrib>Chen, Jianxin</creatorcontrib><creatorcontrib>Zhong, Yunlong</creatorcontrib><creatorcontrib>Ren, Liang</creatorcontrib><creatorcontrib>Pu, Yunping</creatorcontrib><creatorcontrib>Dong, Zhipeng</creatorcontrib><creatorcontrib>Wu, Hong</creatorcontrib><collection>CrossRef</collection><collection>Gale In Context: Science</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>ProQuest Engineering Collection</collection><collection>Engineering Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>Engineering Collection</collection><jtitle>Journal of materials science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Wang, Chongbin</au><au>Li, Zhiyuan</au><au>Chen, Jianxin</au><au>Zhong, Yunlong</au><au>Ren, Liang</au><au>Pu, Yunping</au><au>Dong, Zhipeng</au><au>Wu, Hong</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Influence of blending zwitterionic functionalized titanium nanotubes on flux and anti-fouling performance of polyamide nanofiltration membranes</atitle><jtitle>Journal of materials science</jtitle><stitle>J Mater Sci</stitle><date>2018-07-01</date><risdate>2018</risdate><volume>53</volume><issue>14</issue><spage>10499</spage><epage>10512</epage><pages>10499-10512</pages><issn>0022-2461</issn><eissn>1573-4803</eissn><abstract>Organic–inorganic hybrid membranes represent an efficient approach to construct membranes with both improved membrane flux and solute selectivity. Zwitterions bearing equimolar number of anions and cations in one monomer unit exhibit excellent anti-fouling characteristics. Based on the exceptional separation performance of hybrid membrane and fouling resistance feature of zwitterions, a novel nanofiltration membrane was fabricated by incorporating zwitterionic functionalized titanium nanotubes (z-TNTs) into polyamide (PA) layer. The special tubular structure of z-TNTs can provide more and shorter internal channels to shorten flow lanes for water molecules. The zwitterionic functionalization on the titanium nanotubes surface improved not only the interfacial compatibility between nano-materials and polymer matrix but also the antifouling performance of membranes. The water flux of membrane prepared with z-TNTs was up to 220 L m
−2
h
−1
MPa
−1
while the Na
2
SO
4
rejection remained above 90%. The as-prepared z-TNTs/PA membrane exhibited improved anti-fouling property against protein with a notably reduced flux decline ratio.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10853-018-2288-2</doi><tpages>14</tpages></addata></record> |
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subjects | Antifouling Characterization and Evaluation of Materials Chemistry and Materials Science Classical Mechanics Crystallography and Scattering Methods Flux Materials Science Membranes Nanofiltration Nanotubes Paths Polyamide resins Polyamides Polymer Sciences Polymers Selectivity Sodium sulfate Solid Mechanics Surface active agents Titanium Water chemistry Zwitterions |
title | Influence of blending zwitterionic functionalized titanium nanotubes on flux and anti-fouling performance of polyamide nanofiltration membranes |
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