Influence of blending zwitterionic functionalized titanium nanotubes on flux and anti-fouling performance of polyamide nanofiltration membranes

Organic–inorganic hybrid membranes represent an efficient approach to construct membranes with both improved membrane flux and solute selectivity. Zwitterions bearing equimolar number of anions and cations in one monomer unit exhibit excellent anti-fouling characteristics. Based on the exceptional s...

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Veröffentlicht in:Journal of materials science 2018-07, Vol.53 (14), p.10499-10512
Hauptverfasser: Wang, Chongbin, Li, Zhiyuan, Chen, Jianxin, Zhong, Yunlong, Ren, Liang, Pu, Yunping, Dong, Zhipeng, Wu, Hong
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container_end_page 10512
container_issue 14
container_start_page 10499
container_title Journal of materials science
container_volume 53
creator Wang, Chongbin
Li, Zhiyuan
Chen, Jianxin
Zhong, Yunlong
Ren, Liang
Pu, Yunping
Dong, Zhipeng
Wu, Hong
description Organic–inorganic hybrid membranes represent an efficient approach to construct membranes with both improved membrane flux and solute selectivity. Zwitterions bearing equimolar number of anions and cations in one monomer unit exhibit excellent anti-fouling characteristics. Based on the exceptional separation performance of hybrid membrane and fouling resistance feature of zwitterions, a novel nanofiltration membrane was fabricated by incorporating zwitterionic functionalized titanium nanotubes (z-TNTs) into polyamide (PA) layer. The special tubular structure of z-TNTs can provide more and shorter internal channels to shorten flow lanes for water molecules. The zwitterionic functionalization on the titanium nanotubes surface improved not only the interfacial compatibility between nano-materials and polymer matrix but also the antifouling performance of membranes. The water flux of membrane prepared with z-TNTs was up to 220 L m −2  h −1  MPa −1 while the Na 2 SO 4 rejection remained above 90%. The as-prepared z-TNTs/PA membrane exhibited improved anti-fouling property against protein with a notably reduced flux decline ratio.
doi_str_mv 10.1007/s10853-018-2288-2
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Zwitterions bearing equimolar number of anions and cations in one monomer unit exhibit excellent anti-fouling characteristics. Based on the exceptional separation performance of hybrid membrane and fouling resistance feature of zwitterions, a novel nanofiltration membrane was fabricated by incorporating zwitterionic functionalized titanium nanotubes (z-TNTs) into polyamide (PA) layer. The special tubular structure of z-TNTs can provide more and shorter internal channels to shorten flow lanes for water molecules. The zwitterionic functionalization on the titanium nanotubes surface improved not only the interfacial compatibility between nano-materials and polymer matrix but also the antifouling performance of membranes. The water flux of membrane prepared with z-TNTs was up to 220 L m −2  h −1  MPa −1 while the Na 2 SO 4 rejection remained above 90%. 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subjects Antifouling
Characterization and Evaluation of Materials
Chemistry and Materials Science
Classical Mechanics
Crystallography and Scattering Methods
Flux
Materials Science
Membranes
Nanofiltration
Nanotubes
Paths
Polyamide resins
Polyamides
Polymer Sciences
Polymers
Selectivity
Sodium sulfate
Solid Mechanics
Surface active agents
Titanium
Water chemistry
Zwitterions
title Influence of blending zwitterionic functionalized titanium nanotubes on flux and anti-fouling performance of polyamide nanofiltration membranes
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