The effect of para-divinyl benzene on styrenic emulsion-templated porous polymers: a chemical Trojan horse
Emulsion-templated porous polymers such as polymerized high internal phase emulsions (polyHIPEs) are an exciting class of porous polymer due to tunable physical and chemical properties. One original use of polyHIPEs was in high-energy laser experiments. However, a density heterogeneity issue has bee...
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| Veröffentlicht in: | Journal of materials science 2017-03, Vol.52 (6), p.3179-3187 |
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| creator | Musgrave, Christopher S. A. Nazarov, Wigen Bazin, Nick |
| description | Emulsion-templated porous polymers such as polymerized high internal phase emulsions (polyHIPEs) are an exciting class of porous polymer due to tunable physical and chemical properties. One original use of polyHIPEs was in high-energy laser experiments. However, a density heterogeneity issue has been identified in polyHIPEs during screening for suitability as a laser target. To understand this problem, we studied the physical properties in detail of a well-understood polyHIPE system, styrene-
co
-divinyl benzene (S-
co
-DVB). Dynamic mechanical analysis (DMA), scanning electron microscopy, Mercury porosimetry, and time domain nuclear magnetic resonance (TD-NMR) identified that
para
-DVB, a component of divinyl benzene (DVB80), was an unstable species—effectively behaving as a chemical Trojan horse. TD-NMR spin–lattice and spin–lock relaxation times elucidated more structural detail on the polymer structure for all the polyHIPEs studied, such as long spin–lattice times corresponded to high modulus values. Furthermore, we observed that the Young’s modulus was reduced by 40% in polyHIPEs containing
para
-DVB as the cross-linker. Understanding the factors affecting polyHIPE physical properties is an important step to further enhance their effectiveness in the many growing applications of polyHIPEs. |
| doi_str_mv | 10.1007/s10853-016-0607-z |
| format | Article |
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co
-divinyl benzene (S-
co
-DVB). Dynamic mechanical analysis (DMA), scanning electron microscopy, Mercury porosimetry, and time domain nuclear magnetic resonance (TD-NMR) identified that
para
-DVB, a component of divinyl benzene (DVB80), was an unstable species—effectively behaving as a chemical Trojan horse. TD-NMR spin–lattice and spin–lock relaxation times elucidated more structural detail on the polymer structure for all the polyHIPEs studied, such as long spin–lattice times corresponded to high modulus values. Furthermore, we observed that the Young’s modulus was reduced by 40% in polyHIPEs containing
para
-DVB as the cross-linker. Understanding the factors affecting polyHIPE physical properties is an important step to further enhance their effectiveness in the many growing applications of polyHIPEs.</description><identifier>ISSN: 0022-2461</identifier><identifier>EISSN: 1573-4803</identifier><identifier>DOI: 10.1007/s10853-016-0607-z</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Benzene ; Characterization and Evaluation of Materials ; Chemical properties ; Chemistry and Materials Science ; Classical Mechanics ; Crosslinking ; Crystallography and Scattering Methods ; Divinylbenzene ; Dynamic mechanical analysis ; Emulsion polymerization ; Hydrocarbons ; Malware ; Materials Science ; Modulus of elasticity ; NMR ; Nuclear magnetic resonance ; Organic chemistry ; Original Paper ; Physical properties ; Polymer industry ; Polymer Sciences ; Polymers ; Porosity ; Scanning electron microscopy ; Solid Mechanics</subject><ispartof>Journal of materials science, 2017-03, Vol.52 (6), p.3179-3187</ispartof><rights>Springer Science+Business Media New York 2016</rights><rights>COPYRIGHT 2017 Springer</rights><rights>Journal of Materials Science is a copyright of Springer, (2016). All Rights Reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c433t-d6bd50b17adde1fac9f1e6736946b144e06a5838a2c700e859fa3c2cbcff8ae73</citedby><cites>FETCH-LOGICAL-c433t-d6bd50b17adde1fac9f1e6736946b144e06a5838a2c700e859fa3c2cbcff8ae73</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10853-016-0607-z$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10853-016-0607-z$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27903,27904,41467,42536,51297</link.rule.ids></links><search><creatorcontrib>Musgrave, Christopher S. A.</creatorcontrib><creatorcontrib>Nazarov, Wigen</creatorcontrib><creatorcontrib>Bazin, Nick</creatorcontrib><title>The effect of para-divinyl benzene on styrenic emulsion-templated porous polymers: a chemical Trojan horse</title><title>Journal of materials science</title><addtitle>J Mater Sci</addtitle><description>Emulsion-templated porous polymers such as polymerized high internal phase emulsions (polyHIPEs) are an exciting class of porous polymer due to tunable physical and chemical properties. One original use of polyHIPEs was in high-energy laser experiments. However, a density heterogeneity issue has been identified in polyHIPEs during screening for suitability as a laser target. To understand this problem, we studied the physical properties in detail of a well-understood polyHIPE system, styrene-
co
-divinyl benzene (S-
co
-DVB). Dynamic mechanical analysis (DMA), scanning electron microscopy, Mercury porosimetry, and time domain nuclear magnetic resonance (TD-NMR) identified that
para
-DVB, a component of divinyl benzene (DVB80), was an unstable species—effectively behaving as a chemical Trojan horse. TD-NMR spin–lattice and spin–lock relaxation times elucidated more structural detail on the polymer structure for all the polyHIPEs studied, such as long spin–lattice times corresponded to high modulus values. Furthermore, we observed that the Young’s modulus was reduced by 40% in polyHIPEs containing
para
-DVB as the cross-linker. Understanding the factors affecting polyHIPE physical properties is an important step to further enhance their effectiveness in the many growing applications of polyHIPEs.</description><subject>Benzene</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemical properties</subject><subject>Chemistry and Materials Science</subject><subject>Classical Mechanics</subject><subject>Crosslinking</subject><subject>Crystallography and Scattering Methods</subject><subject>Divinylbenzene</subject><subject>Dynamic mechanical analysis</subject><subject>Emulsion polymerization</subject><subject>Hydrocarbons</subject><subject>Malware</subject><subject>Materials Science</subject><subject>Modulus of elasticity</subject><subject>NMR</subject><subject>Nuclear magnetic resonance</subject><subject>Organic chemistry</subject><subject>Original Paper</subject><subject>Physical properties</subject><subject>Polymer industry</subject><subject>Polymer Sciences</subject><subject>Polymers</subject><subject>Porosity</subject><subject>Scanning electron microscopy</subject><subject>Solid Mechanics</subject><issn>0022-2461</issn><issn>1573-4803</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><sourceid>BENPR</sourceid><recordid>eNp1kUGLFDEQhYMoOI7-AG8BTx6yVpLupMfbsri6sCDoeA7pdGWmh-6kTbrFmV9vhhZkD1KHguJ7VY96hLzlcMMB9IfMoaklA64YKNDs8oxseK0lqxqQz8kGQAgmKsVfklc5nwCg1oJvyGl_RIreo5tp9HSyybKu_9WH80BbDBcMSGOgeT4nDL2jOC5D7mNgM47TYGfs6BRTXHJpw3nElD9SS90Rx97Zge5TPNlAjzFlfE1eeDtkfPO3b8mP-0_7uy_s8evnh7vbR-YqKWfWqbaroeXadh1yb93Oc1Raql2lWl5VCMrWjWyscBoAm3rnrXTCtc77xqKWW_Ju3Tul-HPBPJtTXFIoJ40Q9U7J8hdVqJuVOtgBTR98nJN1pbqr9RjQ92V-W-mKK8HLb7fk_RNBYWb8PR_skrN5-P7tKctX1qWYc0JvptSPNp0NB3PNy6x5mZKXueZlLkUjVk0ubDhg-mf7_6I_lguZhg</recordid><startdate>20170301</startdate><enddate>20170301</enddate><creator>Musgrave, Christopher S. A.</creator><creator>Nazarov, Wigen</creator><creator>Bazin, Nick</creator><general>Springer US</general><general>Springer</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>ISR</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>L6V</scope><scope>M7S</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>PTHSS</scope></search><sort><creationdate>20170301</creationdate><title>The effect of para-divinyl benzene on styrenic emulsion-templated porous polymers: a chemical Trojan horse</title><author>Musgrave, Christopher S. A. ; Nazarov, Wigen ; Bazin, Nick</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c433t-d6bd50b17adde1fac9f1e6736946b144e06a5838a2c700e859fa3c2cbcff8ae73</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Benzene</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemical properties</topic><topic>Chemistry and Materials Science</topic><topic>Classical Mechanics</topic><topic>Crosslinking</topic><topic>Crystallography and Scattering Methods</topic><topic>Divinylbenzene</topic><topic>Dynamic mechanical analysis</topic><topic>Emulsion polymerization</topic><topic>Hydrocarbons</topic><topic>Malware</topic><topic>Materials Science</topic><topic>Modulus of elasticity</topic><topic>NMR</topic><topic>Nuclear magnetic resonance</topic><topic>Organic chemistry</topic><topic>Original Paper</topic><topic>Physical properties</topic><topic>Polymer industry</topic><topic>Polymer Sciences</topic><topic>Polymers</topic><topic>Porosity</topic><topic>Scanning electron microscopy</topic><topic>Solid Mechanics</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Musgrave, Christopher S. A.</creatorcontrib><creatorcontrib>Nazarov, Wigen</creatorcontrib><creatorcontrib>Bazin, Nick</creatorcontrib><collection>CrossRef</collection><collection>Gale In Context: Science</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>ProQuest Engineering Collection</collection><collection>Engineering Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>Engineering Collection</collection><jtitle>Journal of materials science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Musgrave, Christopher S. A.</au><au>Nazarov, Wigen</au><au>Bazin, Nick</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>The effect of para-divinyl benzene on styrenic emulsion-templated porous polymers: a chemical Trojan horse</atitle><jtitle>Journal of materials science</jtitle><stitle>J Mater Sci</stitle><date>2017-03-01</date><risdate>2017</risdate><volume>52</volume><issue>6</issue><spage>3179</spage><epage>3187</epage><pages>3179-3187</pages><issn>0022-2461</issn><eissn>1573-4803</eissn><abstract>Emulsion-templated porous polymers such as polymerized high internal phase emulsions (polyHIPEs) are an exciting class of porous polymer due to tunable physical and chemical properties. One original use of polyHIPEs was in high-energy laser experiments. However, a density heterogeneity issue has been identified in polyHIPEs during screening for suitability as a laser target. To understand this problem, we studied the physical properties in detail of a well-understood polyHIPE system, styrene-
co
-divinyl benzene (S-
co
-DVB). Dynamic mechanical analysis (DMA), scanning electron microscopy, Mercury porosimetry, and time domain nuclear magnetic resonance (TD-NMR) identified that
para
-DVB, a component of divinyl benzene (DVB80), was an unstable species—effectively behaving as a chemical Trojan horse. TD-NMR spin–lattice and spin–lock relaxation times elucidated more structural detail on the polymer structure for all the polyHIPEs studied, such as long spin–lattice times corresponded to high modulus values. Furthermore, we observed that the Young’s modulus was reduced by 40% in polyHIPEs containing
para
-DVB as the cross-linker. Understanding the factors affecting polyHIPE physical properties is an important step to further enhance their effectiveness in the many growing applications of polyHIPEs.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10853-016-0607-z</doi><tpages>9</tpages></addata></record> |
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| subjects | Benzene Characterization and Evaluation of Materials Chemical properties Chemistry and Materials Science Classical Mechanics Crosslinking Crystallography and Scattering Methods Divinylbenzene Dynamic mechanical analysis Emulsion polymerization Hydrocarbons Malware Materials Science Modulus of elasticity NMR Nuclear magnetic resonance Organic chemistry Original Paper Physical properties Polymer industry Polymer Sciences Polymers Porosity Scanning electron microscopy Solid Mechanics |
| title | The effect of para-divinyl benzene on styrenic emulsion-templated porous polymers: a chemical Trojan horse |
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