Rechargeable organic batteries using chloro-substituted naphthazarin derivatives as positive electrode materials
The use of redox active organic compounds as an alternative positive electrode material of rechargeable lithium batteries can be a solution for the resource issues of the current battery system. To satisfy both the high capacity and long cycle life of the batteries using organic active materials, na...
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| Veröffentlicht in: | Journal of materials science 2017-10, Vol.52 (20), p.12401-12408 |
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| creator | Yao, Masaru Umetani, Shinji Ando, Hisanori Kiyobayashi, Tetsu Takeichi, Nobuhiko Kondo, Ryota Takeshita, Hiroyuki T. |
| description | The use of redox active organic compounds as an alternative positive electrode material of rechargeable lithium batteries can be a solution for the resource issues of the current battery system. To satisfy both the high capacity and long cycle life of the batteries using organic active materials, naphthazarin (5,8-dihydroxy-1,4-naphthoquinone) derivatives, which potentially exhibit a four-electron transfer redox reaction, were investigated. While the unsubstituted naphthazarin lithium salt (
1
), having a high theoretical capacity of up to about 550 mAh g
−1
, showed only half the expected capacity and a short cycle life as a positive electrode active material, the chloro-substituted ones (
1
-
Cl
2
,
1
-
Cl
4
) exhibited improved properties in both their initial capacity utilization and cycle life. In addition, the high stability of a chloro-substituted naphthazarin salt (
1
-
Cl
4
) was supported by a reversible electrochromic behavior during the redox reaction. The substituent effect of the naphthazarin derivatives on the cycle stability was discussed with respect to the battery performance and electrochromic behavior. Also, a guide for designing a new organic active material which shows a high capacity and long cycle life is suggested. |
| doi_str_mv | 10.1007/s10853-017-1368-z |
| format | Article |
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1
), having a high theoretical capacity of up to about 550 mAh g
−1
, showed only half the expected capacity and a short cycle life as a positive electrode active material, the chloro-substituted ones (
1
-
Cl
2
,
1
-
Cl
4
) exhibited improved properties in both their initial capacity utilization and cycle life. In addition, the high stability of a chloro-substituted naphthazarin salt (
1
-
Cl
4
) was supported by a reversible electrochromic behavior during the redox reaction. The substituent effect of the naphthazarin derivatives on the cycle stability was discussed with respect to the battery performance and electrochromic behavior. Also, a guide for designing a new organic active material which shows a high capacity and long cycle life is suggested.</description><identifier>ISSN: 0022-2461</identifier><identifier>EISSN: 1573-4803</identifier><identifier>DOI: 10.1007/s10853-017-1368-z</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Batteries ; Characterization and Evaluation of Materials ; Chemistry and Materials Science ; Classical Mechanics ; Crystallography and Scattering Methods ; Derivatives ; Electrochromism ; Electrode materials ; Electrodes ; Electron transfer ; Electron transport ; Energy Materials ; Lithium ; Lithium batteries ; Materials Science ; Materials substitution ; Organic compounds ; Polymer Sciences ; Rechargeable batteries ; Solid Mechanics ; Stability</subject><ispartof>Journal of materials science, 2017-10, Vol.52 (20), p.12401-12408</ispartof><rights>Springer Science+Business Media, LLC 2017</rights><rights>COPYRIGHT 2017 Springer</rights><rights>Journal of Materials Science is a copyright of Springer, (2017). All Rights Reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c494t-57d0594d8956986ad1addbe1b3cc4090ecced8111885e85187dc13c3cc992f683</citedby><cites>FETCH-LOGICAL-c494t-57d0594d8956986ad1addbe1b3cc4090ecced8111885e85187dc13c3cc992f683</cites><orcidid>0000-0002-5940-833X</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10853-017-1368-z$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10853-017-1368-z$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Yao, Masaru</creatorcontrib><creatorcontrib>Umetani, Shinji</creatorcontrib><creatorcontrib>Ando, Hisanori</creatorcontrib><creatorcontrib>Kiyobayashi, Tetsu</creatorcontrib><creatorcontrib>Takeichi, Nobuhiko</creatorcontrib><creatorcontrib>Kondo, Ryota</creatorcontrib><creatorcontrib>Takeshita, Hiroyuki T.</creatorcontrib><title>Rechargeable organic batteries using chloro-substituted naphthazarin derivatives as positive electrode materials</title><title>Journal of materials science</title><addtitle>J Mater Sci</addtitle><description>The use of redox active organic compounds as an alternative positive electrode material of rechargeable lithium batteries can be a solution for the resource issues of the current battery system. To satisfy both the high capacity and long cycle life of the batteries using organic active materials, naphthazarin (5,8-dihydroxy-1,4-naphthoquinone) derivatives, which potentially exhibit a four-electron transfer redox reaction, were investigated. While the unsubstituted naphthazarin lithium salt (
1
), having a high theoretical capacity of up to about 550 mAh g
−1
, showed only half the expected capacity and a short cycle life as a positive electrode active material, the chloro-substituted ones (
1
-
Cl
2
,
1
-
Cl
4
) exhibited improved properties in both their initial capacity utilization and cycle life. In addition, the high stability of a chloro-substituted naphthazarin salt (
1
-
Cl
4
) was supported by a reversible electrochromic behavior during the redox reaction. The substituent effect of the naphthazarin derivatives on the cycle stability was discussed with respect to the battery performance and electrochromic behavior. Also, a guide for designing a new organic active material which shows a high capacity and long cycle life is suggested.</description><subject>Batteries</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry and Materials Science</subject><subject>Classical Mechanics</subject><subject>Crystallography and Scattering Methods</subject><subject>Derivatives</subject><subject>Electrochromism</subject><subject>Electrode materials</subject><subject>Electrodes</subject><subject>Electron transfer</subject><subject>Electron transport</subject><subject>Energy Materials</subject><subject>Lithium</subject><subject>Lithium batteries</subject><subject>Materials Science</subject><subject>Materials substitution</subject><subject>Organic compounds</subject><subject>Polymer Sciences</subject><subject>Rechargeable batteries</subject><subject>Solid Mechanics</subject><subject>Stability</subject><issn>0022-2461</issn><issn>1573-4803</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNp1kcFqHSEUhqW00Ns0D5Cd0FUXpurojC5DaJtAoJC2a3H0zFzD3HGqTmju09fLBEoWwcVB_b5zxB-hC0YvGaXdl8yokg2hrCOsaRU5vkE7JruGCEWbt2hHKeeEi5a9Rx9yfqCUyo6zHVruwe1tGsH2E-CYRjsHh3tbCqQAGa85zCN2-ymmSPLa5xLKWsDj2S77srdHm8KMfYUfbQmP1bAZLzGH0wbDBK6k6AEf7KmhnfJH9G6oBc6f6xn6_e3rr-sbcvfj--311R1xQotCZOep1MIrLVutWuuZ9b4H1jfOCaopOAdeMcaUkqAkU513rHH1Vms-tKo5Q5-2vkuKf1bIxTzENc11pOFc6rZhXOlKXW7UaCcwYR5iSdbV5eEQXJxhCPX8SmhdP1UoUYXPL4TKFPhbRrvmbG5_3r9k2ca6FHNOMJglhYNNT4ZRc0rNbKmZmpo5pWaO1eGbkys7j5D-P_t16R92YJyv</recordid><startdate>20171001</startdate><enddate>20171001</enddate><creator>Yao, Masaru</creator><creator>Umetani, Shinji</creator><creator>Ando, Hisanori</creator><creator>Kiyobayashi, Tetsu</creator><creator>Takeichi, Nobuhiko</creator><creator>Kondo, Ryota</creator><creator>Takeshita, Hiroyuki T.</creator><general>Springer US</general><general>Springer</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>ISR</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>L6V</scope><scope>M7S</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>PTHSS</scope><orcidid>https://orcid.org/0000-0002-5940-833X</orcidid></search><sort><creationdate>20171001</creationdate><title>Rechargeable organic batteries using chloro-substituted naphthazarin derivatives as positive electrode materials</title><author>Yao, Masaru ; Umetani, Shinji ; Ando, Hisanori ; Kiyobayashi, Tetsu ; Takeichi, Nobuhiko ; Kondo, Ryota ; Takeshita, Hiroyuki T.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c494t-57d0594d8956986ad1addbe1b3cc4090ecced8111885e85187dc13c3cc992f683</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Batteries</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry and Materials Science</topic><topic>Classical Mechanics</topic><topic>Crystallography and Scattering Methods</topic><topic>Derivatives</topic><topic>Electrochromism</topic><topic>Electrode materials</topic><topic>Electrodes</topic><topic>Electron transfer</topic><topic>Electron transport</topic><topic>Energy Materials</topic><topic>Lithium</topic><topic>Lithium batteries</topic><topic>Materials Science</topic><topic>Materials substitution</topic><topic>Organic compounds</topic><topic>Polymer Sciences</topic><topic>Rechargeable batteries</topic><topic>Solid Mechanics</topic><topic>Stability</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Yao, Masaru</creatorcontrib><creatorcontrib>Umetani, Shinji</creatorcontrib><creatorcontrib>Ando, Hisanori</creatorcontrib><creatorcontrib>Kiyobayashi, Tetsu</creatorcontrib><creatorcontrib>Takeichi, Nobuhiko</creatorcontrib><creatorcontrib>Kondo, Ryota</creatorcontrib><creatorcontrib>Takeshita, Hiroyuki T.</creatorcontrib><collection>CrossRef</collection><collection>Science (Gale in Context)</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central</collection><collection>SciTech Premium Collection</collection><collection>https://resources.nclive.org/materials</collection><collection>ProQuest Engineering Collection</collection><collection>Engineering Database</collection><collection>Materials science collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>Engineering collection</collection><jtitle>Journal of materials science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Yao, Masaru</au><au>Umetani, Shinji</au><au>Ando, Hisanori</au><au>Kiyobayashi, Tetsu</au><au>Takeichi, Nobuhiko</au><au>Kondo, Ryota</au><au>Takeshita, Hiroyuki T.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Rechargeable organic batteries using chloro-substituted naphthazarin derivatives as positive electrode materials</atitle><jtitle>Journal of materials science</jtitle><stitle>J Mater Sci</stitle><date>2017-10-01</date><risdate>2017</risdate><volume>52</volume><issue>20</issue><spage>12401</spage><epage>12408</epage><pages>12401-12408</pages><issn>0022-2461</issn><eissn>1573-4803</eissn><abstract>The use of redox active organic compounds as an alternative positive electrode material of rechargeable lithium batteries can be a solution for the resource issues of the current battery system. To satisfy both the high capacity and long cycle life of the batteries using organic active materials, naphthazarin (5,8-dihydroxy-1,4-naphthoquinone) derivatives, which potentially exhibit a four-electron transfer redox reaction, were investigated. While the unsubstituted naphthazarin lithium salt (
1
), having a high theoretical capacity of up to about 550 mAh g
−1
, showed only half the expected capacity and a short cycle life as a positive electrode active material, the chloro-substituted ones (
1
-
Cl
2
,
1
-
Cl
4
) exhibited improved properties in both their initial capacity utilization and cycle life. In addition, the high stability of a chloro-substituted naphthazarin salt (
1
-
Cl
4
) was supported by a reversible electrochromic behavior during the redox reaction. The substituent effect of the naphthazarin derivatives on the cycle stability was discussed with respect to the battery performance and electrochromic behavior. Also, a guide for designing a new organic active material which shows a high capacity and long cycle life is suggested.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10853-017-1368-z</doi><tpages>8</tpages><orcidid>https://orcid.org/0000-0002-5940-833X</orcidid></addata></record> |
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| subjects | Batteries Characterization and Evaluation of Materials Chemistry and Materials Science Classical Mechanics Crystallography and Scattering Methods Derivatives Electrochromism Electrode materials Electrodes Electron transfer Electron transport Energy Materials Lithium Lithium batteries Materials Science Materials substitution Organic compounds Polymer Sciences Rechargeable batteries Solid Mechanics Stability |
| title | Rechargeable organic batteries using chloro-substituted naphthazarin derivatives as positive electrode materials |
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