Synthesis of type-II CdSe(S)/Fe2O3 core/shell quantum dots: the effect of shell on the properties of core/shell quantum dots

CdSe(S)/Fe₂O₃ core/shell quantum dots (QDs) were prepared in an aqueous synthetic route. These were shown to be highly crystalline nanoparticles using X-ray diffraction and HRTEM, whilst optical spectroscopy showed that the particles exhibited highly photoluminescent emissions. A red shift in the em...

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Veröffentlicht in:Journal of materials science 2016-06, Vol.51 (11), p.5252-5258
Hauptverfasser: Mirnajafizadeh, Fatemeh, Wang, Fan, Reece, Peter, Stride, John Arron
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creator Mirnajafizadeh, Fatemeh
Wang, Fan
Reece, Peter
Stride, John Arron
description CdSe(S)/Fe₂O₃ core/shell quantum dots (QDs) were prepared in an aqueous synthetic route. These were shown to be highly crystalline nanoparticles using X-ray diffraction and HRTEM, whilst optical spectroscopy showed that the particles exhibited highly photoluminescent emissions. A red shift in the emission wavelength of CdSe(S) QDs coated with Fe₂O₃ was observed, despite the crystal structure of the core remaining intact after coating with ferric oxide, indicating a direct influence of the shell on the electronic levels of the QD core. The effects of the shell on the optical properties of core/shell QDs of these type-II CdSe(S)/Fe₂O₃ QDs are rationalised by comparison to type-I CdSe(S)/ZnO QDs.
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subjects Cadmium selenides
Characterization and Evaluation of Materials
Chemistry and Materials Science
Classical Mechanics
Crystal structure
Crystallography and Scattering Methods
Doppler effect
Ferric oxide
Iron oxides
Materials Science
Nanoparticles
Optical properties
Original Paper
Photoluminescence
Polymer Sciences
Quantum dots
Red shift
Solid Mechanics
X-ray diffraction
Zinc oxide
title Synthesis of type-II CdSe(S)/Fe2O3 core/shell quantum dots: the effect of shell on the properties of core/shell quantum dots
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