Effective thermal expansion coefficient of a sintered glass–eucryptite composite
The paper focuses on a glass–ceramic composite consisting of lead borate glass matrix containing isolated eucryptite granules (hereafter called inhomogeneities) having negative thermal expansion coefficient. We discuss the dependence of the overall thermal expansion on the size of the particles and...
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| Veröffentlicht in: | Journal of materials science 2017-10, Vol.52 (19), p.11314-11325 |
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| container_issue | 19 |
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| container_title | Journal of materials science |
| container_volume | 52 |
| creator | Kryukova, O. N. Knyazeva, A. G. Pogrebenkov, V. M. Kostikov, K. S. Sevostianov, I. |
| description | The paper focuses on a glass–ceramic composite consisting of lead borate glass matrix containing isolated eucryptite granules (hereafter called inhomogeneities) having negative thermal expansion coefficient. We discuss the dependence of the overall thermal expansion on the size of the particles and the temperature of sintering as well as the process of the diffusion of lithium from eucryptite into the glass matrix. The latter leads to the formation of interphase zones between the matrix and inhomogeneities. The overall thermal expansion coefficient is measured experimentally and modeled using various micromechanical schemes. The best agreement for the entire range of variation of the eucryptite volume fraction is provided by Maxwell homogenization scheme. |
| doi_str_mv | 10.1007/s10853-017-1298-9 |
| format | Article |
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M.</creatorcontrib><creatorcontrib>Kostikov, K. S.</creatorcontrib><creatorcontrib>Sevostianov, I.</creatorcontrib><title>Effective thermal expansion coefficient of a sintered glass–eucryptite composite</title><title>Journal of materials science</title><addtitle>J Mater Sci</addtitle><description>The paper focuses on a glass–ceramic composite consisting of lead borate glass matrix containing isolated eucryptite granules (hereafter called inhomogeneities) having negative thermal expansion coefficient. We discuss the dependence of the overall thermal expansion on the size of the particles and the temperature of sintering as well as the process of the diffusion of lithium from eucryptite into the glass matrix. The latter leads to the formation of interphase zones between the matrix and inhomogeneities. The overall thermal expansion coefficient is measured experimentally and modeled using various micromechanical schemes. The best agreement for the entire range of variation of the eucryptite volume fraction is provided by Maxwell homogenization scheme.</description><subject>Ceramics</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry and Materials Science</subject><subject>Classical Mechanics</subject><subject>Crystallography and Scattering Methods</subject><subject>Dependence</subject><subject>Eucryptite</subject><subject>Glass ceramics</subject><subject>Inhomogeneity</subject><subject>Lithium</subject><subject>Lithium compounds</subject><subject>Materials Science</subject><subject>Polymer Sciences</subject><subject>Sintering</subject><subject>Solid Mechanics</subject><subject>Thermal expansion</subject><subject>Thermal properties</subject><issn>0022-2461</issn><issn>1573-4803</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><sourceid>BENPR</sourceid><recordid>eNp1kclKBDEQhoMoOC4P4K3Bk4fWrJPkKOIGguByDpl0ZYzMdNokI87Nd_ANfRIjLYgHqUOK8H2pCj9CBwQfE4zlSSZYCdZiIltCtWr1BpoQIVnLFWabaIIxpS3lU7KNdnJ-xhgLSckE3Z17D66EV2jKE6SlXTTwNtg-h9g3LoL3wQXoSxN9Y5sc-gIJuma-sDl_vn_AyqX1UEKBCi-HmGu3h7a8XWTY_zl30ePF-cPZVXtze3l9dnrTOqZ0aXnHlfVuCrSDGae2c4QI1oEkvGNiJi1V1mkigHhQWmnLlRQMSy9nytFOsF10OL47pPiyglzMc1ylvo40lAo9pbz-t1LHIzW3CzCh97Ek62p1sAwu9uBDvT_lWlFBNWNVOPojVKbAW5nbVc7m-v7uL0tG1qWYcwJvhhSWNq0NweY7FzPmYmou5jsXo6tDRydXtp9D-l37f-kLlj2RBQ</recordid><startdate>20171001</startdate><enddate>20171001</enddate><creator>Kryukova, O. 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S. ; Sevostianov, I.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c389t-4d48afc6e2deb42adc1153de714d35b7a28ac915e1fe8989a4875307f7b8c2d53</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Ceramics</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry and Materials Science</topic><topic>Classical Mechanics</topic><topic>Crystallography and Scattering Methods</topic><topic>Dependence</topic><topic>Eucryptite</topic><topic>Glass ceramics</topic><topic>Inhomogeneity</topic><topic>Lithium</topic><topic>Lithium compounds</topic><topic>Materials Science</topic><topic>Polymer Sciences</topic><topic>Sintering</topic><topic>Solid Mechanics</topic><topic>Thermal expansion</topic><topic>Thermal properties</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kryukova, O. 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| subjects | Ceramics Characterization and Evaluation of Materials Chemistry and Materials Science Classical Mechanics Crystallography and Scattering Methods Dependence Eucryptite Glass ceramics Inhomogeneity Lithium Lithium compounds Materials Science Polymer Sciences Sintering Solid Mechanics Thermal expansion Thermal properties |
| title | Effective thermal expansion coefficient of a sintered glass–eucryptite composite |
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