Facile synthesis of 3D binder-free N-doped carbon nanonet derived from silkworm cocoon for Li–O2 battery
Rechargeable nonaqueous lithium–O 2 batteries are considered as the most promising energy storage system for electric vehicles due to their extremely high energy density. However, the inefficient O 2 diffusion, large overpotential and unwanted side reaction still restrict their specific capacity and...
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| Veröffentlicht in: | Journal of materials science 2018-03, Vol.53 (6), p.4395-4405 |
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| container_title | Journal of materials science |
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| creator | Jing, Shengyu Zhang, Maoshen Liang, Huagen Shen, Baolong Yin, Shibin Yang, Xu |
| description | Rechargeable nonaqueous lithium–O
2
batteries are considered as the most promising energy storage system for electric vehicles due to their extremely high energy density. However, the inefficient O
2
diffusion, large overpotential and unwanted side reaction still restrict their specific capacity and cycle performance. This work presents a facile method to prepare a novel 3D binder-free N-doped carbon nanonet by using an economical, green and sustainable biomass—silkworm cocoon as the precursor. Li–O
2
batteries with this N-doped carbon nanonet as the cathode delivered a superior specific capacity and excellent cycling stability, which attributable to the 3D porous and through structure, high specific surface area, the enhanced catalytic activity of ORR/OER arising from the incorporation of N, and the absence of binders in the electrode. Therefore, by taking advantages of the unique structure and morphology of biomass, the low-cost and green 3D binder-free N-doped carbon materials are a feasible approach for the preparation of high-performance cathode for Li–O
2
battery. |
| doi_str_mv | 10.1007/s10853-017-1818-7 |
| format | Article |
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2
batteries are considered as the most promising energy storage system for electric vehicles due to their extremely high energy density. However, the inefficient O
2
diffusion, large overpotential and unwanted side reaction still restrict their specific capacity and cycle performance. This work presents a facile method to prepare a novel 3D binder-free N-doped carbon nanonet by using an economical, green and sustainable biomass—silkworm cocoon as the precursor. Li–O
2
batteries with this N-doped carbon nanonet as the cathode delivered a superior specific capacity and excellent cycling stability, which attributable to the 3D porous and through structure, high specific surface area, the enhanced catalytic activity of ORR/OER arising from the incorporation of N, and the absence of binders in the electrode. Therefore, by taking advantages of the unique structure and morphology of biomass, the low-cost and green 3D binder-free N-doped carbon materials are a feasible approach for the preparation of high-performance cathode for Li–O
2
battery.</description><identifier>ISSN: 0022-2461</identifier><identifier>EISSN: 1573-4803</identifier><identifier>DOI: 10.1007/s10853-017-1818-7</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Biomass ; Carbon ; Catalysis ; Catalytic activity ; Cathodes ; Characterization and Evaluation of Materials ; Chemistry and Materials Science ; Classical Mechanics ; Crystallography and Scattering Methods ; Electric vehicles ; Energy Materials ; Energy storage ; Flux density ; Lithium ; Materials Science ; Morphology ; Polymer Sciences ; Rechargeable batteries ; Silkworms ; Solid Mechanics ; Storage batteries</subject><ispartof>Journal of materials science, 2018-03, Vol.53 (6), p.4395-4405</ispartof><rights>Springer Science+Business Media, LLC, part of Springer Nature 2017</rights><rights>Journal of Materials Science is a copyright of Springer, (2017). All Rights Reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c2707-87019406aa4a384ba3e4949ac9937b966cade9d9fd3d13ce92c34905fd907eb53</citedby><cites>FETCH-LOGICAL-c2707-87019406aa4a384ba3e4949ac9937b966cade9d9fd3d13ce92c34905fd907eb53</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10853-017-1818-7$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10853-017-1818-7$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Jing, Shengyu</creatorcontrib><creatorcontrib>Zhang, Maoshen</creatorcontrib><creatorcontrib>Liang, Huagen</creatorcontrib><creatorcontrib>Shen, Baolong</creatorcontrib><creatorcontrib>Yin, Shibin</creatorcontrib><creatorcontrib>Yang, Xu</creatorcontrib><title>Facile synthesis of 3D binder-free N-doped carbon nanonet derived from silkworm cocoon for Li–O2 battery</title><title>Journal of materials science</title><addtitle>J Mater Sci</addtitle><description>Rechargeable nonaqueous lithium–O
2
batteries are considered as the most promising energy storage system for electric vehicles due to their extremely high energy density. However, the inefficient O
2
diffusion, large overpotential and unwanted side reaction still restrict their specific capacity and cycle performance. This work presents a facile method to prepare a novel 3D binder-free N-doped carbon nanonet by using an economical, green and sustainable biomass—silkworm cocoon as the precursor. Li–O
2
batteries with this N-doped carbon nanonet as the cathode delivered a superior specific capacity and excellent cycling stability, which attributable to the 3D porous and through structure, high specific surface area, the enhanced catalytic activity of ORR/OER arising from the incorporation of N, and the absence of binders in the electrode. Therefore, by taking advantages of the unique structure and morphology of biomass, the low-cost and green 3D binder-free N-doped carbon materials are a feasible approach for the preparation of high-performance cathode for Li–O
2
battery.</description><subject>Biomass</subject><subject>Carbon</subject><subject>Catalysis</subject><subject>Catalytic activity</subject><subject>Cathodes</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry and Materials Science</subject><subject>Classical Mechanics</subject><subject>Crystallography and Scattering Methods</subject><subject>Electric vehicles</subject><subject>Energy Materials</subject><subject>Energy storage</subject><subject>Flux density</subject><subject>Lithium</subject><subject>Materials Science</subject><subject>Morphology</subject><subject>Polymer Sciences</subject><subject>Rechargeable batteries</subject><subject>Silkworms</subject><subject>Solid Mechanics</subject><subject>Storage batteries</subject><issn>0022-2461</issn><issn>1573-4803</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><sourceid>BENPR</sourceid><recordid>eNp1kMtKAzEUhoMoWKsP4C7gOnpymclkKfUKxW50HTJJRqe2SU2mSne-g2_ok5hSwZWrA-d8_3_gQ-iUwjkFkBeZQlNxAlQS2tCGyD00opXkRDTA99EIgDHCRE0P0VHOcwCoJKMjNL8xtl94nDdhePG5zzh2mF_htg_OJ9Il7_EDcXHlHbYmtTHgYEIMfsDl3r-XdZfiEud-8foR0xLbaGOBupjwtP_-_Jox3Jph8GlzjA46s8j-5HeO0dPN9ePkjkxnt_eTyymxTIIkjQSqBNTGCMMb0RruhRLKWKW4bFVdW-O8cqpz3FFuvWKWCwVV5xRI31Z8jM52vasU39Y-D3oe1ymUl5qxStVUSQGFojvKpphz8p1epX5p0kZT0FuleqdUF6V6q1TLkmG7TC5sePbpr_n_0A9mUXm2</recordid><startdate>20180301</startdate><enddate>20180301</enddate><creator>Jing, Shengyu</creator><creator>Zhang, Maoshen</creator><creator>Liang, Huagen</creator><creator>Shen, Baolong</creator><creator>Yin, Shibin</creator><creator>Yang, Xu</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>L6V</scope><scope>M7S</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>PTHSS</scope></search><sort><creationdate>20180301</creationdate><title>Facile synthesis of 3D binder-free N-doped carbon nanonet derived from silkworm cocoon for Li–O2 battery</title><author>Jing, Shengyu ; Zhang, Maoshen ; Liang, Huagen ; Shen, Baolong ; Yin, Shibin ; Yang, Xu</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c2707-87019406aa4a384ba3e4949ac9937b966cade9d9fd3d13ce92c34905fd907eb53</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Biomass</topic><topic>Carbon</topic><topic>Catalysis</topic><topic>Catalytic activity</topic><topic>Cathodes</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry and Materials Science</topic><topic>Classical Mechanics</topic><topic>Crystallography and Scattering Methods</topic><topic>Electric vehicles</topic><topic>Energy Materials</topic><topic>Energy storage</topic><topic>Flux density</topic><topic>Lithium</topic><topic>Materials Science</topic><topic>Morphology</topic><topic>Polymer Sciences</topic><topic>Rechargeable batteries</topic><topic>Silkworms</topic><topic>Solid Mechanics</topic><topic>Storage batteries</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Jing, Shengyu</creatorcontrib><creatorcontrib>Zhang, Maoshen</creatorcontrib><creatorcontrib>Liang, Huagen</creatorcontrib><creatorcontrib>Shen, Baolong</creatorcontrib><creatorcontrib>Yin, Shibin</creatorcontrib><creatorcontrib>Yang, Xu</creatorcontrib><collection>CrossRef</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>ProQuest Engineering Collection</collection><collection>Engineering Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>Engineering Collection</collection><jtitle>Journal of materials science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Jing, Shengyu</au><au>Zhang, Maoshen</au><au>Liang, Huagen</au><au>Shen, Baolong</au><au>Yin, Shibin</au><au>Yang, Xu</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Facile synthesis of 3D binder-free N-doped carbon nanonet derived from silkworm cocoon for Li–O2 battery</atitle><jtitle>Journal of materials science</jtitle><stitle>J Mater Sci</stitle><date>2018-03-01</date><risdate>2018</risdate><volume>53</volume><issue>6</issue><spage>4395</spage><epage>4405</epage><pages>4395-4405</pages><issn>0022-2461</issn><eissn>1573-4803</eissn><abstract>Rechargeable nonaqueous lithium–O
2
batteries are considered as the most promising energy storage system for electric vehicles due to their extremely high energy density. However, the inefficient O
2
diffusion, large overpotential and unwanted side reaction still restrict their specific capacity and cycle performance. This work presents a facile method to prepare a novel 3D binder-free N-doped carbon nanonet by using an economical, green and sustainable biomass—silkworm cocoon as the precursor. Li–O
2
batteries with this N-doped carbon nanonet as the cathode delivered a superior specific capacity and excellent cycling stability, which attributable to the 3D porous and through structure, high specific surface area, the enhanced catalytic activity of ORR/OER arising from the incorporation of N, and the absence of binders in the electrode. Therefore, by taking advantages of the unique structure and morphology of biomass, the low-cost and green 3D binder-free N-doped carbon materials are a feasible approach for the preparation of high-performance cathode for Li–O
2
battery.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10853-017-1818-7</doi><tpages>11</tpages></addata></record> |
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| subjects | Biomass Carbon Catalysis Catalytic activity Cathodes Characterization and Evaluation of Materials Chemistry and Materials Science Classical Mechanics Crystallography and Scattering Methods Electric vehicles Energy Materials Energy storage Flux density Lithium Materials Science Morphology Polymer Sciences Rechargeable batteries Silkworms Solid Mechanics Storage batteries |
| title | Facile synthesis of 3D binder-free N-doped carbon nanonet derived from silkworm cocoon for Li–O2 battery |
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