Facile synthesis of nitrogen-containing porous carbon as electrode materials for superior-performance electrical double-layer capacitors

Nitrogen-containing porous carbons with numerous micropores were fabricated by pyrolysing polyvinylidene fluoride (PVDF) membrane following potassium hydroxide (KOH) activation at 600–900 °C for 2 h under N 2 atmosphere. The fabricated nitrogen-containing porous carbons have a large specific surface...

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Veröffentlicht in:Journal of materials science 2018-02, Vol.53 (3), p.2137-2148
Hauptverfasser: Chen, Jing, Wei, Huanming, Fu, Ning, Chen, Haijun, Lan, Guoxian, Lin, Hualin, Han, Sheng
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container_end_page 2148
container_issue 3
container_start_page 2137
container_title Journal of materials science
container_volume 53
creator Chen, Jing
Wei, Huanming
Fu, Ning
Chen, Haijun
Lan, Guoxian
Lin, Hualin
Han, Sheng
description Nitrogen-containing porous carbons with numerous micropores were fabricated by pyrolysing polyvinylidene fluoride (PVDF) membrane following potassium hydroxide (KOH) activation at 600–900 °C for 2 h under N 2 atmosphere. The fabricated nitrogen-containing porous carbons have a large specific surface area of approximately 2289 m 2  g −1 , a certain nitrogen content of 1.35 at.% and a favourable hierarchical porous structure possessing a great number of micropores and a part of mesopores. The carbon materials exhibit high specific capacitance of 338 F g −1 at 0.5 A g −1 in a 6 M KOH and outstanding cycling property of 91.6% maintenance at 2 A g −1 after 10000 cycles. An all-solid-state symmetrical supercapacitor with these as-prepared materials as electrodes can deliver energy densities of 21.9 to 10.4 W h kg −1 at power densities from 700.8 to 12910.3 W kg −1 . To sum up, the as-obtained porous carbon is a type of potential electrode material for electrical double-layer capacitor.
doi_str_mv 10.1007/s10853-017-1664-7
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subjects Capacitors
Carbon
Characterization and Evaluation of Materials
Chemistry and Materials Science
Circuit components
Classical Mechanics
Crystallography and Scattering Methods
Electrode materials
Electrodes
Electronic components industry
Energy Materials
Hydroxides
Materials Science
Nitrogen
Polymer Sciences
Polyvinylidene fluoride
Polyvinylidene fluorides
Porous materials
Potassium hydroxides
Solid Mechanics
Structural hierarchy
title Facile synthesis of nitrogen-containing porous carbon as electrode materials for superior-performance electrical double-layer capacitors
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