Experimental investigation on phase equilibria of Cu–Ti–Hf system and performance of Cu(Ti, Hf)2 phase
Phase relations in Cu–Ti–Hf ternary system have been studied by diffusion triple technique supplemented with typical alloy sampling method. Based on results from electron-probe microscopy analysis and X-ray diffraction, isothermal sections of the Cu–Ti–Hf system at 800 and 700 °C were established, w...
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creator | Liu, J. L. Huang, X. M. Li, G. H. Cai, G. M. Liu, H. S. Jin, Z. P. |
description | Phase relations in Cu–Ti–Hf ternary system have been studied by diffusion triple technique supplemented with typical alloy sampling method. Based on results from electron-probe microscopy analysis and X-ray diffraction, isothermal sections of the Cu–Ti–Hf system at 800 and 700 °C were established, which consist of ten and nine three-phase regions, respectively. It is observed that Ti can completely substitute Hf in the CuHf
2
phase, indicating formation of a continuous solid solution Cu(Ti,Hf)
2
. Hf can substitute about 20% Ti in the phase CuTi, while solubility of Ti in Cu
10
Hf
7
and Cu
51
Hf
14
phases reaches to 14 and 11 at.% at 800 °C, respectively. The Cu
8
Hf
3
phase in existence at 800 °C was proved to be unstable at 700 °C. In addition, the elastic modulus and hardness of solid solution Cu(Ti,Hf)
2
were determined by using nano-indentation techniques. |
doi_str_mv | 10.1007/s10853-018-2058-1 |
format | Article |
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2
phase, indicating formation of a continuous solid solution Cu(Ti,Hf)
2
. Hf can substitute about 20% Ti in the phase CuTi, while solubility of Ti in Cu
10
Hf
7
and Cu
51
Hf
14
phases reaches to 14 and 11 at.% at 800 °C, respectively. The Cu
8
Hf
3
phase in existence at 800 °C was proved to be unstable at 700 °C. In addition, the elastic modulus and hardness of solid solution Cu(Ti,Hf)
2
were determined by using nano-indentation techniques.</description><identifier>ISSN: 0022-2461</identifier><identifier>EISSN: 1573-4803</identifier><identifier>DOI: 10.1007/s10853-018-2058-1</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Characterization and Evaluation of Materials ; Chemistry and Materials Science ; Classical Mechanics ; Copper ; Crystallography and Scattering Methods ; Hafnium ; Materials Science ; Metals ; Modulus of elasticity ; Nanoindentation ; Phase equilibria ; Polymer Sciences ; Solid Mechanics ; Solid solutions ; Substitutes ; Ternary systems ; X-ray diffraction</subject><ispartof>Journal of materials science, 2018-05, Vol.53 (10), p.7809-7821</ispartof><rights>Springer Science+Business Media, LLC, part of Springer Nature 2018</rights><rights>Journal of Materials Science is a copyright of Springer, (2018). All Rights Reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c316t-ec94c033ddd1eccbab569be6ad4e7136fb9de871923a4f43bc26dc79e7346be73</citedby><cites>FETCH-LOGICAL-c316t-ec94c033ddd1eccbab569be6ad4e7136fb9de871923a4f43bc26dc79e7346be73</cites><orcidid>0000-0001-9046-6397</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10853-018-2058-1$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10853-018-2058-1$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27903,27904,41467,42536,51298</link.rule.ids></links><search><creatorcontrib>Liu, J. L.</creatorcontrib><creatorcontrib>Huang, X. M.</creatorcontrib><creatorcontrib>Li, G. H.</creatorcontrib><creatorcontrib>Cai, G. M.</creatorcontrib><creatorcontrib>Liu, H. S.</creatorcontrib><creatorcontrib>Jin, Z. P.</creatorcontrib><title>Experimental investigation on phase equilibria of Cu–Ti–Hf system and performance of Cu(Ti, Hf)2 phase</title><title>Journal of materials science</title><addtitle>J Mater Sci</addtitle><description>Phase relations in Cu–Ti–Hf ternary system have been studied by diffusion triple technique supplemented with typical alloy sampling method. Based on results from electron-probe microscopy analysis and X-ray diffraction, isothermal sections of the Cu–Ti–Hf system at 800 and 700 °C were established, which consist of ten and nine three-phase regions, respectively. It is observed that Ti can completely substitute Hf in the CuHf
2
phase, indicating formation of a continuous solid solution Cu(Ti,Hf)
2
. Hf can substitute about 20% Ti in the phase CuTi, while solubility of Ti in Cu
10
Hf
7
and Cu
51
Hf
14
phases reaches to 14 and 11 at.% at 800 °C, respectively. The Cu
8
Hf
3
phase in existence at 800 °C was proved to be unstable at 700 °C. In addition, the elastic modulus and hardness of solid solution Cu(Ti,Hf)
2
were determined by using nano-indentation techniques.</description><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry and Materials Science</subject><subject>Classical Mechanics</subject><subject>Copper</subject><subject>Crystallography and Scattering Methods</subject><subject>Hafnium</subject><subject>Materials Science</subject><subject>Metals</subject><subject>Modulus of elasticity</subject><subject>Nanoindentation</subject><subject>Phase equilibria</subject><subject>Polymer Sciences</subject><subject>Solid Mechanics</subject><subject>Solid solutions</subject><subject>Substitutes</subject><subject>Ternary systems</subject><subject>X-ray diffraction</subject><issn>0022-2461</issn><issn>1573-4803</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNp1kMFKAzEQhoMoWKsP4C3gRcFoJtnN7h6lVCsUvNRzyGZna0q72ya7Ym--g2_ok5iygidh-Ofy__8wHyGXwO-A8-w-AM9TyTjkTPA0Z3BERpBmkiU5l8dkxLkQTCQKTslZCCvOeZoJGJHV9GOL3m2w6cyauuYdQ-eWpnNtQ-Ns30xAirverV3pnaFtTSf99-fXwkWZ1TTsQ4cbapqKxp669RvTWBxs1wt3S2f1jRhqzslJbdYBL373mLw-TheTGZu_PD1PHubMSlAdQ1sklktZVRWgtaUpU1WUqEyVYAZS1WVRYZ5BIaRJ6kSWVqjKZgVmMlFl1DG5Gnq3vt318R-9anvfxJNaiLRQIAQcXDC4rG9D8FjrbcRg_F4D1wekekCqI1J9QKohZsSQCdHbLNH_Nf8f-gHK_3uo</recordid><startdate>20180501</startdate><enddate>20180501</enddate><creator>Liu, J. L.</creator><creator>Huang, X. M.</creator><creator>Li, G. H.</creator><creator>Cai, G. M.</creator><creator>Liu, H. S.</creator><creator>Jin, Z. P.</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>L6V</scope><scope>M7S</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>PTHSS</scope><orcidid>https://orcid.org/0000-0001-9046-6397</orcidid></search><sort><creationdate>20180501</creationdate><title>Experimental investigation on phase equilibria of Cu–Ti–Hf system and performance of Cu(Ti, Hf)2 phase</title><author>Liu, J. L. ; Huang, X. M. ; Li, G. H. ; Cai, G. M. ; Liu, H. S. ; Jin, Z. P.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c316t-ec94c033ddd1eccbab569be6ad4e7136fb9de871923a4f43bc26dc79e7346be73</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry and Materials Science</topic><topic>Classical Mechanics</topic><topic>Copper</topic><topic>Crystallography and Scattering Methods</topic><topic>Hafnium</topic><topic>Materials Science</topic><topic>Metals</topic><topic>Modulus of elasticity</topic><topic>Nanoindentation</topic><topic>Phase equilibria</topic><topic>Polymer Sciences</topic><topic>Solid Mechanics</topic><topic>Solid solutions</topic><topic>Substitutes</topic><topic>Ternary systems</topic><topic>X-ray diffraction</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Liu, J. L.</creatorcontrib><creatorcontrib>Huang, X. M.</creatorcontrib><creatorcontrib>Li, G. H.</creatorcontrib><creatorcontrib>Cai, G. M.</creatorcontrib><creatorcontrib>Liu, H. S.</creatorcontrib><creatorcontrib>Jin, Z. P.</creatorcontrib><collection>CrossRef</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>ProQuest Engineering Collection</collection><collection>Engineering Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>Engineering Collection</collection><jtitle>Journal of materials science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Liu, J. L.</au><au>Huang, X. M.</au><au>Li, G. H.</au><au>Cai, G. M.</au><au>Liu, H. S.</au><au>Jin, Z. P.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Experimental investigation on phase equilibria of Cu–Ti–Hf system and performance of Cu(Ti, Hf)2 phase</atitle><jtitle>Journal of materials science</jtitle><stitle>J Mater Sci</stitle><date>2018-05-01</date><risdate>2018</risdate><volume>53</volume><issue>10</issue><spage>7809</spage><epage>7821</epage><pages>7809-7821</pages><issn>0022-2461</issn><eissn>1573-4803</eissn><abstract>Phase relations in Cu–Ti–Hf ternary system have been studied by diffusion triple technique supplemented with typical alloy sampling method. Based on results from electron-probe microscopy analysis and X-ray diffraction, isothermal sections of the Cu–Ti–Hf system at 800 and 700 °C were established, which consist of ten and nine three-phase regions, respectively. It is observed that Ti can completely substitute Hf in the CuHf
2
phase, indicating formation of a continuous solid solution Cu(Ti,Hf)
2
. Hf can substitute about 20% Ti in the phase CuTi, while solubility of Ti in Cu
10
Hf
7
and Cu
51
Hf
14
phases reaches to 14 and 11 at.% at 800 °C, respectively. The Cu
8
Hf
3
phase in existence at 800 °C was proved to be unstable at 700 °C. In addition, the elastic modulus and hardness of solid solution Cu(Ti,Hf)
2
were determined by using nano-indentation techniques.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10853-018-2058-1</doi><tpages>13</tpages><orcidid>https://orcid.org/0000-0001-9046-6397</orcidid></addata></record> |
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source | Springer Nature - Complete Springer Journals |
subjects | Characterization and Evaluation of Materials Chemistry and Materials Science Classical Mechanics Copper Crystallography and Scattering Methods Hafnium Materials Science Metals Modulus of elasticity Nanoindentation Phase equilibria Polymer Sciences Solid Mechanics Solid solutions Substitutes Ternary systems X-ray diffraction |
title | Experimental investigation on phase equilibria of Cu–Ti–Hf system and performance of Cu(Ti, Hf)2 phase |
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