Experimental investigation on phase equilibria of Cu–Ti–Hf system and performance of Cu(Ti, Hf)2 phase

Phase relations in Cu–Ti–Hf ternary system have been studied by diffusion triple technique supplemented with typical alloy sampling method. Based on results from electron-probe microscopy analysis and X-ray diffraction, isothermal sections of the Cu–Ti–Hf system at 800 and 700 °C were established, w...

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Veröffentlicht in:Journal of materials science 2018-05, Vol.53 (10), p.7809-7821
Hauptverfasser: Liu, J. L., Huang, X. M., Li, G. H., Cai, G. M., Liu, H. S., Jin, Z. P.
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container_issue 10
container_start_page 7809
container_title Journal of materials science
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creator Liu, J. L.
Huang, X. M.
Li, G. H.
Cai, G. M.
Liu, H. S.
Jin, Z. P.
description Phase relations in Cu–Ti–Hf ternary system have been studied by diffusion triple technique supplemented with typical alloy sampling method. Based on results from electron-probe microscopy analysis and X-ray diffraction, isothermal sections of the Cu–Ti–Hf system at 800 and 700 °C were established, which consist of ten and nine three-phase regions, respectively. It is observed that Ti can completely substitute Hf in the CuHf 2 phase, indicating formation of a continuous solid solution Cu(Ti,Hf) 2 . Hf can substitute about 20% Ti in the phase CuTi, while solubility of Ti in Cu 10 Hf 7 and Cu 51 Hf 14 phases reaches to 14 and 11 at.% at 800 °C, respectively. The Cu 8 Hf 3 phase in existence at 800 °C was proved to be unstable at 700 °C. In addition, the elastic modulus and hardness of solid solution Cu(Ti,Hf) 2 were determined by using nano-indentation techniques.
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The Cu 8 Hf 3 phase in existence at 800 °C was proved to be unstable at 700 °C. 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subjects Characterization and Evaluation of Materials
Chemistry and Materials Science
Classical Mechanics
Copper
Crystallography and Scattering Methods
Hafnium
Materials Science
Metals
Modulus of elasticity
Nanoindentation
Phase equilibria
Polymer Sciences
Solid Mechanics
Solid solutions
Substitutes
Ternary systems
X-ray diffraction
title Experimental investigation on phase equilibria of Cu–Ti–Hf system and performance of Cu(Ti, Hf)2 phase
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