Growth and physical properties of large MoO3 single crystals

Molybdenum trioxide (MoO 3 ) is an interesting material for smart windows, electrodes for batteries, and gas sensors. So far, it is known that the growth of large single crystal of MoO 3 is elusive because of the rapid changing of activation energy at 650 °C. Small MoO 3 crystals can be made by subl...

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Veröffentlicht in:Journal of materials science 2016-10, Vol.51 (19), p.8928-8934
Hauptverfasser: Kong, Hyeonjun, Ahn, Eunyoung, Ryu, Sangkyun, Kim, Ji Woong, Cho, Jinhyung, Park, Sungkyun, Kim, Dongjin, Jeen, Gwang-Soo, Lee, Inwon, Jeen, Hyoungjeen
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container_end_page 8934
container_issue 19
container_start_page 8928
container_title Journal of materials science
container_volume 51
creator Kong, Hyeonjun
Ahn, Eunyoung
Ryu, Sangkyun
Kim, Ji Woong
Cho, Jinhyung
Park, Sungkyun
Kim, Dongjin
Jeen, Gwang-Soo
Lee, Inwon
Jeen, Hyoungjeen
description Molybdenum trioxide (MoO 3 ) is an interesting material for smart windows, electrodes for batteries, and gas sensors. So far, it is known that the growth of large single crystal of MoO 3 is elusive because of the rapid changing of activation energy at 650 °C. Small MoO 3 crystals can be made by sublimation. In this study, we successfully grew large MoO 3 single crystals through the modified vertical Bridgman method, which can prevent the sublimation of MoO 3 . Similar structural and optical properties were measured like those of nano/micro-crystalline MoO 3 . This study can provide evidence to contribute to the creation of large single crystals, which have a lower sublimation temperature than melting temperature.
doi_str_mv 10.1007/s10853-016-0144-9
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subjects Bridgman method
Characterization and Evaluation of Materials
Chemistry and Materials Science
Classical Mechanics
Crystal growth
Crystallography and Scattering Methods
Gas sensors
Materials Science
Melt temperature
Molybdenum oxides
Molybdenum trioxide
Optical properties
Original Paper
Physical properties
Polymer Sciences
Single crystals
Smart materials
Solid Mechanics
Sublimation
title Growth and physical properties of large MoO3 single crystals
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