Covalent grafting of triazine derivatives onto graphene oxide for preparation of epoxy composites with improved interfacial and mechanical properties
Interface interactions are the important problems in improving the mechanical properties of graphene and polymer composites. In this work, a simple method is proposed to prepare epoxy composites with admirable properties through constructing dendrimers with cyanuric chloride (TCT) and diethylenetria...
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| Veröffentlicht in: | Journal of materials science 2018-12, Vol.53 (24), p.16318-16330 |
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| creator | Guo, Shimei Ma, Lichun Song, Guojun Li, Xiaoru Li, Peiyao Wang, Mingye Shi, Longlong Gu, Zheng Huang, Yudong |
| description | Interface interactions are the important problems in improving the mechanical properties of graphene and polymer composites. In this work, a simple method is proposed to prepare epoxy composites with admirable properties through constructing dendrimers with cyanuric chloride (TCT) and diethylenetriamine (DETA) onto graphene oxide (GO) surface. The FTIR, XRD, XPS, Raman spectroscopy, SEM and TEM were used to confirm the successful grafting of TCT and DETA molecules onto the surface of GO. The interfacial adhesion between GO–TCT–DETA and epoxy resin is enhanced due to the formation of a strong chemical bond between the amino group on the GO surface and the epoxy resins. The tensile and flexural strength of GO–TCT–DETA/epoxy composites have considerable improvement (40.79 and 48.56%) compared with that of epoxy resin due to stronger interfacial interaction. In addition, the strengthening mechanism and dispersion of GO–TCT–DETA in epoxy matrix were also demonstrated. |
| doi_str_mv | 10.1007/s10853-018-2788-0 |
| format | Article |
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In this work, a simple method is proposed to prepare epoxy composites with admirable properties through constructing dendrimers with cyanuric chloride (TCT) and diethylenetriamine (DETA) onto graphene oxide (GO) surface. The FTIR, XRD, XPS, Raman spectroscopy, SEM and TEM were used to confirm the successful grafting of TCT and DETA molecules onto the surface of GO. The interfacial adhesion between GO–TCT–DETA and epoxy resin is enhanced due to the formation of a strong chemical bond between the amino group on the GO surface and the epoxy resins. The tensile and flexural strength of GO–TCT–DETA/epoxy composites have considerable improvement (40.79 and 48.56%) compared with that of epoxy resin due to stronger interfacial interaction. In addition, the strengthening mechanism and dispersion of GO–TCT–DETA in epoxy matrix were also demonstrated.</description><identifier>ISSN: 0022-2461</identifier><identifier>EISSN: 1573-4803</identifier><identifier>DOI: 10.1007/s10853-018-2788-0</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Characterization and Evaluation of Materials ; Chemical bonds ; Chemical properties ; Chemistry and Materials Science ; Classical Mechanics ; Composites ; Crystallography and Scattering Methods ; Dendrimers ; Epoxy matrix composites ; Epoxy resins ; Grafting ; Graphene ; Graphite ; Materials Science ; Mechanical properties ; Organic chemistry ; Polymer matrix composites ; Polymer Sciences ; Raman spectroscopy ; Rapid prototyping ; Solid Mechanics ; X ray photoelectron spectroscopy</subject><ispartof>Journal of materials science, 2018-12, Vol.53 (24), p.16318-16330</ispartof><rights>Springer Science+Business Media, LLC, part of Springer Nature 2018</rights><rights>COPYRIGHT 2018 Springer</rights><rights>Journal of Materials Science is a copyright of Springer, (2018). All Rights Reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c389t-21a46e89946f8d2f397629397845bf73074c3edd4594025f9a57e03ef743275c3</citedby><cites>FETCH-LOGICAL-c389t-21a46e89946f8d2f397629397845bf73074c3edd4594025f9a57e03ef743275c3</cites><orcidid>0000-0002-3829-3414 ; 0000-0002-5769-4360 ; 0000-0002-8957-5251 ; 0000-0002-9447-0323 ; 0000-0002-1268-5313 ; 0000-0002-7044-5545 ; 0000-0001-9521-2863 ; 0000-0001-6614-3395 ; 0000-0002-0208-7563</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10853-018-2788-0$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10853-018-2788-0$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Guo, Shimei</creatorcontrib><creatorcontrib>Ma, Lichun</creatorcontrib><creatorcontrib>Song, Guojun</creatorcontrib><creatorcontrib>Li, Xiaoru</creatorcontrib><creatorcontrib>Li, Peiyao</creatorcontrib><creatorcontrib>Wang, Mingye</creatorcontrib><creatorcontrib>Shi, Longlong</creatorcontrib><creatorcontrib>Gu, Zheng</creatorcontrib><creatorcontrib>Huang, Yudong</creatorcontrib><title>Covalent grafting of triazine derivatives onto graphene oxide for preparation of epoxy composites with improved interfacial and mechanical properties</title><title>Journal of materials science</title><addtitle>J Mater Sci</addtitle><description>Interface interactions are the important problems in improving the mechanical properties of graphene and polymer composites. In this work, a simple method is proposed to prepare epoxy composites with admirable properties through constructing dendrimers with cyanuric chloride (TCT) and diethylenetriamine (DETA) onto graphene oxide (GO) surface. The FTIR, XRD, XPS, Raman spectroscopy, SEM and TEM were used to confirm the successful grafting of TCT and DETA molecules onto the surface of GO. The interfacial adhesion between GO–TCT–DETA and epoxy resin is enhanced due to the formation of a strong chemical bond between the amino group on the GO surface and the epoxy resins. The tensile and flexural strength of GO–TCT–DETA/epoxy composites have considerable improvement (40.79 and 48.56%) compared with that of epoxy resin due to stronger interfacial interaction. In addition, the strengthening mechanism and dispersion of GO–TCT–DETA in epoxy matrix were also demonstrated.</description><subject>Characterization and Evaluation of Materials</subject><subject>Chemical bonds</subject><subject>Chemical properties</subject><subject>Chemistry and Materials Science</subject><subject>Classical Mechanics</subject><subject>Composites</subject><subject>Crystallography and Scattering Methods</subject><subject>Dendrimers</subject><subject>Epoxy matrix composites</subject><subject>Epoxy resins</subject><subject>Grafting</subject><subject>Graphene</subject><subject>Graphite</subject><subject>Materials Science</subject><subject>Mechanical properties</subject><subject>Organic chemistry</subject><subject>Polymer matrix composites</subject><subject>Polymer Sciences</subject><subject>Raman spectroscopy</subject><subject>Rapid prototyping</subject><subject>Solid Mechanics</subject><subject>X ray photoelectron spectroscopy</subject><issn>0022-2461</issn><issn>1573-4803</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNp1kcuKHCEUhiUkkM4kD5CdkFUWNfFaWsuhyWVgYCCXtRjrWO3QpRW1Oz15j7xv7FRgmEUUFPX7POKP0GtKLikh6l2hREveEao7prTuyBO0oVLxTmjCn6INIYx1TPT0OXpRyh0hRCpGN-j3Nh3tHmLFU7a-hjjh5HHNwf4KEfAIORxtDUcoOMWaztSyg3aSTmEE7FPGS4bF5galeHZhSad77NK8pBJq836GusNhXnI6wohDrJC9dcHusY0jnsHtbAyuLRuxQK4Bykv0zNt9gVf_5gv07cP7r9tP3c3tx-vt1U3nuB5qx6gVPehhEL3XI_N8UD0b2qiF_O4VJ0o4DuMo5CAIk36wUgHh4JXgTEnHL9Cb9d5W-scBSjV36ZBjK2kYk0NPW5ONulypqf2UCdGnmq1rfYQ5uBTBh7Z_JWXj--Gv8PaR0JgKpzrZQynm-svnxyxdWZdTKRm8WXKYbb43lJhztGaN1rRozTlaQ5rDVqc0Nk6QH579f-kPseGoPg</recordid><startdate>20181201</startdate><enddate>20181201</enddate><creator>Guo, Shimei</creator><creator>Ma, Lichun</creator><creator>Song, Guojun</creator><creator>Li, Xiaoru</creator><creator>Li, Peiyao</creator><creator>Wang, Mingye</creator><creator>Shi, Longlong</creator><creator>Gu, Zheng</creator><creator>Huang, Yudong</creator><general>Springer US</general><general>Springer</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>ISR</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>L6V</scope><scope>M7S</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>PTHSS</scope><orcidid>https://orcid.org/0000-0002-3829-3414</orcidid><orcidid>https://orcid.org/0000-0002-5769-4360</orcidid><orcidid>https://orcid.org/0000-0002-8957-5251</orcidid><orcidid>https://orcid.org/0000-0002-9447-0323</orcidid><orcidid>https://orcid.org/0000-0002-1268-5313</orcidid><orcidid>https://orcid.org/0000-0002-7044-5545</orcidid><orcidid>https://orcid.org/0000-0001-9521-2863</orcidid><orcidid>https://orcid.org/0000-0001-6614-3395</orcidid><orcidid>https://orcid.org/0000-0002-0208-7563</orcidid></search><sort><creationdate>20181201</creationdate><title>Covalent grafting of triazine derivatives onto graphene oxide for preparation of epoxy composites with improved interfacial and mechanical properties</title><author>Guo, Shimei ; Ma, Lichun ; Song, Guojun ; Li, Xiaoru ; Li, Peiyao ; Wang, Mingye ; Shi, Longlong ; Gu, Zheng ; Huang, Yudong</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c389t-21a46e89946f8d2f397629397845bf73074c3edd4594025f9a57e03ef743275c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Characterization and Evaluation of Materials</topic><topic>Chemical bonds</topic><topic>Chemical properties</topic><topic>Chemistry and Materials Science</topic><topic>Classical Mechanics</topic><topic>Composites</topic><topic>Crystallography and Scattering Methods</topic><topic>Dendrimers</topic><topic>Epoxy matrix composites</topic><topic>Epoxy resins</topic><topic>Grafting</topic><topic>Graphene</topic><topic>Graphite</topic><topic>Materials Science</topic><topic>Mechanical properties</topic><topic>Organic chemistry</topic><topic>Polymer matrix composites</topic><topic>Polymer Sciences</topic><topic>Raman spectroscopy</topic><topic>Rapid prototyping</topic><topic>Solid Mechanics</topic><topic>X ray photoelectron spectroscopy</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Guo, Shimei</creatorcontrib><creatorcontrib>Ma, Lichun</creatorcontrib><creatorcontrib>Song, Guojun</creatorcontrib><creatorcontrib>Li, Xiaoru</creatorcontrib><creatorcontrib>Li, Peiyao</creatorcontrib><creatorcontrib>Wang, Mingye</creatorcontrib><creatorcontrib>Shi, Longlong</creatorcontrib><creatorcontrib>Gu, Zheng</creatorcontrib><creatorcontrib>Huang, Yudong</creatorcontrib><collection>CrossRef</collection><collection>Gale In Context: Science</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>ProQuest Engineering Collection</collection><collection>Engineering Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>Engineering Collection</collection><jtitle>Journal of materials science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Guo, Shimei</au><au>Ma, Lichun</au><au>Song, Guojun</au><au>Li, Xiaoru</au><au>Li, Peiyao</au><au>Wang, Mingye</au><au>Shi, Longlong</au><au>Gu, Zheng</au><au>Huang, Yudong</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Covalent grafting of triazine derivatives onto graphene oxide for preparation of epoxy composites with improved interfacial and mechanical properties</atitle><jtitle>Journal of materials science</jtitle><stitle>J Mater Sci</stitle><date>2018-12-01</date><risdate>2018</risdate><volume>53</volume><issue>24</issue><spage>16318</spage><epage>16330</epage><pages>16318-16330</pages><issn>0022-2461</issn><eissn>1573-4803</eissn><abstract>Interface interactions are the important problems in improving the mechanical properties of graphene and polymer composites. In this work, a simple method is proposed to prepare epoxy composites with admirable properties through constructing dendrimers with cyanuric chloride (TCT) and diethylenetriamine (DETA) onto graphene oxide (GO) surface. The FTIR, XRD, XPS, Raman spectroscopy, SEM and TEM were used to confirm the successful grafting of TCT and DETA molecules onto the surface of GO. The interfacial adhesion between GO–TCT–DETA and epoxy resin is enhanced due to the formation of a strong chemical bond between the amino group on the GO surface and the epoxy resins. The tensile and flexural strength of GO–TCT–DETA/epoxy composites have considerable improvement (40.79 and 48.56%) compared with that of epoxy resin due to stronger interfacial interaction. In addition, the strengthening mechanism and dispersion of GO–TCT–DETA in epoxy matrix were also demonstrated.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10853-018-2788-0</doi><tpages>13</tpages><orcidid>https://orcid.org/0000-0002-3829-3414</orcidid><orcidid>https://orcid.org/0000-0002-5769-4360</orcidid><orcidid>https://orcid.org/0000-0002-8957-5251</orcidid><orcidid>https://orcid.org/0000-0002-9447-0323</orcidid><orcidid>https://orcid.org/0000-0002-1268-5313</orcidid><orcidid>https://orcid.org/0000-0002-7044-5545</orcidid><orcidid>https://orcid.org/0000-0001-9521-2863</orcidid><orcidid>https://orcid.org/0000-0001-6614-3395</orcidid><orcidid>https://orcid.org/0000-0002-0208-7563</orcidid></addata></record> |
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| subjects | Characterization and Evaluation of Materials Chemical bonds Chemical properties Chemistry and Materials Science Classical Mechanics Composites Crystallography and Scattering Methods Dendrimers Epoxy matrix composites Epoxy resins Grafting Graphene Graphite Materials Science Mechanical properties Organic chemistry Polymer matrix composites Polymer Sciences Raman spectroscopy Rapid prototyping Solid Mechanics X ray photoelectron spectroscopy |
| title | Covalent grafting of triazine derivatives onto graphene oxide for preparation of epoxy composites with improved interfacial and mechanical properties |
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