Inhibition effect of nicotinamide and its Mannich base derivatives on mild steel corrosion in HCl
Mannich base derivatives of nicotinamide (NA), namely N -(morpholino(phenyl)methyl)nicotinamide (NMB) and N -(phenyl(piperidin-1-yl)methyl) nicotinamide (NPB), were synthesized, characterized and studied as corrosion inhibitors for mild steel (MS) in 1.0 M hydrochloric acid using gravimetric, electr...
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| Veröffentlicht in: | Journal of materials science 2017-11, Vol.52 (21), p.12861-12888 |
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| creator | Jeeva, M. Venkatesa Prabhu, G. Rajesh, C. M. |
| description | Mannich base derivatives of nicotinamide (NA), namely
N
-(morpholino(phenyl)methyl)nicotinamide (NMB) and
N
-(phenyl(piperidin-1-yl)methyl) nicotinamide (NPB), were synthesized, characterized and studied as corrosion inhibitors for mild steel (MS) in 1.0 M hydrochloric acid using gravimetric, electrochemical experiments and theoretical calculations. Nicotinamide was also subjected for all these studies. The adsorption of NA, NMB and NPB molecules on the mild steel surface in the presence of 1.0 M HCl was found to be spontaneous and obey the Langmuir adsorption isotherm as well as Dubinin–Radushkevich isotherm. Tafel polarization measurements evidenced that all the studied inhibitors are of mixed type. EIS measurements showed that the addition of NA, NMB and NPB decreases the double-layer capacitance (
C
dl
) and consequently increases the charge transfer resistance (
R
CT
) of the corrosion process. FT-IR analysis, SEM micrographs and AFM analysis confirmed the presence of inhibitor film and its role on the MS surface. Quantum chemical calculations at the DFT level were achieved to correlate electronic structure parameters of NA, NMB and NPB molecules with the experimental results. |
| doi_str_mv | 10.1007/s10853-017-1401-2 |
| format | Article |
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N
-(morpholino(phenyl)methyl)nicotinamide (NMB) and
N
-(phenyl(piperidin-1-yl)methyl) nicotinamide (NPB), were synthesized, characterized and studied as corrosion inhibitors for mild steel (MS) in 1.0 M hydrochloric acid using gravimetric, electrochemical experiments and theoretical calculations. Nicotinamide was also subjected for all these studies. The adsorption of NA, NMB and NPB molecules on the mild steel surface in the presence of 1.0 M HCl was found to be spontaneous and obey the Langmuir adsorption isotherm as well as Dubinin–Radushkevich isotherm. Tafel polarization measurements evidenced that all the studied inhibitors are of mixed type. EIS measurements showed that the addition of NA, NMB and NPB decreases the double-layer capacitance (
C
dl
) and consequently increases the charge transfer resistance (
R
CT
) of the corrosion process. FT-IR analysis, SEM micrographs and AFM analysis confirmed the presence of inhibitor film and its role on the MS surface. Quantum chemical calculations at the DFT level were achieved to correlate electronic structure parameters of NA, NMB and NPB molecules with the experimental results.</description><identifier>ISSN: 0022-2461</identifier><identifier>EISSN: 1573-4803</identifier><identifier>DOI: 10.1007/s10853-017-1401-2</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Adsorption ; Characterization and Evaluation of Materials ; Charge transfer ; Chemistry and Materials Science ; Classical Mechanics ; Corrosion ; Corrosion effects ; Corrosion inhibitors ; Corrosion resistance ; Crystallography and Scattering Methods ; Derivatives ; Electronic structure ; Gravimetry ; Hydrochloric acid ; Infrared analysis ; Isotherms ; Low carbon steels ; Materials Science ; Mathematical analysis ; Metals ; Niacinamide ; Nicotinamide ; Organic chemistry ; Photomicrographs ; Polymer Sciences ; Quantum chemistry ; Reagents ; Solid Mechanics ; Steel corrosion ; Surface chemistry</subject><ispartof>Journal of materials science, 2017-11, Vol.52 (21), p.12861-12888</ispartof><rights>Springer Science+Business Media, LLC 2017</rights><rights>COPYRIGHT 2017 Springer</rights><rights>Journal of Materials Science is a copyright of Springer, (2017). All Rights Reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c417t-769b4e8e18197546b0b3510e43481991614faa24d6db54ea3b5334b610125ea63</citedby><cites>FETCH-LOGICAL-c417t-769b4e8e18197546b0b3510e43481991614faa24d6db54ea3b5334b610125ea63</cites><orcidid>0000-0002-5042-4018</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10853-017-1401-2$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10853-017-1401-2$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Jeeva, M.</creatorcontrib><creatorcontrib>Venkatesa Prabhu, G.</creatorcontrib><creatorcontrib>Rajesh, C. M.</creatorcontrib><title>Inhibition effect of nicotinamide and its Mannich base derivatives on mild steel corrosion in HCl</title><title>Journal of materials science</title><addtitle>J Mater Sci</addtitle><description>Mannich base derivatives of nicotinamide (NA), namely
N
-(morpholino(phenyl)methyl)nicotinamide (NMB) and
N
-(phenyl(piperidin-1-yl)methyl) nicotinamide (NPB), were synthesized, characterized and studied as corrosion inhibitors for mild steel (MS) in 1.0 M hydrochloric acid using gravimetric, electrochemical experiments and theoretical calculations. Nicotinamide was also subjected for all these studies. The adsorption of NA, NMB and NPB molecules on the mild steel surface in the presence of 1.0 M HCl was found to be spontaneous and obey the Langmuir adsorption isotherm as well as Dubinin–Radushkevich isotherm. Tafel polarization measurements evidenced that all the studied inhibitors are of mixed type. EIS measurements showed that the addition of NA, NMB and NPB decreases the double-layer capacitance (
C
dl
) and consequently increases the charge transfer resistance (
R
CT
) of the corrosion process. FT-IR analysis, SEM micrographs and AFM analysis confirmed the presence of inhibitor film and its role on the MS surface. Quantum chemical calculations at the DFT level were achieved to correlate electronic structure parameters of NA, NMB and NPB molecules with the experimental results.</description><subject>Adsorption</subject><subject>Characterization and Evaluation of Materials</subject><subject>Charge transfer</subject><subject>Chemistry and Materials Science</subject><subject>Classical Mechanics</subject><subject>Corrosion</subject><subject>Corrosion effects</subject><subject>Corrosion inhibitors</subject><subject>Corrosion resistance</subject><subject>Crystallography and Scattering Methods</subject><subject>Derivatives</subject><subject>Electronic structure</subject><subject>Gravimetry</subject><subject>Hydrochloric acid</subject><subject>Infrared analysis</subject><subject>Isotherms</subject><subject>Low carbon steels</subject><subject>Materials Science</subject><subject>Mathematical analysis</subject><subject>Metals</subject><subject>Niacinamide</subject><subject>Nicotinamide</subject><subject>Organic chemistry</subject><subject>Photomicrographs</subject><subject>Polymer Sciences</subject><subject>Quantum chemistry</subject><subject>Reagents</subject><subject>Solid Mechanics</subject><subject>Steel corrosion</subject><subject>Surface chemistry</subject><issn>0022-2461</issn><issn>1573-4803</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNp1kUtr3DAUhUVpodO0P6A7QVZZOL1XDz-WYchjIKWQx1rI9vVEwZYTSRPafx-ZCYSBVFoIDt85F93D2E-EUwSofkWEWssCsCpQARbiE1uhrmShapCf2QpAiEKoEr-ybzE-AoCuBK6Y3fgH17rkZs9pGKhLfB64d92cnLeT64lb33OXIv9tfdYfeGsj8Z6Ce7HJvVDk2Tq5secxEY28m0OY45LnPL9aj9_Zl8GOkX68vUfs_uL8bn1VXP-53KzProtOYZWKqmxaRTVhjU2lVdlCKzUCKamy0mCJarBWqL7sW63IylZLqdoSAYUmW8ojdrzPfQrz845iMo_zLvg80gihmxKX805t7UjG-WFOwXaTi5050zmqqQUsWacfUPn2NOXVeBpc1g8MJweGzCT6m7Z2F6PZ3N4csrhnu7ynGGgwT8FNNvwzCGYp0-zLNLlMs5RpRPaIvSdm1m8pvH_u_6ZXzoWdrg</recordid><startdate>20171101</startdate><enddate>20171101</enddate><creator>Jeeva, M.</creator><creator>Venkatesa Prabhu, G.</creator><creator>Rajesh, C. M.</creator><general>Springer US</general><general>Springer</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>ISR</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>L6V</scope><scope>M7S</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>PTHSS</scope><orcidid>https://orcid.org/0000-0002-5042-4018</orcidid></search><sort><creationdate>20171101</creationdate><title>Inhibition effect of nicotinamide and its Mannich base derivatives on mild steel corrosion in HCl</title><author>Jeeva, M. ; Venkatesa Prabhu, G. ; Rajesh, C. M.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c417t-769b4e8e18197546b0b3510e43481991614faa24d6db54ea3b5334b610125ea63</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Adsorption</topic><topic>Characterization and Evaluation of Materials</topic><topic>Charge transfer</topic><topic>Chemistry and Materials Science</topic><topic>Classical Mechanics</topic><topic>Corrosion</topic><topic>Corrosion effects</topic><topic>Corrosion inhibitors</topic><topic>Corrosion resistance</topic><topic>Crystallography and Scattering Methods</topic><topic>Derivatives</topic><topic>Electronic structure</topic><topic>Gravimetry</topic><topic>Hydrochloric acid</topic><topic>Infrared analysis</topic><topic>Isotherms</topic><topic>Low carbon steels</topic><topic>Materials Science</topic><topic>Mathematical analysis</topic><topic>Metals</topic><topic>Niacinamide</topic><topic>Nicotinamide</topic><topic>Organic chemistry</topic><topic>Photomicrographs</topic><topic>Polymer Sciences</topic><topic>Quantum chemistry</topic><topic>Reagents</topic><topic>Solid Mechanics</topic><topic>Steel corrosion</topic><topic>Surface chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Jeeva, M.</creatorcontrib><creatorcontrib>Venkatesa Prabhu, G.</creatorcontrib><creatorcontrib>Rajesh, C. M.</creatorcontrib><collection>CrossRef</collection><collection>Gale In Context: Science</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>ProQuest Engineering Collection</collection><collection>Engineering Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>Engineering Collection</collection><jtitle>Journal of materials science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Jeeva, M.</au><au>Venkatesa Prabhu, G.</au><au>Rajesh, C. M.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Inhibition effect of nicotinamide and its Mannich base derivatives on mild steel corrosion in HCl</atitle><jtitle>Journal of materials science</jtitle><stitle>J Mater Sci</stitle><date>2017-11-01</date><risdate>2017</risdate><volume>52</volume><issue>21</issue><spage>12861</spage><epage>12888</epage><pages>12861-12888</pages><issn>0022-2461</issn><eissn>1573-4803</eissn><abstract>Mannich base derivatives of nicotinamide (NA), namely
N
-(morpholino(phenyl)methyl)nicotinamide (NMB) and
N
-(phenyl(piperidin-1-yl)methyl) nicotinamide (NPB), were synthesized, characterized and studied as corrosion inhibitors for mild steel (MS) in 1.0 M hydrochloric acid using gravimetric, electrochemical experiments and theoretical calculations. Nicotinamide was also subjected for all these studies. The adsorption of NA, NMB and NPB molecules on the mild steel surface in the presence of 1.0 M HCl was found to be spontaneous and obey the Langmuir adsorption isotherm as well as Dubinin–Radushkevich isotherm. Tafel polarization measurements evidenced that all the studied inhibitors are of mixed type. EIS measurements showed that the addition of NA, NMB and NPB decreases the double-layer capacitance (
C
dl
) and consequently increases the charge transfer resistance (
R
CT
) of the corrosion process. FT-IR analysis, SEM micrographs and AFM analysis confirmed the presence of inhibitor film and its role on the MS surface. Quantum chemical calculations at the DFT level were achieved to correlate electronic structure parameters of NA, NMB and NPB molecules with the experimental results.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10853-017-1401-2</doi><tpages>28</tpages><orcidid>https://orcid.org/0000-0002-5042-4018</orcidid></addata></record> |
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| subjects | Adsorption Characterization and Evaluation of Materials Charge transfer Chemistry and Materials Science Classical Mechanics Corrosion Corrosion effects Corrosion inhibitors Corrosion resistance Crystallography and Scattering Methods Derivatives Electronic structure Gravimetry Hydrochloric acid Infrared analysis Isotherms Low carbon steels Materials Science Mathematical analysis Metals Niacinamide Nicotinamide Organic chemistry Photomicrographs Polymer Sciences Quantum chemistry Reagents Solid Mechanics Steel corrosion Surface chemistry |
| title | Inhibition effect of nicotinamide and its Mannich base derivatives on mild steel corrosion in HCl |
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