Copper-containing glass polyalkenoate cements based on SiO2–ZnO–CaO–SrO–P2O5 glasses: glass characterization, physical and antibacterial properties
A series of copper (Cu)-containing glasses were synthesized and incorporated into a SiO 2 –ZnO–CaO–SrO–P 2 O 5 -based glass system. Additions of 6 and 12 mol% CuO retained the amorphous character, and glasses were processed to possess similar particle sizes and surface areas. Glass characterization...
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| Veröffentlicht in: | Journal of materials science 2017-08, Vol.52 (15), p.8886-8903 |
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| creator | Mokhtari, S. Skelly, K. D. Krull, E. A. Coughlan, A. Mellott, N. P. Gong, Y. Borges, R. Wren, A. W. |
| description | A series of copper (Cu)-containing glasses were synthesized and incorporated into a SiO
2
–ZnO–CaO–SrO–P
2
O
5
-based glass system. Additions of 6 and 12 mol% CuO retained the amorphous character, and glasses were processed to possess similar particle sizes and surface areas. Glass characterization using X-ray photoelectron spectroscopy and magic angle spinning nuclear magnetic resonance determined that the addition of 12 mol% CuO increased the fraction of Q
4
-speciation and the concentration of bridging oxygens. Each glass presented solubility profiles for the release of Si
4+
(18–31 mg/L), Ca
2+
(13–16 mg/L), Zn
2+
( |
| doi_str_mv | 10.1007/s10853-017-0945-5 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2259604256</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2259604256</sourcerecordid><originalsourceid>FETCH-LOGICAL-c316t-e8b8f9414d14955359bb504315950af535194ee01c1887d3583c7620a9e1d3793</originalsourceid><addsrcrecordid>eNp1UctuFDEQtBBILIEP4DZSrjhpv2bGuUUrEiJFWqTAJRfL4-ndOJnYg-0clhP_wJG_y5fg1UTixKGrpe6q6paKkI8MThhAd5oZ9EpQYB0FLRVVr8iKqU5Q2YN4TVYAnFMuW_aWvMv5HgBUx9mK_FnHecZEXQzF-uDDrtlNNudmjtPeTg8Yoi3YOHzEUHIz2IxjE0Nz4zf8-dfv27CpuLYHvEkH_Mo3arHAfPbi5e5ssq5g8j9t8TF8aua7ffbOTo0NY63ih2VfJ3OK9aHiMb8nb7Z2yvjhpR-R7xefv62_0OvN5dX6_Jo6wdpCsR_6rZZMjkxqpYTSw6BACqa0ArutA6YlIjDH-r4bheqF61oOViMbRafFETlefOvpH0-Yi7mPTynUk4ZzpVuQXLWVxRaWSzHnhFszJ_9o094wMIcMzJKBqRmYQwZGVQ1fNLlyww7TP-f_i_4C6pKOaw</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2259604256</pqid></control><display><type>article</type><title>Copper-containing glass polyalkenoate cements based on SiO2–ZnO–CaO–SrO–P2O5 glasses: glass characterization, physical and antibacterial properties</title><source>SpringerLink Journals</source><creator>Mokhtari, S. ; Skelly, K. D. ; Krull, E. A. ; Coughlan, A. ; Mellott, N. P. ; Gong, Y. ; Borges, R. ; Wren, A. W.</creator><creatorcontrib>Mokhtari, S. ; Skelly, K. D. ; Krull, E. A. ; Coughlan, A. ; Mellott, N. P. ; Gong, Y. ; Borges, R. ; Wren, A. W.</creatorcontrib><description>A series of copper (Cu)-containing glasses were synthesized and incorporated into a SiO
2
–ZnO–CaO–SrO–P
2
O
5
-based glass system. Additions of 6 and 12 mol% CuO retained the amorphous character, and glasses were processed to possess similar particle sizes and surface areas. Glass characterization using X-ray photoelectron spectroscopy and magic angle spinning nuclear magnetic resonance determined that the addition of 12 mol% CuO increased the fraction of Q
4
-speciation and the concentration of bridging oxygens. Each glass presented solubility profiles for the release of Si
4+
(18–31 mg/L), Ca
2+
(13–16 mg/L), Zn
2+
(<3 mg/L) and Sr
2+
(2–10 mg/L); however, no Cu
2+
or P
5+
were released. Cu-GPCs were formulated, and the working time (
T
w
) and setting times (
T
s
) were found to be dependent on both polyacrylic acid concentration and CuO addition. The mechanical properties, i.e. the compressive strength (18–30 MPa) and the adhesive bond strength (0.79–1.32 MPa), were relative low which is likely due to the glass structure. Antibacterial properties were evaluated in
E
.
coli
(4 mm),
S
.
epidermidis
(10 mm),
S
.
aureus
(UMAS-1) and vancomycin resistant
S
.
aureus
(2 mm) and presented antibacterial effects in each microbe tested.</description><identifier>ISSN: 0022-2461</identifier><identifier>EISSN: 1573-4803</identifier><identifier>DOI: 10.1007/s10853-017-0945-5</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Adhesive bonding ; Adhesive strength ; Bond strength ; Bonding strength ; Calcium ions ; Calcium oxide ; Cements ; Characterization and Evaluation of Materials ; Chemistry and Materials Science ; Classical Mechanics ; Compressive strength ; Copper ; Copper oxides ; Crystallography and Scattering Methods ; E coli ; Glass ; In Honor of Larry Hench ; Materials Science ; Mechanical properties ; NMR ; Nuclear magnetic resonance ; Phosphorus pentoxide ; Photoelectrons ; Polyacrylic acid ; Polymer Sciences ; Silicon dioxide ; Solid Mechanics ; Speciation ; Strontium oxides ; Vancomycin ; Zinc oxide</subject><ispartof>Journal of materials science, 2017-08, Vol.52 (15), p.8886-8903</ispartof><rights>Springer Science+Business Media New York 2017</rights><rights>Journal of Materials Science is a copyright of Springer, (2017). All Rights Reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c316t-e8b8f9414d14955359bb504315950af535194ee01c1887d3583c7620a9e1d3793</citedby><cites>FETCH-LOGICAL-c316t-e8b8f9414d14955359bb504315950af535194ee01c1887d3583c7620a9e1d3793</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10853-017-0945-5$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10853-017-0945-5$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Mokhtari, S.</creatorcontrib><creatorcontrib>Skelly, K. D.</creatorcontrib><creatorcontrib>Krull, E. A.</creatorcontrib><creatorcontrib>Coughlan, A.</creatorcontrib><creatorcontrib>Mellott, N. P.</creatorcontrib><creatorcontrib>Gong, Y.</creatorcontrib><creatorcontrib>Borges, R.</creatorcontrib><creatorcontrib>Wren, A. W.</creatorcontrib><title>Copper-containing glass polyalkenoate cements based on SiO2–ZnO–CaO–SrO–P2O5 glasses: glass characterization, physical and antibacterial properties</title><title>Journal of materials science</title><addtitle>J Mater Sci</addtitle><description>A series of copper (Cu)-containing glasses were synthesized and incorporated into a SiO
2
–ZnO–CaO–SrO–P
2
O
5
-based glass system. Additions of 6 and 12 mol% CuO retained the amorphous character, and glasses were processed to possess similar particle sizes and surface areas. Glass characterization using X-ray photoelectron spectroscopy and magic angle spinning nuclear magnetic resonance determined that the addition of 12 mol% CuO increased the fraction of Q
4
-speciation and the concentration of bridging oxygens. Each glass presented solubility profiles for the release of Si
4+
(18–31 mg/L), Ca
2+
(13–16 mg/L), Zn
2+
(<3 mg/L) and Sr
2+
(2–10 mg/L); however, no Cu
2+
or P
5+
were released. Cu-GPCs were formulated, and the working time (
T
w
) and setting times (
T
s
) were found to be dependent on both polyacrylic acid concentration and CuO addition. The mechanical properties, i.e. the compressive strength (18–30 MPa) and the adhesive bond strength (0.79–1.32 MPa), were relative low which is likely due to the glass structure. Antibacterial properties were evaluated in
E
.
coli
(4 mm),
S
.
epidermidis
(10 mm),
S
.
aureus
(UMAS-1) and vancomycin resistant
S
.
aureus
(2 mm) and presented antibacterial effects in each microbe tested.</description><subject>Adhesive bonding</subject><subject>Adhesive strength</subject><subject>Bond strength</subject><subject>Bonding strength</subject><subject>Calcium ions</subject><subject>Calcium oxide</subject><subject>Cements</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry and Materials Science</subject><subject>Classical Mechanics</subject><subject>Compressive strength</subject><subject>Copper</subject><subject>Copper oxides</subject><subject>Crystallography and Scattering Methods</subject><subject>E coli</subject><subject>Glass</subject><subject>In Honor of Larry Hench</subject><subject>Materials Science</subject><subject>Mechanical properties</subject><subject>NMR</subject><subject>Nuclear magnetic resonance</subject><subject>Phosphorus pentoxide</subject><subject>Photoelectrons</subject><subject>Polyacrylic acid</subject><subject>Polymer Sciences</subject><subject>Silicon dioxide</subject><subject>Solid Mechanics</subject><subject>Speciation</subject><subject>Strontium oxides</subject><subject>Vancomycin</subject><subject>Zinc oxide</subject><issn>0022-2461</issn><issn>1573-4803</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><sourceid>BENPR</sourceid><recordid>eNp1UctuFDEQtBBILIEP4DZSrjhpv2bGuUUrEiJFWqTAJRfL4-ndOJnYg-0clhP_wJG_y5fg1UTixKGrpe6q6paKkI8MThhAd5oZ9EpQYB0FLRVVr8iKqU5Q2YN4TVYAnFMuW_aWvMv5HgBUx9mK_FnHecZEXQzF-uDDrtlNNudmjtPeTg8Yoi3YOHzEUHIz2IxjE0Nz4zf8-dfv27CpuLYHvEkH_Mo3arHAfPbi5e5ssq5g8j9t8TF8aua7ffbOTo0NY63ih2VfJ3OK9aHiMb8nb7Z2yvjhpR-R7xefv62_0OvN5dX6_Jo6wdpCsR_6rZZMjkxqpYTSw6BACqa0ArutA6YlIjDH-r4bheqF61oOViMbRafFETlefOvpH0-Yi7mPTynUk4ZzpVuQXLWVxRaWSzHnhFszJ_9o094wMIcMzJKBqRmYQwZGVQ1fNLlyww7TP-f_i_4C6pKOaw</recordid><startdate>20170801</startdate><enddate>20170801</enddate><creator>Mokhtari, S.</creator><creator>Skelly, K. D.</creator><creator>Krull, E. A.</creator><creator>Coughlan, A.</creator><creator>Mellott, N. P.</creator><creator>Gong, Y.</creator><creator>Borges, R.</creator><creator>Wren, A. W.</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>L6V</scope><scope>M7S</scope><scope>PDBOC</scope><scope>PHGZM</scope><scope>PHGZT</scope><scope>PKEHL</scope><scope>PQEST</scope><scope>PQGLB</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>PTHSS</scope></search><sort><creationdate>20170801</creationdate><title>Copper-containing glass polyalkenoate cements based on SiO2–ZnO–CaO–SrO–P2O5 glasses: glass characterization, physical and antibacterial properties</title><author>Mokhtari, S. ; Skelly, K. D. ; Krull, E. A. ; Coughlan, A. ; Mellott, N. P. ; Gong, Y. ; Borges, R. ; Wren, A. W.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c316t-e8b8f9414d14955359bb504315950af535194ee01c1887d3583c7620a9e1d3793</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Adhesive bonding</topic><topic>Adhesive strength</topic><topic>Bond strength</topic><topic>Bonding strength</topic><topic>Calcium ions</topic><topic>Calcium oxide</topic><topic>Cements</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry and Materials Science</topic><topic>Classical Mechanics</topic><topic>Compressive strength</topic><topic>Copper</topic><topic>Copper oxides</topic><topic>Crystallography and Scattering Methods</topic><topic>E coli</topic><topic>Glass</topic><topic>In Honor of Larry Hench</topic><topic>Materials Science</topic><topic>Mechanical properties</topic><topic>NMR</topic><topic>Nuclear magnetic resonance</topic><topic>Phosphorus pentoxide</topic><topic>Photoelectrons</topic><topic>Polyacrylic acid</topic><topic>Polymer Sciences</topic><topic>Silicon dioxide</topic><topic>Solid Mechanics</topic><topic>Speciation</topic><topic>Strontium oxides</topic><topic>Vancomycin</topic><topic>Zinc oxide</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Mokhtari, S.</creatorcontrib><creatorcontrib>Skelly, K. D.</creatorcontrib><creatorcontrib>Krull, E. A.</creatorcontrib><creatorcontrib>Coughlan, A.</creatorcontrib><creatorcontrib>Mellott, N. P.</creatorcontrib><creatorcontrib>Gong, Y.</creatorcontrib><creatorcontrib>Borges, R.</creatorcontrib><creatorcontrib>Wren, A. W.</creatorcontrib><collection>CrossRef</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>ProQuest Engineering Collection</collection><collection>Engineering Database</collection><collection>Materials Science Collection</collection><collection>ProQuest Central (New)</collection><collection>ProQuest One Academic (New)</collection><collection>ProQuest One Academic Middle East (New)</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Applied & Life Sciences</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>Engineering Collection</collection><jtitle>Journal of materials science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Mokhtari, S.</au><au>Skelly, K. D.</au><au>Krull, E. A.</au><au>Coughlan, A.</au><au>Mellott, N. P.</au><au>Gong, Y.</au><au>Borges, R.</au><au>Wren, A. W.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Copper-containing glass polyalkenoate cements based on SiO2–ZnO–CaO–SrO–P2O5 glasses: glass characterization, physical and antibacterial properties</atitle><jtitle>Journal of materials science</jtitle><stitle>J Mater Sci</stitle><date>2017-08-01</date><risdate>2017</risdate><volume>52</volume><issue>15</issue><spage>8886</spage><epage>8903</epage><pages>8886-8903</pages><issn>0022-2461</issn><eissn>1573-4803</eissn><abstract>A series of copper (Cu)-containing glasses were synthesized and incorporated into a SiO
2
–ZnO–CaO–SrO–P
2
O
5
-based glass system. Additions of 6 and 12 mol% CuO retained the amorphous character, and glasses were processed to possess similar particle sizes and surface areas. Glass characterization using X-ray photoelectron spectroscopy and magic angle spinning nuclear magnetic resonance determined that the addition of 12 mol% CuO increased the fraction of Q
4
-speciation and the concentration of bridging oxygens. Each glass presented solubility profiles for the release of Si
4+
(18–31 mg/L), Ca
2+
(13–16 mg/L), Zn
2+
(<3 mg/L) and Sr
2+
(2–10 mg/L); however, no Cu
2+
or P
5+
were released. Cu-GPCs were formulated, and the working time (
T
w
) and setting times (
T
s
) were found to be dependent on both polyacrylic acid concentration and CuO addition. The mechanical properties, i.e. the compressive strength (18–30 MPa) and the adhesive bond strength (0.79–1.32 MPa), were relative low which is likely due to the glass structure. Antibacterial properties were evaluated in
E
.
coli
(4 mm),
S
.
epidermidis
(10 mm),
S
.
aureus
(UMAS-1) and vancomycin resistant
S
.
aureus
(2 mm) and presented antibacterial effects in each microbe tested.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10853-017-0945-5</doi><tpages>18</tpages></addata></record> |
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| issn | 0022-2461 1573-4803 |
| language | eng |
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| source | SpringerLink Journals |
| subjects | Adhesive bonding Adhesive strength Bond strength Bonding strength Calcium ions Calcium oxide Cements Characterization and Evaluation of Materials Chemistry and Materials Science Classical Mechanics Compressive strength Copper Copper oxides Crystallography and Scattering Methods E coli Glass In Honor of Larry Hench Materials Science Mechanical properties NMR Nuclear magnetic resonance Phosphorus pentoxide Photoelectrons Polyacrylic acid Polymer Sciences Silicon dioxide Solid Mechanics Speciation Strontium oxides Vancomycin Zinc oxide |
| title | Copper-containing glass polyalkenoate cements based on SiO2–ZnO–CaO–SrO–P2O5 glasses: glass characterization, physical and antibacterial properties |
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