Ionic liquid-derived Co3O4/carbon nano-onions composite and its enhanced performance as anode for lithium-ion batteries
In this work, a novel composite of Co 3 O 4 nanoparticle and carbon nano-onions (CNOs) is synthesized by using ionic liquid as carbon and nitrogen source through a facile carbothermic reduction followed by low-temperature oxidation method. The SEM and HRTEM images reveal that the Co 3 O 4 particles...
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| Veröffentlicht in: | Journal of materials science 2017-11, Vol.52 (22), p.13192-13202 |
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| container_issue | 22 |
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| container_title | Journal of materials science |
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| creator | Meng, Yanshuang Wang, Gongrui Xiao, Mingjun Duan, Chaoyu Wang, Chen Zhu, Fuliang Zhang, Yue |
| description | In this work, a novel composite of Co
3
O
4
nanoparticle and carbon nano-onions (CNOs) is synthesized by using ionic liquid as carbon and nitrogen source through a facile carbothermic reduction followed by low-temperature oxidation method. The SEM and HRTEM images reveal that the Co
3
O
4
particles are homogenously embedded in the CNOs. Due to the unique nano-structure, the electrolyte contacts well with the active materials, leading to a better transfer of lithium ions. Moreover, the unique nano-structure not only buffers the volume changes but also facilitates the shuttling of electrons during the cycling process. As a result, the electrode made up of Co
3
O
4
/CNOs composite delivers favorable cycling performance (676 mAh g
−1
after 200 cycles) and rate capability (557 mAh g
−1
at the current of 1 C), showing a promising prospect for lithium-ion batteries as anode materials. |
| doi_str_mv | 10.1007/s10853-017-1414-x |
| format | Article |
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3
O
4
nanoparticle and carbon nano-onions (CNOs) is synthesized by using ionic liquid as carbon and nitrogen source through a facile carbothermic reduction followed by low-temperature oxidation method. The SEM and HRTEM images reveal that the Co
3
O
4
particles are homogenously embedded in the CNOs. Due to the unique nano-structure, the electrolyte contacts well with the active materials, leading to a better transfer of lithium ions. Moreover, the unique nano-structure not only buffers the volume changes but also facilitates the shuttling of electrons during the cycling process. As a result, the electrode made up of Co
3
O
4
/CNOs composite delivers favorable cycling performance (676 mAh g
−1
after 200 cycles) and rate capability (557 mAh g
−1
at the current of 1 C), showing a promising prospect for lithium-ion batteries as anode materials.</description><identifier>ISSN: 0022-2461</identifier><identifier>EISSN: 1573-4803</identifier><identifier>DOI: 10.1007/s10853-017-1414-x</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Anodes ; Carbon ; Carbothermic reactions ; Characterization and Evaluation of Materials ; Chemistry and Materials Science ; Classical Mechanics ; Cobalt oxides ; Crystallography and Scattering Methods ; Cycles ; Electrode materials ; Energy Materials ; Ionic liquids ; Ions ; Lithium ; Lithium-ion batteries ; Materials Science ; Nanoparticles ; Oxidation ; Performance enhancement ; Polymer Sciences ; Rechargeable batteries ; Solid Mechanics</subject><ispartof>Journal of materials science, 2017-11, Vol.52 (22), p.13192-13202</ispartof><rights>Springer Science+Business Media, LLC 2017</rights><rights>Journal of Materials Science is a copyright of Springer, (2017). All Rights Reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c353t-881957a4a3a676ec1ee56b4388c7280ebb90c39f2eaa41800ef1a36aece438333</citedby><cites>FETCH-LOGICAL-c353t-881957a4a3a676ec1ee56b4388c7280ebb90c39f2eaa41800ef1a36aece438333</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10853-017-1414-x$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10853-017-1414-x$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Meng, Yanshuang</creatorcontrib><creatorcontrib>Wang, Gongrui</creatorcontrib><creatorcontrib>Xiao, Mingjun</creatorcontrib><creatorcontrib>Duan, Chaoyu</creatorcontrib><creatorcontrib>Wang, Chen</creatorcontrib><creatorcontrib>Zhu, Fuliang</creatorcontrib><creatorcontrib>Zhang, Yue</creatorcontrib><title>Ionic liquid-derived Co3O4/carbon nano-onions composite and its enhanced performance as anode for lithium-ion batteries</title><title>Journal of materials science</title><addtitle>J Mater Sci</addtitle><description>In this work, a novel composite of Co
3
O
4
nanoparticle and carbon nano-onions (CNOs) is synthesized by using ionic liquid as carbon and nitrogen source through a facile carbothermic reduction followed by low-temperature oxidation method. The SEM and HRTEM images reveal that the Co
3
O
4
particles are homogenously embedded in the CNOs. Due to the unique nano-structure, the electrolyte contacts well with the active materials, leading to a better transfer of lithium ions. Moreover, the unique nano-structure not only buffers the volume changes but also facilitates the shuttling of electrons during the cycling process. As a result, the electrode made up of Co
3
O
4
/CNOs composite delivers favorable cycling performance (676 mAh g
−1
after 200 cycles) and rate capability (557 mAh g
−1
at the current of 1 C), showing a promising prospect for lithium-ion batteries as anode materials.</description><subject>Anodes</subject><subject>Carbon</subject><subject>Carbothermic reactions</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry and Materials Science</subject><subject>Classical Mechanics</subject><subject>Cobalt oxides</subject><subject>Crystallography and Scattering Methods</subject><subject>Cycles</subject><subject>Electrode materials</subject><subject>Energy Materials</subject><subject>Ionic liquids</subject><subject>Ions</subject><subject>Lithium</subject><subject>Lithium-ion batteries</subject><subject>Materials Science</subject><subject>Nanoparticles</subject><subject>Oxidation</subject><subject>Performance enhancement</subject><subject>Polymer Sciences</subject><subject>Rechargeable batteries</subject><subject>Solid Mechanics</subject><issn>0022-2461</issn><issn>1573-4803</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><sourceid>BENPR</sourceid><recordid>eNp1kEtPwzAQhC0EEqXwA7hZ4my6tvM8ooqXVKkXOFuOs6GpGju1Eyj_HkdB4sRptbvfzEhDyC2Hew6QrwKHIpUMeM54whN2OiMLnuaSJQXIc7IAEIKJJOOX5CqEPQCkueAL8vXqbGvooT2Obc1q9O0n1nTt5DZZGe0rZ6nV1rFIORuocV3vQjsg1bam7RAo2p22Jmp69I3z3bRQHeLf1UjjJXoPu3bsWDSglR6GmIHhmlw0-hDw5ncuyfvT49v6hW22z6_rhw0zMpUDKwpeprlOtNRZnqHhiGlWJbIoTC4KwKoqwciyEah1wgsAbLiWmUaDEZJSLsnd7Nt7dxwxDGrvRm9jpBIiLdMYABPFZ8p4F4LHRvW-7bT_VhzU1K-a-1WxXzX1q05RI2ZNiKz9QP_n_L_oB1XBfz8</recordid><startdate>20171101</startdate><enddate>20171101</enddate><creator>Meng, Yanshuang</creator><creator>Wang, Gongrui</creator><creator>Xiao, Mingjun</creator><creator>Duan, Chaoyu</creator><creator>Wang, Chen</creator><creator>Zhu, Fuliang</creator><creator>Zhang, Yue</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>L6V</scope><scope>M7S</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>PTHSS</scope></search><sort><creationdate>20171101</creationdate><title>Ionic liquid-derived Co3O4/carbon nano-onions composite and its enhanced performance as anode for lithium-ion batteries</title><author>Meng, Yanshuang ; Wang, Gongrui ; Xiao, Mingjun ; Duan, Chaoyu ; Wang, Chen ; Zhu, Fuliang ; Zhang, Yue</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c353t-881957a4a3a676ec1ee56b4388c7280ebb90c39f2eaa41800ef1a36aece438333</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Anodes</topic><topic>Carbon</topic><topic>Carbothermic reactions</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry and Materials Science</topic><topic>Classical Mechanics</topic><topic>Cobalt oxides</topic><topic>Crystallography and Scattering Methods</topic><topic>Cycles</topic><topic>Electrode materials</topic><topic>Energy Materials</topic><topic>Ionic liquids</topic><topic>Ions</topic><topic>Lithium</topic><topic>Lithium-ion batteries</topic><topic>Materials Science</topic><topic>Nanoparticles</topic><topic>Oxidation</topic><topic>Performance enhancement</topic><topic>Polymer Sciences</topic><topic>Rechargeable batteries</topic><topic>Solid Mechanics</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Meng, Yanshuang</creatorcontrib><creatorcontrib>Wang, Gongrui</creatorcontrib><creatorcontrib>Xiao, Mingjun</creatorcontrib><creatorcontrib>Duan, Chaoyu</creatorcontrib><creatorcontrib>Wang, Chen</creatorcontrib><creatorcontrib>Zhu, Fuliang</creatorcontrib><creatorcontrib>Zhang, Yue</creatorcontrib><collection>CrossRef</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>ProQuest Engineering Collection</collection><collection>Engineering Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>Engineering Collection</collection><jtitle>Journal of materials science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Meng, Yanshuang</au><au>Wang, Gongrui</au><au>Xiao, Mingjun</au><au>Duan, Chaoyu</au><au>Wang, Chen</au><au>Zhu, Fuliang</au><au>Zhang, Yue</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Ionic liquid-derived Co3O4/carbon nano-onions composite and its enhanced performance as anode for lithium-ion batteries</atitle><jtitle>Journal of materials science</jtitle><stitle>J Mater Sci</stitle><date>2017-11-01</date><risdate>2017</risdate><volume>52</volume><issue>22</issue><spage>13192</spage><epage>13202</epage><pages>13192-13202</pages><issn>0022-2461</issn><eissn>1573-4803</eissn><abstract>In this work, a novel composite of Co
3
O
4
nanoparticle and carbon nano-onions (CNOs) is synthesized by using ionic liquid as carbon and nitrogen source through a facile carbothermic reduction followed by low-temperature oxidation method. The SEM and HRTEM images reveal that the Co
3
O
4
particles are homogenously embedded in the CNOs. Due to the unique nano-structure, the electrolyte contacts well with the active materials, leading to a better transfer of lithium ions. Moreover, the unique nano-structure not only buffers the volume changes but also facilitates the shuttling of electrons during the cycling process. As a result, the electrode made up of Co
3
O
4
/CNOs composite delivers favorable cycling performance (676 mAh g
−1
after 200 cycles) and rate capability (557 mAh g
−1
at the current of 1 C), showing a promising prospect for lithium-ion batteries as anode materials.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10853-017-1414-x</doi><tpages>11</tpages></addata></record> |
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| subjects | Anodes Carbon Carbothermic reactions Characterization and Evaluation of Materials Chemistry and Materials Science Classical Mechanics Cobalt oxides Crystallography and Scattering Methods Cycles Electrode materials Energy Materials Ionic liquids Ions Lithium Lithium-ion batteries Materials Science Nanoparticles Oxidation Performance enhancement Polymer Sciences Rechargeable batteries Solid Mechanics |
| title | Ionic liquid-derived Co3O4/carbon nano-onions composite and its enhanced performance as anode for lithium-ion batteries |
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