Enhancement of optical transparency in Bi2O3-modified (K0.5Na0.5)0.9Sr0.1Nb0.9Ti0.1O3 ceramics for electro-optic applications
Transparent relaxor ferroelectrics, (K₀.₅Na₀.₅)₀.₉Sr₀.₁Nb₀.₉Ti₀.₁O₃–x%Bi₂O₃ (x = 0, 0.5, 1.0, 1.5, and 2, abbreviated as KNSNT-10x), were fabricated using a pressureless sintering method. With the modification of Bi₂O₃, the crystal phase of KNSNT ceramics transformed from tetragonal to cubic-like sy...
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| Veröffentlicht in: | Journal of materials science 2015-12, Vol.50 (24), p.7958-7966 |
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| creator | Liu, Zhiyong Fan, Huiqing Peng, Biaolin |
| description | Transparent relaxor ferroelectrics, (K₀.₅Na₀.₅)₀.₉Sr₀.₁Nb₀.₉Ti₀.₁O₃–x%Bi₂O₃ (x = 0, 0.5, 1.0, 1.5, and 2, abbreviated as KNSNT-10x), were fabricated using a pressureless sintering method. With the modification of Bi₂O₃, the crystal phase of KNSNT ceramics transformed from tetragonal to cubic-like symmetry, and dielectric behaviors became more relaxor like. These changes could reduce the light scattering arisen from birefringence and long-range ordering structure, thus enhancing the optical properties. For KNSNT-10 transparent ceramics, fingerprint morphological nanodomains were observed in the transmission electron microscope image, which made the ceramics sensitive to electric field. Therefore, a large effective linear electro-optic coefficient of 26.1 pm/V was obtained for the KNSNT-10 ceramics, and it is higher than the value (19.9 pm/V) for LiNbO₃ single crystal. |
| doi_str_mv | 10.1007/s10853-015-9360-y |
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With the modification of Bi₂O₃, the crystal phase of KNSNT ceramics transformed from tetragonal to cubic-like symmetry, and dielectric behaviors became more relaxor like. These changes could reduce the light scattering arisen from birefringence and long-range ordering structure, thus enhancing the optical properties. For KNSNT-10 transparent ceramics, fingerprint morphological nanodomains were observed in the transmission electron microscope image, which made the ceramics sensitive to electric field. Therefore, a large effective linear electro-optic coefficient of 26.1 pm/V was obtained for the KNSNT-10 ceramics, and it is higher than the value (19.9 pm/V) for LiNbO₃ single crystal.</description><identifier>ISSN: 0022-2461</identifier><identifier>EISSN: 1573-4803</identifier><identifier>DOI: 10.1007/s10853-015-9360-y</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Birefringence ; Bismuth oxides ; Bismuth trioxide ; Ceramics ; Characterization and Evaluation of Materials ; Chemistry and Materials Science ; Classical Mechanics ; Crystallography and Scattering Methods ; Dielectric relaxation ; electric field ; Electric fields ; Ferroelectric materials ; Ferroelectricity ; Image transmission ; Light scattering ; Lithium niobates ; Loose powder sintering ; Materials Science ; Optical properties ; Optics ; Original Paper ; Phase transitions ; Polymer Sciences ; Relaxors ; Single crystals ; Solid Mechanics ; transmission electron microscopes</subject><ispartof>Journal of materials science, 2015-12, Vol.50 (24), p.7958-7966</ispartof><rights>Springer Science+Business Media New York 2015</rights><rights>Journal of Materials Science is a copyright of Springer, (2015). All Rights Reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c321y-9929f8a317f2c19aa6433ab80f1e166c2cad6d61b158d941fc652f426dbb0e843</citedby><cites>FETCH-LOGICAL-c321y-9929f8a317f2c19aa6433ab80f1e166c2cad6d61b158d941fc652f426dbb0e843</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10853-015-9360-y$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10853-015-9360-y$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Liu, Zhiyong</creatorcontrib><creatorcontrib>Fan, Huiqing</creatorcontrib><creatorcontrib>Peng, Biaolin</creatorcontrib><title>Enhancement of optical transparency in Bi2O3-modified (K0.5Na0.5)0.9Sr0.1Nb0.9Ti0.1O3 ceramics for electro-optic applications</title><title>Journal of materials science</title><addtitle>J Mater Sci</addtitle><description>Transparent relaxor ferroelectrics, (K₀.₅Na₀.₅)₀.₉Sr₀.₁Nb₀.₉Ti₀.₁O₃–x%Bi₂O₃ (x = 0, 0.5, 1.0, 1.5, and 2, abbreviated as KNSNT-10x), were fabricated using a pressureless sintering method. With the modification of Bi₂O₃, the crystal phase of KNSNT ceramics transformed from tetragonal to cubic-like symmetry, and dielectric behaviors became more relaxor like. These changes could reduce the light scattering arisen from birefringence and long-range ordering structure, thus enhancing the optical properties. For KNSNT-10 transparent ceramics, fingerprint morphological nanodomains were observed in the transmission electron microscope image, which made the ceramics sensitive to electric field. Therefore, a large effective linear electro-optic coefficient of 26.1 pm/V was obtained for the KNSNT-10 ceramics, and it is higher than the value (19.9 pm/V) for LiNbO₃ single crystal.</description><subject>Birefringence</subject><subject>Bismuth oxides</subject><subject>Bismuth trioxide</subject><subject>Ceramics</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry and Materials Science</subject><subject>Classical Mechanics</subject><subject>Crystallography and Scattering Methods</subject><subject>Dielectric relaxation</subject><subject>electric field</subject><subject>Electric fields</subject><subject>Ferroelectric materials</subject><subject>Ferroelectricity</subject><subject>Image transmission</subject><subject>Light scattering</subject><subject>Lithium niobates</subject><subject>Loose powder sintering</subject><subject>Materials Science</subject><subject>Optical properties</subject><subject>Optics</subject><subject>Original Paper</subject><subject>Phase transitions</subject><subject>Polymer Sciences</subject><subject>Relaxors</subject><subject>Single crystals</subject><subject>Solid Mechanics</subject><subject>transmission electron microscopes</subject><issn>0022-2461</issn><issn>1573-4803</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNp9UT1vFDEQtRBIHIEfQIUlGih8zNhr77qEKHyIKFckqS2v1w6O7uzF3hRb8N9xWCQ6mplXvI_RG0JeI-wRoP9QEQYpGKBkWihg6xOyQ9kL1g0gnpIdAOeMdwqfkxe13gOA7DnuyK-L9MMm508-LTQHmuclOnukS7Gpzrb45FYaE_0U-UGwU55iiH6i777DXl7ZNt7DXl-XdsXV2NBNbOggqPPFnqKrNORC_dG7pWT2x5vaeT62iCXmVF-SZ8Eeq3_1d5-R288XN-df2eXhy7fzj5fMCY4r05rrMFiBfeAOtbWqE8KOAwT0qJTjzk5qUjiiHCbdYXBK8tBxNY0j-KETZ-Tt5juX_PPB18Xc54eSWqThXGo5CKH7xsKN5Uqutfhg5hJPtqwGwTy2bLaWTWvZPLZs1qbhm6Y2brrz5Z_z_0RvNlGw2di7Equ5veaAqr2FC9714jeg24ay</recordid><startdate>20151201</startdate><enddate>20151201</enddate><creator>Liu, Zhiyong</creator><creator>Fan, Huiqing</creator><creator>Peng, Biaolin</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>FBQ</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>L6V</scope><scope>M7S</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>PTHSS</scope></search><sort><creationdate>20151201</creationdate><title>Enhancement of optical transparency in Bi2O3-modified (K0.5Na0.5)0.9Sr0.1Nb0.9Ti0.1O3 ceramics for electro-optic applications</title><author>Liu, Zhiyong ; Fan, Huiqing ; Peng, Biaolin</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c321y-9929f8a317f2c19aa6433ab80f1e166c2cad6d61b158d941fc652f426dbb0e843</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><topic>Birefringence</topic><topic>Bismuth oxides</topic><topic>Bismuth trioxide</topic><topic>Ceramics</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry and Materials Science</topic><topic>Classical Mechanics</topic><topic>Crystallography and Scattering Methods</topic><topic>Dielectric relaxation</topic><topic>electric field</topic><topic>Electric fields</topic><topic>Ferroelectric materials</topic><topic>Ferroelectricity</topic><topic>Image transmission</topic><topic>Light scattering</topic><topic>Lithium niobates</topic><topic>Loose powder sintering</topic><topic>Materials Science</topic><topic>Optical properties</topic><topic>Optics</topic><topic>Original Paper</topic><topic>Phase transitions</topic><topic>Polymer Sciences</topic><topic>Relaxors</topic><topic>Single crystals</topic><topic>Solid Mechanics</topic><topic>transmission electron microscopes</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Liu, Zhiyong</creatorcontrib><creatorcontrib>Fan, Huiqing</creatorcontrib><creatorcontrib>Peng, Biaolin</creatorcontrib><collection>AGRIS</collection><collection>CrossRef</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>ProQuest Engineering Collection</collection><collection>Engineering Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>Engineering Collection</collection><jtitle>Journal of materials science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Liu, Zhiyong</au><au>Fan, Huiqing</au><au>Peng, Biaolin</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Enhancement of optical transparency in Bi2O3-modified (K0.5Na0.5)0.9Sr0.1Nb0.9Ti0.1O3 ceramics for electro-optic applications</atitle><jtitle>Journal of materials science</jtitle><stitle>J Mater Sci</stitle><date>2015-12-01</date><risdate>2015</risdate><volume>50</volume><issue>24</issue><spage>7958</spage><epage>7966</epage><pages>7958-7966</pages><issn>0022-2461</issn><eissn>1573-4803</eissn><abstract>Transparent relaxor ferroelectrics, (K₀.₅Na₀.₅)₀.₉Sr₀.₁Nb₀.₉Ti₀.₁O₃–x%Bi₂O₃ (x = 0, 0.5, 1.0, 1.5, and 2, abbreviated as KNSNT-10x), were fabricated using a pressureless sintering method. With the modification of Bi₂O₃, the crystal phase of KNSNT ceramics transformed from tetragonal to cubic-like symmetry, and dielectric behaviors became more relaxor like. These changes could reduce the light scattering arisen from birefringence and long-range ordering structure, thus enhancing the optical properties. For KNSNT-10 transparent ceramics, fingerprint morphological nanodomains were observed in the transmission electron microscope image, which made the ceramics sensitive to electric field. Therefore, a large effective linear electro-optic coefficient of 26.1 pm/V was obtained for the KNSNT-10 ceramics, and it is higher than the value (19.9 pm/V) for LiNbO₃ single crystal.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10853-015-9360-y</doi><tpages>9</tpages></addata></record> |
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| subjects | Birefringence Bismuth oxides Bismuth trioxide Ceramics Characterization and Evaluation of Materials Chemistry and Materials Science Classical Mechanics Crystallography and Scattering Methods Dielectric relaxation electric field Electric fields Ferroelectric materials Ferroelectricity Image transmission Light scattering Lithium niobates Loose powder sintering Materials Science Optical properties Optics Original Paper Phase transitions Polymer Sciences Relaxors Single crystals Solid Mechanics transmission electron microscopes |
| title | Enhancement of optical transparency in Bi2O3-modified (K0.5Na0.5)0.9Sr0.1Nb0.9Ti0.1O3 ceramics for electro-optic applications |
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