Photoluminescence spectra and crystallization of θ-Al2O3 and α-Al2O3 from AlOOH-Fe(NO3)3 gels

Diphasic boehmite derived unseeded and seeded (by either α-Al2O3, α-Fe2O3, or Fe(NO3)3) alumina gel planar monoliths were examined by DTA, XRD and photoluminescence spectroscopy. Luminescence spectra enable sensitive monitoring of the Θ- and α-Al2O3 crystallization in heat-treated gels due to Cr3+ i...

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Veröffentlicht in:Journal of sol-gel science and technology 2001-08, Vol.21 (3), p.167-172
Hauptverfasser: KAKOS, J, BACA, L', VEIS, P, PACH, L
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creator KAKOS, J
BACA, L'
VEIS, P
PACH, L
description Diphasic boehmite derived unseeded and seeded (by either α-Al2O3, α-Fe2O3, or Fe(NO3)3) alumina gel planar monoliths were examined by DTA, XRD and photoluminescence spectroscopy. Luminescence spectra enable sensitive monitoring of the Θ- and α-Al2O3 crystallization in heat-treated gels due to Cr3+ impurity traces. Fe(NO3)3 unlike other seeds effectively influences crystallization of both Θ- and α-Al2O3. The present results are interpreted as prevailing solution or Fe3+ ion effect on the crystallization process.
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1573-4846
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subjects Aluminum oxide
Boehmite
Chemistry
Colloidal gels. Colloidal sols
Colloidal state and disperse state
Crystallization
Exact sciences and technology
Gels
General and physical chemistry
Heat treatment
Photoluminescence
Spectrum analysis
title Photoluminescence spectra and crystallization of θ-Al2O3 and α-Al2O3 from AlOOH-Fe(NO3)3 gels
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