Effect of La/Zr ratio in the precursor solution on the properties of La2Zr2O7 and CeO2/La2Zr2O7 films
La 2 Zr 2 O 7 (LZO) films and CeO 2 /LZO composite films were prepared on the biaxially textured NiW tapes using metal organic deposition method. Effect of molar ratio of La/Zr in the precursor solution on the texture and surface morphology of LZO films and composite CeO 2 /LZO films was investigate...
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| Veröffentlicht in: | Journal of sol-gel science and technology 2017-05, Vol.82 (2), p.586-593 |
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| container_title | Journal of sol-gel science and technology |
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| creator | Bian, Weibai Chen, Yuanqing Tang, Xinni Nishii, Junji Li, Lingwei Li, Na Wu, Huimin Zhao, Gaoyang |
| description | La
2
Zr
2
O
7
(LZO) films and CeO
2
/LZO composite films were prepared on the biaxially textured NiW tapes using metal organic deposition method. Effect of molar ratio of La/Zr in the precursor solution on the texture and surface morphology of LZO films and composite CeO
2
/LZO films was investigated systemically. It was found that the content of lanthanum played an important role in the orientation control of the LZO film. Finally, the LZO film with ratio of La/Zr = 1.1/1 was obtained with the best properties as compared to others. And highly textured LZO-11 and CeO
2
/LZO-11 films with smooth surface were obtained on the NiW tape. YBa
2
Cu
3
O
7-x
(YBCO) films with enhanced critical current density (J
c
) were obtained on the optimized CeO
2
/LZO buffer layer.
Graphical Abstract
The LZO films were prepared from different LZO solutions with different molar ratio of La/Zr, and the effects of the La/Zr ratio on the texture and surface morphology of LZO films were systemically investigated. The results confirmed that the content of lanthanum in solution was closely related to the orientation control of the LZO film. When the ratio of La/Zr was smaller than La/Zr = 1, the pure (l00)-oriented phase was not achieved. When that was larger than La/Zr = 1.2, in spite of the pure (l00)-oriented phase, the more lanthanum content increased the lattice parameter of the LZO films. In summary, the ratio of La/Zr = 1.1 was the optimized ratio for the fabrication of LZO film due to the best texture and surface morphology. |
| doi_str_mv | 10.1007/s10971-017-4303-5 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2259553915</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2259553915</sourcerecordid><originalsourceid>FETCH-LOGICAL-c344t-edd2397e32be29589006e8bbf39138aec4e795b3fb34d1728bfd4b75df0e856b3</originalsourceid><addsrcrecordid>eNp9kEtLAzEQx4MoWKsfwFvAc2yeTXKUUh9Q6EUvvYTN7kS3tJua7B789qasihc9Dcz_McMPoWtGbxmlepYZtZoRyjSRggqiTtCEKS2INHJ-iibUckOopvocXeS8pZQqyfQEwTIEqHscA15Vs03CqerbiNsO92-ADwnqIeWYcI67oQgdjt9KPEDqW8hjlG8SX2tcdQ1ewJrPfjah3e3zJToL1S7D1decopf75fPikazWD0-LuxWphZQ9gabhwmoQ3AO3ylhK52C8D8IyYSqoJWirvAheyIZpbnxopNeqCRSMmnsxRTdjb3nvfYDcu20cUldOOs6VVaoUqf9czBihCippiouNrjrFnBMEd0jtvkofjlF3ZO5G5q4wd0fm7tjMx0wu3u4V0q_mP0OfGbaBkg</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2259553915</pqid></control><display><type>article</type><title>Effect of La/Zr ratio in the precursor solution on the properties of La2Zr2O7 and CeO2/La2Zr2O7 films</title><source>SpringerLink Journals - AutoHoldings</source><creator>Bian, Weibai ; Chen, Yuanqing ; Tang, Xinni ; Nishii, Junji ; Li, Lingwei ; Li, Na ; Wu, Huimin ; Zhao, Gaoyang</creator><creatorcontrib>Bian, Weibai ; Chen, Yuanqing ; Tang, Xinni ; Nishii, Junji ; Li, Lingwei ; Li, Na ; Wu, Huimin ; Zhao, Gaoyang</creatorcontrib><description>La
2
Zr
2
O
7
(LZO) films and CeO
2
/LZO composite films were prepared on the biaxially textured NiW tapes using metal organic deposition method. Effect of molar ratio of La/Zr in the precursor solution on the texture and surface morphology of LZO films and composite CeO
2
/LZO films was investigated systemically. It was found that the content of lanthanum played an important role in the orientation control of the LZO film. Finally, the LZO film with ratio of La/Zr = 1.1/1 was obtained with the best properties as compared to others. And highly textured LZO-11 and CeO
2
/LZO-11 films with smooth surface were obtained on the NiW tape. YBa
2
Cu
3
O
7-x
(YBCO) films with enhanced critical current density (J
c
) were obtained on the optimized CeO
2
/LZO buffer layer.
Graphical Abstract
The LZO films were prepared from different LZO solutions with different molar ratio of La/Zr, and the effects of the La/Zr ratio on the texture and surface morphology of LZO films were systemically investigated. The results confirmed that the content of lanthanum in solution was closely related to the orientation control of the LZO film. When the ratio of La/Zr was smaller than La/Zr = 1, the pure (l00)-oriented phase was not achieved. When that was larger than La/Zr = 1.2, in spite of the pure (l00)-oriented phase, the more lanthanum content increased the lattice parameter of the LZO films. In summary, the ratio of La/Zr = 1.1 was the optimized ratio for the fabrication of LZO film due to the best texture and surface morphology.</description><identifier>ISSN: 0928-0707</identifier><identifier>EISSN: 1573-4846</identifier><identifier>DOI: 10.1007/s10971-017-4303-5</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Buffer layers ; Ceramics ; Cerium oxides ; Chemistry and Materials Science ; Composites ; Critical current density ; Glass ; hybrids and solution chemistries ; Inorganic Chemistry ; Lanthanum ; Materials Science ; Morphology ; Nanotechnology ; Natural Materials ; Optical and Electronic Materials ; Orientation effects ; Original Paper: Sol-gel ; Precursors ; Surface layers ; Texture ; YBCO superconductors ; Zirconium</subject><ispartof>Journal of sol-gel science and technology, 2017-05, Vol.82 (2), p.586-593</ispartof><rights>Springer Science+Business Media New York 2017</rights><rights>Copyright Springer Science & Business Media 2017</rights><rights>Journal of Sol-Gel Science and Technology is a copyright of Springer, (2017). All Rights Reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c344t-edd2397e32be29589006e8bbf39138aec4e795b3fb34d1728bfd4b75df0e856b3</citedby><cites>FETCH-LOGICAL-c344t-edd2397e32be29589006e8bbf39138aec4e795b3fb34d1728bfd4b75df0e856b3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10971-017-4303-5$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10971-017-4303-5$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27923,27924,41487,42556,51318</link.rule.ids></links><search><creatorcontrib>Bian, Weibai</creatorcontrib><creatorcontrib>Chen, Yuanqing</creatorcontrib><creatorcontrib>Tang, Xinni</creatorcontrib><creatorcontrib>Nishii, Junji</creatorcontrib><creatorcontrib>Li, Lingwei</creatorcontrib><creatorcontrib>Li, Na</creatorcontrib><creatorcontrib>Wu, Huimin</creatorcontrib><creatorcontrib>Zhao, Gaoyang</creatorcontrib><title>Effect of La/Zr ratio in the precursor solution on the properties of La2Zr2O7 and CeO2/La2Zr2O7 films</title><title>Journal of sol-gel science and technology</title><addtitle>J Sol-Gel Sci Technol</addtitle><description>La
2
Zr
2
O
7
(LZO) films and CeO
2
/LZO composite films were prepared on the biaxially textured NiW tapes using metal organic deposition method. Effect of molar ratio of La/Zr in the precursor solution on the texture and surface morphology of LZO films and composite CeO
2
/LZO films was investigated systemically. It was found that the content of lanthanum played an important role in the orientation control of the LZO film. Finally, the LZO film with ratio of La/Zr = 1.1/1 was obtained with the best properties as compared to others. And highly textured LZO-11 and CeO
2
/LZO-11 films with smooth surface were obtained on the NiW tape. YBa
2
Cu
3
O
7-x
(YBCO) films with enhanced critical current density (J
c
) were obtained on the optimized CeO
2
/LZO buffer layer.
Graphical Abstract
The LZO films were prepared from different LZO solutions with different molar ratio of La/Zr, and the effects of the La/Zr ratio on the texture and surface morphology of LZO films were systemically investigated. The results confirmed that the content of lanthanum in solution was closely related to the orientation control of the LZO film. When the ratio of La/Zr was smaller than La/Zr = 1, the pure (l00)-oriented phase was not achieved. When that was larger than La/Zr = 1.2, in spite of the pure (l00)-oriented phase, the more lanthanum content increased the lattice parameter of the LZO films. In summary, the ratio of La/Zr = 1.1 was the optimized ratio for the fabrication of LZO film due to the best texture and surface morphology.</description><subject>Buffer layers</subject><subject>Ceramics</subject><subject>Cerium oxides</subject><subject>Chemistry and Materials Science</subject><subject>Composites</subject><subject>Critical current density</subject><subject>Glass</subject><subject>hybrids and solution chemistries</subject><subject>Inorganic Chemistry</subject><subject>Lanthanum</subject><subject>Materials Science</subject><subject>Morphology</subject><subject>Nanotechnology</subject><subject>Natural Materials</subject><subject>Optical and Electronic Materials</subject><subject>Orientation effects</subject><subject>Original Paper: Sol-gel</subject><subject>Precursors</subject><subject>Surface layers</subject><subject>Texture</subject><subject>YBCO superconductors</subject><subject>Zirconium</subject><issn>0928-0707</issn><issn>1573-4846</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNp9kEtLAzEQx4MoWKsfwFvAc2yeTXKUUh9Q6EUvvYTN7kS3tJua7B789qasihc9Dcz_McMPoWtGbxmlepYZtZoRyjSRggqiTtCEKS2INHJ-iibUckOopvocXeS8pZQqyfQEwTIEqHscA15Vs03CqerbiNsO92-ADwnqIeWYcI67oQgdjt9KPEDqW8hjlG8SX2tcdQ1ewJrPfjah3e3zJToL1S7D1decopf75fPikazWD0-LuxWphZQ9gabhwmoQ3AO3ylhK52C8D8IyYSqoJWirvAheyIZpbnxopNeqCRSMmnsxRTdjb3nvfYDcu20cUldOOs6VVaoUqf9czBihCippiouNrjrFnBMEd0jtvkofjlF3ZO5G5q4wd0fm7tjMx0wu3u4V0q_mP0OfGbaBkg</recordid><startdate>20170501</startdate><enddate>20170501</enddate><creator>Bian, Weibai</creator><creator>Chen, Yuanqing</creator><creator>Tang, Xinni</creator><creator>Nishii, Junji</creator><creator>Li, Lingwei</creator><creator>Li, Na</creator><creator>Wu, Huimin</creator><creator>Zhao, Gaoyang</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>L6V</scope><scope>M7S</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>PTHSS</scope></search><sort><creationdate>20170501</creationdate><title>Effect of La/Zr ratio in the precursor solution on the properties of La2Zr2O7 and CeO2/La2Zr2O7 films</title><author>Bian, Weibai ; Chen, Yuanqing ; Tang, Xinni ; Nishii, Junji ; Li, Lingwei ; Li, Na ; Wu, Huimin ; Zhao, Gaoyang</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c344t-edd2397e32be29589006e8bbf39138aec4e795b3fb34d1728bfd4b75df0e856b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Buffer layers</topic><topic>Ceramics</topic><topic>Cerium oxides</topic><topic>Chemistry and Materials Science</topic><topic>Composites</topic><topic>Critical current density</topic><topic>Glass</topic><topic>hybrids and solution chemistries</topic><topic>Inorganic Chemistry</topic><topic>Lanthanum</topic><topic>Materials Science</topic><topic>Morphology</topic><topic>Nanotechnology</topic><topic>Natural Materials</topic><topic>Optical and Electronic Materials</topic><topic>Orientation effects</topic><topic>Original Paper: Sol-gel</topic><topic>Precursors</topic><topic>Surface layers</topic><topic>Texture</topic><topic>YBCO superconductors</topic><topic>Zirconium</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Bian, Weibai</creatorcontrib><creatorcontrib>Chen, Yuanqing</creatorcontrib><creatorcontrib>Tang, Xinni</creatorcontrib><creatorcontrib>Nishii, Junji</creatorcontrib><creatorcontrib>Li, Lingwei</creatorcontrib><creatorcontrib>Li, Na</creatorcontrib><creatorcontrib>Wu, Huimin</creatorcontrib><creatorcontrib>Zhao, Gaoyang</creatorcontrib><collection>CrossRef</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>ProQuest Engineering Collection</collection><collection>Engineering Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>Engineering Collection</collection><jtitle>Journal of sol-gel science and technology</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Bian, Weibai</au><au>Chen, Yuanqing</au><au>Tang, Xinni</au><au>Nishii, Junji</au><au>Li, Lingwei</au><au>Li, Na</au><au>Wu, Huimin</au><au>Zhao, Gaoyang</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Effect of La/Zr ratio in the precursor solution on the properties of La2Zr2O7 and CeO2/La2Zr2O7 films</atitle><jtitle>Journal of sol-gel science and technology</jtitle><stitle>J Sol-Gel Sci Technol</stitle><date>2017-05-01</date><risdate>2017</risdate><volume>82</volume><issue>2</issue><spage>586</spage><epage>593</epage><pages>586-593</pages><issn>0928-0707</issn><eissn>1573-4846</eissn><abstract>La
2
Zr
2
O
7
(LZO) films and CeO
2
/LZO composite films were prepared on the biaxially textured NiW tapes using metal organic deposition method. Effect of molar ratio of La/Zr in the precursor solution on the texture and surface morphology of LZO films and composite CeO
2
/LZO films was investigated systemically. It was found that the content of lanthanum played an important role in the orientation control of the LZO film. Finally, the LZO film with ratio of La/Zr = 1.1/1 was obtained with the best properties as compared to others. And highly textured LZO-11 and CeO
2
/LZO-11 films with smooth surface were obtained on the NiW tape. YBa
2
Cu
3
O
7-x
(YBCO) films with enhanced critical current density (J
c
) were obtained on the optimized CeO
2
/LZO buffer layer.
Graphical Abstract
The LZO films were prepared from different LZO solutions with different molar ratio of La/Zr, and the effects of the La/Zr ratio on the texture and surface morphology of LZO films were systemically investigated. The results confirmed that the content of lanthanum in solution was closely related to the orientation control of the LZO film. When the ratio of La/Zr was smaller than La/Zr = 1, the pure (l00)-oriented phase was not achieved. When that was larger than La/Zr = 1.2, in spite of the pure (l00)-oriented phase, the more lanthanum content increased the lattice parameter of the LZO films. In summary, the ratio of La/Zr = 1.1 was the optimized ratio for the fabrication of LZO film due to the best texture and surface morphology.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10971-017-4303-5</doi><tpages>8</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0928-0707 |
| ispartof | Journal of sol-gel science and technology, 2017-05, Vol.82 (2), p.586-593 |
| issn | 0928-0707 1573-4846 |
| language | eng |
| recordid | cdi_proquest_journals_2259553915 |
| source | SpringerLink Journals - AutoHoldings |
| subjects | Buffer layers Ceramics Cerium oxides Chemistry and Materials Science Composites Critical current density Glass hybrids and solution chemistries Inorganic Chemistry Lanthanum Materials Science Morphology Nanotechnology Natural Materials Optical and Electronic Materials Orientation effects Original Paper: Sol-gel Precursors Surface layers Texture YBCO superconductors Zirconium |
| title | Effect of La/Zr ratio in the precursor solution on the properties of La2Zr2O7 and CeO2/La2Zr2O7 films |
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