Application of chalcone-based dithiocarbamate derivative incorporated sol–gel for the removal of Hg (II) ion from water
This study demonstrated the application of chalcone-based dithiocarbamate derivative as metal capturing ligand for the removal of mercury ion (Hg 2+ ) in water. Chalcones are a group of naturally occurring compounds which can be obtained from fruits, vegetables, plants, and spice. In this study, cha...
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| Veröffentlicht in: | Journal of sol-gel science and technology 2017-06, Vol.82 (3), p.834-845 |
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| creator | Khor, Soo Wei Lee, Yean Kee Abas, Mhd Radzi Bin Tay, Kheng Soo |
| description | This study demonstrated the application of chalcone-based dithiocarbamate derivative as metal capturing ligand for the removal of mercury ion (Hg
2+
) in water. Chalcones are a group of naturally occurring compounds which can be obtained from fruits, vegetables, plants, and spice. In this study, chalcone was first chemically modified to produce dithiocarbamate derivative (ODPPNE). Chalcone and ODPPNE were then incorporated into sol–gel to produce SG-C and SG-ODPPNE, respectively, as adsorbents. The result from the adsorption study showed that with the presence of dithiocarbamate functional group, SG-ODPPNE exhibited the highest selectivity toward the adsorption of Hg
2+
with lesser response to Cr
3+
, Ni
2+
, Cu
2+
, Zn
2+
, Cd
2+
, and Pb
2+
. The adsorption of Hg
2+
by SG-ODPPNE was found to be adsorbent size, adsorbent dosage, contact time, the initial concentration of sorbate and pH dependent. The obtained experimental data were also analyzed using Freundlich and Langmuir adsorption models. The results showed that the adsorption data were well-fitted to Langmuir isotherm, and the monolayer absorption capacity was found to be 13.5 mg/g. In the absorption kinetic study, the data was analyzed using pseudo-first-order, pseudo-second-order kinetic model, and intraparticle diffusion model. The obtained data were well-fitted to pseudo-second order model. According to intraparticle diffusion model, the adsorption process of Hg
2+
by SG-ODPPNE involves film diffusion, intraparticle diffusion, and equilibrium stages.
Graphical Abstract |
| doi_str_mv | 10.1007/s10971-017-4362-7 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2259552563</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1890233606</sourcerecordid><originalsourceid>FETCH-LOGICAL-c447t-1222627d7a6b241e1da348b0ac1e2881c43622f1684c03975396a04a345d28573</originalsourceid><addsrcrecordid>eNp9kbFOwzAURS0EEqXwAWyWWGAwPDuOnYxVBbQSEgvMluM4baokDnZa1I1_4A_5EhyVgQWmJ1nn3vueL0KXFG4pgLwLFHJJCVBJeCIYkUdoQlOZEJ5xcYwmkLOMgAR5is5C2ABAyqmcoP2s75va6KF2HXYVNmvdGNdZUuhgS1zWw7p2RvtCt3qwuLS-3kV4Z3HdGed75-NziYNrvj4-V7bBlfN4WFvsbet2uhk9Fyt8vVze4DGi8q7F71Hjz9FJpZtgL37mFL0-3L_MF-Tp-XE5nz0Rw7kcCGWMCSZLqUXBOLW01AnPCtCGWpZl1IznsoqKjBtIcpkmudDAI5SWLIs_MEVXB9_eu7etDYPauK3vYqRiLM3TlKUi-Y-iWQ4sSQSISNEDZbwLwdtK9b5utd8rCmrsQR16ULEHNS6mxnx20ITIdivrfzn_KfoGIQSKHQ</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2259552563</pqid></control><display><type>article</type><title>Application of chalcone-based dithiocarbamate derivative incorporated sol–gel for the removal of Hg (II) ion from water</title><source>Springer Nature - Complete Springer Journals</source><creator>Khor, Soo Wei ; Lee, Yean Kee ; Abas, Mhd Radzi Bin ; Tay, Kheng Soo</creator><creatorcontrib>Khor, Soo Wei ; Lee, Yean Kee ; Abas, Mhd Radzi Bin ; Tay, Kheng Soo</creatorcontrib><description>This study demonstrated the application of chalcone-based dithiocarbamate derivative as metal capturing ligand for the removal of mercury ion (Hg
2+
) in water. Chalcones are a group of naturally occurring compounds which can be obtained from fruits, vegetables, plants, and spice. In this study, chalcone was first chemically modified to produce dithiocarbamate derivative (ODPPNE). Chalcone and ODPPNE were then incorporated into sol–gel to produce SG-C and SG-ODPPNE, respectively, as adsorbents. The result from the adsorption study showed that with the presence of dithiocarbamate functional group, SG-ODPPNE exhibited the highest selectivity toward the adsorption of Hg
2+
with lesser response to Cr
3+
, Ni
2+
, Cu
2+
, Zn
2+
, Cd
2+
, and Pb
2+
. The adsorption of Hg
2+
by SG-ODPPNE was found to be adsorbent size, adsorbent dosage, contact time, the initial concentration of sorbate and pH dependent. The obtained experimental data were also analyzed using Freundlich and Langmuir adsorption models. The results showed that the adsorption data were well-fitted to Langmuir isotherm, and the monolayer absorption capacity was found to be 13.5 mg/g. In the absorption kinetic study, the data was analyzed using pseudo-first-order, pseudo-second-order kinetic model, and intraparticle diffusion model. The obtained data were well-fitted to pseudo-second order model. According to intraparticle diffusion model, the adsorption process of Hg
2+
by SG-ODPPNE involves film diffusion, intraparticle diffusion, and equilibrium stages.
Graphical Abstract</description><identifier>ISSN: 0928-0707</identifier><identifier>EISSN: 1573-4846</identifier><identifier>DOI: 10.1007/s10971-017-4362-7</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Absorption ; Adsorbents ; Adsorption ; Ceramics ; Chemistry and Materials Science ; Composites ; Copper ; Data analysis ; Diffusion ; Functional groups ; Glass ; Inorganic Chemistry ; Lead ; Ligands ; Materials Science ; Mercury (metal) ; Nanotechnology ; Natural Materials ; Optical and Electronic Materials ; Organic chemistry ; Original Paper: Sol-gel and hybrid materials with surface modification for applications ; Plants (botany) ; Selectivity ; Sol-gel processes</subject><ispartof>Journal of sol-gel science and technology, 2017-06, Vol.82 (3), p.834-845</ispartof><rights>Springer Science+Business Media New York 2017</rights><rights>Copyright Springer Science & Business Media 2017</rights><rights>Journal of Sol-Gel Science and Technology is a copyright of Springer, (2017). All Rights Reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c447t-1222627d7a6b241e1da348b0ac1e2881c43622f1684c03975396a04a345d28573</citedby><cites>FETCH-LOGICAL-c447t-1222627d7a6b241e1da348b0ac1e2881c43622f1684c03975396a04a345d28573</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10971-017-4362-7$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10971-017-4362-7$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27903,27904,41467,42536,51297</link.rule.ids></links><search><creatorcontrib>Khor, Soo Wei</creatorcontrib><creatorcontrib>Lee, Yean Kee</creatorcontrib><creatorcontrib>Abas, Mhd Radzi Bin</creatorcontrib><creatorcontrib>Tay, Kheng Soo</creatorcontrib><title>Application of chalcone-based dithiocarbamate derivative incorporated sol–gel for the removal of Hg (II) ion from water</title><title>Journal of sol-gel science and technology</title><addtitle>J Sol-Gel Sci Technol</addtitle><description>This study demonstrated the application of chalcone-based dithiocarbamate derivative as metal capturing ligand for the removal of mercury ion (Hg
2+
) in water. Chalcones are a group of naturally occurring compounds which can be obtained from fruits, vegetables, plants, and spice. In this study, chalcone was first chemically modified to produce dithiocarbamate derivative (ODPPNE). Chalcone and ODPPNE were then incorporated into sol–gel to produce SG-C and SG-ODPPNE, respectively, as adsorbents. The result from the adsorption study showed that with the presence of dithiocarbamate functional group, SG-ODPPNE exhibited the highest selectivity toward the adsorption of Hg
2+
with lesser response to Cr
3+
, Ni
2+
, Cu
2+
, Zn
2+
, Cd
2+
, and Pb
2+
. The adsorption of Hg
2+
by SG-ODPPNE was found to be adsorbent size, adsorbent dosage, contact time, the initial concentration of sorbate and pH dependent. The obtained experimental data were also analyzed using Freundlich and Langmuir adsorption models. The results showed that the adsorption data were well-fitted to Langmuir isotherm, and the monolayer absorption capacity was found to be 13.5 mg/g. In the absorption kinetic study, the data was analyzed using pseudo-first-order, pseudo-second-order kinetic model, and intraparticle diffusion model. The obtained data were well-fitted to pseudo-second order model. According to intraparticle diffusion model, the adsorption process of Hg
2+
by SG-ODPPNE involves film diffusion, intraparticle diffusion, and equilibrium stages.
Graphical Abstract</description><subject>Absorption</subject><subject>Adsorbents</subject><subject>Adsorption</subject><subject>Ceramics</subject><subject>Chemistry and Materials Science</subject><subject>Composites</subject><subject>Copper</subject><subject>Data analysis</subject><subject>Diffusion</subject><subject>Functional groups</subject><subject>Glass</subject><subject>Inorganic Chemistry</subject><subject>Lead</subject><subject>Ligands</subject><subject>Materials Science</subject><subject>Mercury (metal)</subject><subject>Nanotechnology</subject><subject>Natural Materials</subject><subject>Optical and Electronic Materials</subject><subject>Organic chemistry</subject><subject>Original Paper: Sol-gel and hybrid materials with surface modification for applications</subject><subject>Plants (botany)</subject><subject>Selectivity</subject><subject>Sol-gel processes</subject><issn>0928-0707</issn><issn>1573-4846</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNp9kbFOwzAURS0EEqXwAWyWWGAwPDuOnYxVBbQSEgvMluM4baokDnZa1I1_4A_5EhyVgQWmJ1nn3vueL0KXFG4pgLwLFHJJCVBJeCIYkUdoQlOZEJ5xcYwmkLOMgAR5is5C2ABAyqmcoP2s75va6KF2HXYVNmvdGNdZUuhgS1zWw7p2RvtCt3qwuLS-3kV4Z3HdGed75-NziYNrvj4-V7bBlfN4WFvsbet2uhk9Fyt8vVze4DGi8q7F71Hjz9FJpZtgL37mFL0-3L_MF-Tp-XE5nz0Rw7kcCGWMCSZLqUXBOLW01AnPCtCGWpZl1IznsoqKjBtIcpkmudDAI5SWLIs_MEVXB9_eu7etDYPauK3vYqRiLM3TlKUi-Y-iWQ4sSQSISNEDZbwLwdtK9b5utd8rCmrsQR16ULEHNS6mxnx20ITIdivrfzn_KfoGIQSKHQ</recordid><startdate>20170601</startdate><enddate>20170601</enddate><creator>Khor, Soo Wei</creator><creator>Lee, Yean Kee</creator><creator>Abas, Mhd Radzi Bin</creator><creator>Tay, Kheng Soo</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>L6V</scope><scope>M7S</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>PTHSS</scope></search><sort><creationdate>20170601</creationdate><title>Application of chalcone-based dithiocarbamate derivative incorporated sol–gel for the removal of Hg (II) ion from water</title><author>Khor, Soo Wei ; Lee, Yean Kee ; Abas, Mhd Radzi Bin ; Tay, Kheng Soo</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c447t-1222627d7a6b241e1da348b0ac1e2881c43622f1684c03975396a04a345d28573</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Absorption</topic><topic>Adsorbents</topic><topic>Adsorption</topic><topic>Ceramics</topic><topic>Chemistry and Materials Science</topic><topic>Composites</topic><topic>Copper</topic><topic>Data analysis</topic><topic>Diffusion</topic><topic>Functional groups</topic><topic>Glass</topic><topic>Inorganic Chemistry</topic><topic>Lead</topic><topic>Ligands</topic><topic>Materials Science</topic><topic>Mercury (metal)</topic><topic>Nanotechnology</topic><topic>Natural Materials</topic><topic>Optical and Electronic Materials</topic><topic>Organic chemistry</topic><topic>Original Paper: Sol-gel and hybrid materials with surface modification for applications</topic><topic>Plants (botany)</topic><topic>Selectivity</topic><topic>Sol-gel processes</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Khor, Soo Wei</creatorcontrib><creatorcontrib>Lee, Yean Kee</creatorcontrib><creatorcontrib>Abas, Mhd Radzi Bin</creatorcontrib><creatorcontrib>Tay, Kheng Soo</creatorcontrib><collection>CrossRef</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection (ProQuest)</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>ProQuest Engineering Collection</collection><collection>Engineering Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>Engineering Collection</collection><jtitle>Journal of sol-gel science and technology</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Khor, Soo Wei</au><au>Lee, Yean Kee</au><au>Abas, Mhd Radzi Bin</au><au>Tay, Kheng Soo</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Application of chalcone-based dithiocarbamate derivative incorporated sol–gel for the removal of Hg (II) ion from water</atitle><jtitle>Journal of sol-gel science and technology</jtitle><stitle>J Sol-Gel Sci Technol</stitle><date>2017-06-01</date><risdate>2017</risdate><volume>82</volume><issue>3</issue><spage>834</spage><epage>845</epage><pages>834-845</pages><issn>0928-0707</issn><eissn>1573-4846</eissn><abstract>This study demonstrated the application of chalcone-based dithiocarbamate derivative as metal capturing ligand for the removal of mercury ion (Hg
2+
) in water. Chalcones are a group of naturally occurring compounds which can be obtained from fruits, vegetables, plants, and spice. In this study, chalcone was first chemically modified to produce dithiocarbamate derivative (ODPPNE). Chalcone and ODPPNE were then incorporated into sol–gel to produce SG-C and SG-ODPPNE, respectively, as adsorbents. The result from the adsorption study showed that with the presence of dithiocarbamate functional group, SG-ODPPNE exhibited the highest selectivity toward the adsorption of Hg
2+
with lesser response to Cr
3+
, Ni
2+
, Cu
2+
, Zn
2+
, Cd
2+
, and Pb
2+
. The adsorption of Hg
2+
by SG-ODPPNE was found to be adsorbent size, adsorbent dosage, contact time, the initial concentration of sorbate and pH dependent. The obtained experimental data were also analyzed using Freundlich and Langmuir adsorption models. The results showed that the adsorption data were well-fitted to Langmuir isotherm, and the monolayer absorption capacity was found to be 13.5 mg/g. In the absorption kinetic study, the data was analyzed using pseudo-first-order, pseudo-second-order kinetic model, and intraparticle diffusion model. The obtained data were well-fitted to pseudo-second order model. According to intraparticle diffusion model, the adsorption process of Hg
2+
by SG-ODPPNE involves film diffusion, intraparticle diffusion, and equilibrium stages.
Graphical Abstract</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10971-017-4362-7</doi><tpages>12</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0928-0707 |
| ispartof | Journal of sol-gel science and technology, 2017-06, Vol.82 (3), p.834-845 |
| issn | 0928-0707 1573-4846 |
| language | eng |
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| source | Springer Nature - Complete Springer Journals |
| subjects | Absorption Adsorbents Adsorption Ceramics Chemistry and Materials Science Composites Copper Data analysis Diffusion Functional groups Glass Inorganic Chemistry Lead Ligands Materials Science Mercury (metal) Nanotechnology Natural Materials Optical and Electronic Materials Organic chemistry Original Paper: Sol-gel and hybrid materials with surface modification for applications Plants (botany) Selectivity Sol-gel processes |
| title | Application of chalcone-based dithiocarbamate derivative incorporated sol–gel for the removal of Hg (II) ion from water |
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