Solubility of porous MgF2 films in water: influence of glass substrates
MgF 2 antireflective coatings exposed to cold water show an increase of porosity and film delamination after prolonged soaking times. The related structural changes within the material were characterized by scanning electron microscopy and ellipsometric porosimetry. The glass substrate type used, na...
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Veröffentlicht in: | Journal of sol-gel science and technology 2017-04, Vol.82 (1), p.40-44 |
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creator | Hegmann, Jan Jahn, Rainer Löbmann, Peer |
description | MgF
2
antireflective coatings exposed to cold water show an increase of porosity and film delamination after prolonged soaking times. The related structural changes within the material were characterized by scanning electron microscopy and ellipsometric porosimetry. The glass substrate type used, namely its sodium content, has a pronounced effect on the film microstructure and its long-term solubility. The stability of MgF
2
films could significantly be improved by Na-doping of the coating solutions.
Graphical Abstract
Porous MgF
2
prepared by sol-gel processing dissolve and delaminate after prolonged exposure to water at room temperature. This behavior is influenced by different glass substrates; film stability can be significantly improved by doping of sodium to the coating solutions. |
doi_str_mv | 10.1007/s10971-016-4280-0 |
format | Article |
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2
antireflective coatings exposed to cold water show an increase of porosity and film delamination after prolonged soaking times. The related structural changes within the material were characterized by scanning electron microscopy and ellipsometric porosimetry. The glass substrate type used, namely its sodium content, has a pronounced effect on the film microstructure and its long-term solubility. The stability of MgF
2
films could significantly be improved by Na-doping of the coating solutions.
Graphical Abstract
Porous MgF
2
prepared by sol-gel processing dissolve and delaminate after prolonged exposure to water at room temperature. This behavior is influenced by different glass substrates; film stability can be significantly improved by doping of sodium to the coating solutions.</description><identifier>ISSN: 0928-0707</identifier><identifier>EISSN: 1573-4846</identifier><identifier>DOI: 10.1007/s10971-016-4280-0</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Antireflection coatings ; Ceramics ; Chemistry and Materials Science ; Cold water ; Composites ; Doping ; Ellipsometry ; Glass ; Glass substrates ; Inorganic Chemistry ; Magnesium fluorides ; Materials Science ; Nanotechnology ; Natural Materials ; Optical and Electronic Materials ; Original Paper: Functional coatings ; Porosity ; Room temperature ; Scanning electron microscopy ; Sodium ; Sol-gel processes ; Solubility ; Stability ; thin films and membranes (including deposition techniques)</subject><ispartof>Journal of sol-gel science and technology, 2017-04, Vol.82 (1), p.40-44</ispartof><rights>Springer Science+Business Media New York 2016</rights><rights>Copyright Springer Science & Business Media 2017</rights><rights>Journal of Sol-Gel Science and Technology is a copyright of Springer, (2016). All Rights Reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c344t-43d3952643b3162ccd9d914d5d695ec16919b14d5a32c9ad3235caa5498aefcf3</citedby><cites>FETCH-LOGICAL-c344t-43d3952643b3162ccd9d914d5d695ec16919b14d5a32c9ad3235caa5498aefcf3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10971-016-4280-0$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10971-016-4280-0$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27903,27904,41467,42536,51297</link.rule.ids></links><search><creatorcontrib>Hegmann, Jan</creatorcontrib><creatorcontrib>Jahn, Rainer</creatorcontrib><creatorcontrib>Löbmann, Peer</creatorcontrib><title>Solubility of porous MgF2 films in water: influence of glass substrates</title><title>Journal of sol-gel science and technology</title><addtitle>J Sol-Gel Sci Technol</addtitle><description>MgF
2
antireflective coatings exposed to cold water show an increase of porosity and film delamination after prolonged soaking times. The related structural changes within the material were characterized by scanning electron microscopy and ellipsometric porosimetry. The glass substrate type used, namely its sodium content, has a pronounced effect on the film microstructure and its long-term solubility. The stability of MgF
2
films could significantly be improved by Na-doping of the coating solutions.
Graphical Abstract
Porous MgF
2
prepared by sol-gel processing dissolve and delaminate after prolonged exposure to water at room temperature. This behavior is influenced by different glass substrates; film stability can be significantly improved by doping of sodium to the coating solutions.</description><subject>Antireflection coatings</subject><subject>Ceramics</subject><subject>Chemistry and Materials Science</subject><subject>Cold water</subject><subject>Composites</subject><subject>Doping</subject><subject>Ellipsometry</subject><subject>Glass</subject><subject>Glass substrates</subject><subject>Inorganic Chemistry</subject><subject>Magnesium fluorides</subject><subject>Materials Science</subject><subject>Nanotechnology</subject><subject>Natural Materials</subject><subject>Optical and Electronic Materials</subject><subject>Original Paper: Functional coatings</subject><subject>Porosity</subject><subject>Room temperature</subject><subject>Scanning electron microscopy</subject><subject>Sodium</subject><subject>Sol-gel processes</subject><subject>Solubility</subject><subject>Stability</subject><subject>thin films and membranes (including deposition techniques)</subject><issn>0928-0707</issn><issn>1573-4846</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><sourceid>BENPR</sourceid><recordid>eNp9kE1LxDAQhoMouK7-AG8Fz9HJV9N4k8VdhRUP6jmkaVq6dNs10yL7722pBy96mhnmeWfgIeSawS0D0HfIwGhGgaVU8gwonJAFU1pQmcn0lCzA8IyCBn1OLhB3AKAk0wuyeeuaIa-buj8mXZkcutgNmLxUa56UdbPHpG6TL9eHeD92ZTOE1ocJrBqHmOCQYx_HNV6Ss9I1GK5-6pJ8rB_fV090-7p5Xj1sqRdS9lSKQhjFUylywVLufWEKw2ShitSo4FlqmMmn2QnujSsEF8o7p6TJXCh9KZbkZr57iN3nELC3u26I7fjScq6MUqCF-o9iWQZaGZZNFJspHzvEGEp7iPXexaNlYCerdrZqR6t2smphzPA5gyPbViH-uvxn6BsKGnhl</recordid><startdate>20170401</startdate><enddate>20170401</enddate><creator>Hegmann, Jan</creator><creator>Jahn, Rainer</creator><creator>Löbmann, Peer</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>L6V</scope><scope>M7S</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>PTHSS</scope></search><sort><creationdate>20170401</creationdate><title>Solubility of porous MgF2 films in water: influence of glass substrates</title><author>Hegmann, Jan ; Jahn, Rainer ; Löbmann, Peer</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c344t-43d3952643b3162ccd9d914d5d695ec16919b14d5a32c9ad3235caa5498aefcf3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Antireflection coatings</topic><topic>Ceramics</topic><topic>Chemistry and Materials Science</topic><topic>Cold water</topic><topic>Composites</topic><topic>Doping</topic><topic>Ellipsometry</topic><topic>Glass</topic><topic>Glass substrates</topic><topic>Inorganic Chemistry</topic><topic>Magnesium fluorides</topic><topic>Materials Science</topic><topic>Nanotechnology</topic><topic>Natural Materials</topic><topic>Optical and Electronic Materials</topic><topic>Original Paper: Functional coatings</topic><topic>Porosity</topic><topic>Room temperature</topic><topic>Scanning electron microscopy</topic><topic>Sodium</topic><topic>Sol-gel processes</topic><topic>Solubility</topic><topic>Stability</topic><topic>thin films and membranes (including deposition techniques)</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Hegmann, Jan</creatorcontrib><creatorcontrib>Jahn, Rainer</creatorcontrib><creatorcontrib>Löbmann, Peer</creatorcontrib><collection>CrossRef</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>ProQuest Engineering Collection</collection><collection>Engineering Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>Engineering Collection</collection><jtitle>Journal of sol-gel science and technology</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Hegmann, Jan</au><au>Jahn, Rainer</au><au>Löbmann, Peer</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Solubility of porous MgF2 films in water: influence of glass substrates</atitle><jtitle>Journal of sol-gel science and technology</jtitle><stitle>J Sol-Gel Sci Technol</stitle><date>2017-04-01</date><risdate>2017</risdate><volume>82</volume><issue>1</issue><spage>40</spage><epage>44</epage><pages>40-44</pages><issn>0928-0707</issn><eissn>1573-4846</eissn><abstract>MgF
2
antireflective coatings exposed to cold water show an increase of porosity and film delamination after prolonged soaking times. The related structural changes within the material were characterized by scanning electron microscopy and ellipsometric porosimetry. The glass substrate type used, namely its sodium content, has a pronounced effect on the film microstructure and its long-term solubility. The stability of MgF
2
films could significantly be improved by Na-doping of the coating solutions.
Graphical Abstract
Porous MgF
2
prepared by sol-gel processing dissolve and delaminate after prolonged exposure to water at room temperature. This behavior is influenced by different glass substrates; film stability can be significantly improved by doping of sodium to the coating solutions.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10971-016-4280-0</doi><tpages>5</tpages></addata></record> |
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subjects | Antireflection coatings Ceramics Chemistry and Materials Science Cold water Composites Doping Ellipsometry Glass Glass substrates Inorganic Chemistry Magnesium fluorides Materials Science Nanotechnology Natural Materials Optical and Electronic Materials Original Paper: Functional coatings Porosity Room temperature Scanning electron microscopy Sodium Sol-gel processes Solubility Stability thin films and membranes (including deposition techniques) |
title | Solubility of porous MgF2 films in water: influence of glass substrates |
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