α-Axis oriented ZnS thin film synthesised by dip coating method
The structural, morphological, optical and electrical properties of α-axis oriented nanostructured ZnS thin film prepared by dip coating have been studied in this article. The X-ray diffraction studies of the film shows that the ZnS was crystallized with cubic structure of particle size 27 nm with a...
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| Veröffentlicht in: | Journal of sol-gel science and technology 2013-11, Vol.68 (2), p.351-355 |
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| creator | Bindu, K. R. Sreenivasan, P. V. Martinez, Arturo I. Anila, E. I. |
| description | The structural, morphological, optical and electrical properties of α-axis oriented nanostructured ZnS thin film prepared by dip coating have been studied in this article. The X-ray diffraction studies of the film shows that the ZnS was crystallized with cubic structure of particle size 27 nm with a strong orientation along (200) plane which is advantageous for optoelectronic devices. The scanning electron microscopy and TEM micrograph reveals that the film consists of nano crystalline columnar particles. From the investigation of the absorption spectra of this ZnS film, the band-gap is found to be higher (4 eV) than bulk (3.7 eV) indicating a blue shift. It is found that the film is having a transparency of >90 % in the visible-near IR region from 400 to 800 nm. From the photoconductivity measurements, it is evident that the film is photosensitive in nature. From the electrical resistivity measurements the conductivity of the film was found to be 3.4 × 10
−2
Ω
−1
cm
−1
. Hot probe method indicates that the synthesized ZnS film is n-type. |
| doi_str_mv | 10.1007/s10971-013-3177-4 |
| format | Article |
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−2
Ω
−1
cm
−1
. Hot probe method indicates that the synthesized ZnS film is n-type.</description><identifier>ISSN: 0928-0707</identifier><identifier>EISSN: 1573-4846</identifier><identifier>DOI: 10.1007/s10971-013-3177-4</identifier><language>eng</language><publisher>Boston: Springer US</publisher><subject>Absorption spectra ; Blue shift ; Ceramics ; Chemistry ; Chemistry and Materials Science ; Colloidal gels. Colloidal sols ; Colloidal state and disperse state ; Composites ; Crystallization ; Electrical properties ; Electrical resistivity ; Exact sciences and technology ; General and physical chemistry ; Glass ; Immersion coating ; Inorganic Chemistry ; Materials Science ; Nanotechnology ; Natural Materials ; Optical and Electronic Materials ; Optical properties ; Optoelectronic devices ; Original Paper ; Photoconductivity ; Photomicrographs ; Photosensitivity ; Scanning electron microscopy ; Thin films ; X-ray diffraction</subject><ispartof>Journal of sol-gel science and technology, 2013-11, Vol.68 (2), p.351-355</ispartof><rights>Springer Science+Business Media New York 2013</rights><rights>2015 INIST-CNRS</rights><rights>Journal of Sol-Gel Science and Technology is a copyright of Springer, (2013). All Rights Reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c346t-f1d7244c39f187770b233fd3ab38055c235a7320869c66da74584a44767582773</citedby><cites>FETCH-LOGICAL-c346t-f1d7244c39f187770b233fd3ab38055c235a7320869c66da74584a44767582773</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10971-013-3177-4$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10971-013-3177-4$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=27942579$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Bindu, K. R.</creatorcontrib><creatorcontrib>Sreenivasan, P. V.</creatorcontrib><creatorcontrib>Martinez, Arturo I.</creatorcontrib><creatorcontrib>Anila, E. I.</creatorcontrib><title>α-Axis oriented ZnS thin film synthesised by dip coating method</title><title>Journal of sol-gel science and technology</title><addtitle>J Sol-Gel Sci Technol</addtitle><description>The structural, morphological, optical and electrical properties of α-axis oriented nanostructured ZnS thin film prepared by dip coating have been studied in this article. The X-ray diffraction studies of the film shows that the ZnS was crystallized with cubic structure of particle size 27 nm with a strong orientation along (200) plane which is advantageous for optoelectronic devices. The scanning electron microscopy and TEM micrograph reveals that the film consists of nano crystalline columnar particles. From the investigation of the absorption spectra of this ZnS film, the band-gap is found to be higher (4 eV) than bulk (3.7 eV) indicating a blue shift. It is found that the film is having a transparency of >90 % in the visible-near IR region from 400 to 800 nm. From the photoconductivity measurements, it is evident that the film is photosensitive in nature. From the electrical resistivity measurements the conductivity of the film was found to be 3.4 × 10
−2
Ω
−1
cm
−1
. Hot probe method indicates that the synthesized ZnS film is n-type.</description><subject>Absorption spectra</subject><subject>Blue shift</subject><subject>Ceramics</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Colloidal gels. Colloidal sols</subject><subject>Colloidal state and disperse state</subject><subject>Composites</subject><subject>Crystallization</subject><subject>Electrical properties</subject><subject>Electrical resistivity</subject><subject>Exact sciences and technology</subject><subject>General and physical chemistry</subject><subject>Glass</subject><subject>Immersion coating</subject><subject>Inorganic Chemistry</subject><subject>Materials Science</subject><subject>Nanotechnology</subject><subject>Natural Materials</subject><subject>Optical and Electronic Materials</subject><subject>Optical properties</subject><subject>Optoelectronic devices</subject><subject>Original Paper</subject><subject>Photoconductivity</subject><subject>Photomicrographs</subject><subject>Photosensitivity</subject><subject>Scanning electron microscopy</subject><subject>Thin films</subject><subject>X-ray diffraction</subject><issn>0928-0707</issn><issn>1573-4846</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><sourceid>BENPR</sourceid><recordid>eNp1kMtKAzEUhoMoWKsP4C4gLqMntzmTnaV4g4ILdeMmpDOZNqXN1GQE-1i-iM_klBZduTqL8_3_OXyEnHO44gB4nTkY5Ay4ZJIjMnVABlyjZKpUxSEZgBElAwQ8Jic5LwBAK44DcvP9xUafIdM2BR87X9O3-Ey7eYi0CcsVzZvYzX0Oud9MN7QOa1q1rgtxRle-m7f1KTlq3DL7s_0ckte725fxA5s83T-ORxNWSVV0rOE1CqUqaRpeIiJMhZRNLd1UlqB1JaR2KAWUhamKonaodKmcUligLgWiHJKLXe86te8fPnd20X6k2J-0QmijpVEgeorvqCq1OSff2HUKK5c2loPdirI7UbYXZbeirOozl_tmlyu3bJKLVci_QYFGCY2m58SOy_0qznz6--D_8h-rTXXX</recordid><startdate>20131101</startdate><enddate>20131101</enddate><creator>Bindu, K. 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I.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c346t-f1d7244c39f187770b233fd3ab38055c235a7320869c66da74584a44767582773</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><topic>Absorption spectra</topic><topic>Blue shift</topic><topic>Ceramics</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Colloidal gels. Colloidal sols</topic><topic>Colloidal state and disperse state</topic><topic>Composites</topic><topic>Crystallization</topic><topic>Electrical properties</topic><topic>Electrical resistivity</topic><topic>Exact sciences and technology</topic><topic>General and physical chemistry</topic><topic>Glass</topic><topic>Immersion coating</topic><topic>Inorganic Chemistry</topic><topic>Materials Science</topic><topic>Nanotechnology</topic><topic>Natural Materials</topic><topic>Optical and Electronic Materials</topic><topic>Optical properties</topic><topic>Optoelectronic devices</topic><topic>Original Paper</topic><topic>Photoconductivity</topic><topic>Photomicrographs</topic><topic>Photosensitivity</topic><topic>Scanning electron microscopy</topic><topic>Thin films</topic><topic>X-ray diffraction</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Bindu, K. R.</creatorcontrib><creatorcontrib>Sreenivasan, P. 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R.</au><au>Sreenivasan, P. V.</au><au>Martinez, Arturo I.</au><au>Anila, E. I.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>α-Axis oriented ZnS thin film synthesised by dip coating method</atitle><jtitle>Journal of sol-gel science and technology</jtitle><stitle>J Sol-Gel Sci Technol</stitle><date>2013-11-01</date><risdate>2013</risdate><volume>68</volume><issue>2</issue><spage>351</spage><epage>355</epage><pages>351-355</pages><issn>0928-0707</issn><eissn>1573-4846</eissn><abstract>The structural, morphological, optical and electrical properties of α-axis oriented nanostructured ZnS thin film prepared by dip coating have been studied in this article. The X-ray diffraction studies of the film shows that the ZnS was crystallized with cubic structure of particle size 27 nm with a strong orientation along (200) plane which is advantageous for optoelectronic devices. The scanning electron microscopy and TEM micrograph reveals that the film consists of nano crystalline columnar particles. From the investigation of the absorption spectra of this ZnS film, the band-gap is found to be higher (4 eV) than bulk (3.7 eV) indicating a blue shift. It is found that the film is having a transparency of >90 % in the visible-near IR region from 400 to 800 nm. From the photoconductivity measurements, it is evident that the film is photosensitive in nature. From the electrical resistivity measurements the conductivity of the film was found to be 3.4 × 10
−2
Ω
−1
cm
−1
. Hot probe method indicates that the synthesized ZnS film is n-type.</abstract><cop>Boston</cop><pub>Springer US</pub><doi>10.1007/s10971-013-3177-4</doi><tpages>5</tpages></addata></record> |
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| subjects | Absorption spectra Blue shift Ceramics Chemistry Chemistry and Materials Science Colloidal gels. Colloidal sols Colloidal state and disperse state Composites Crystallization Electrical properties Electrical resistivity Exact sciences and technology General and physical chemistry Glass Immersion coating Inorganic Chemistry Materials Science Nanotechnology Natural Materials Optical and Electronic Materials Optical properties Optoelectronic devices Original Paper Photoconductivity Photomicrographs Photosensitivity Scanning electron microscopy Thin films X-ray diffraction |
| title | α-Axis oriented ZnS thin film synthesised by dip coating method |
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