Reaction of the novel Ru3(CO)10[Ph2P(CH2)2Si(OEt3)]2 complex on SBA-15 and MCM-41 mesoporous silicas
The reaction of Ru 3 (CO) 12 with 2(diphenylphosphino)ethyl-triethoxysilane (DPTS) in hydrocarbons, leads to the functionalized Ru 3 (CO) 12− n [Ph 2 P(CH 2 ) 2 Si(OEt 3 )] n ( n = 1,2) complexes. The complex with two phosphine substituents was chemically anchored on mesoporous silicas, SBA-15 and...
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| Veröffentlicht in: | Journal of sol-gel science and technology 2009-11, Vol.52 (2), p.235-241 |
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| container_title | Journal of sol-gel science and technology |
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| creator | Carniato, Fabio Secco, Andrea Gatti, Giorgio Marchese, Leonardo Sappa, Enrico |
| description | The reaction of Ru
3
(CO)
12
with 2(diphenylphosphino)ethyl-triethoxysilane (DPTS) in hydrocarbons, leads to the functionalized Ru
3
(CO)
12−
n
[Ph
2
P(CH
2
)
2
Si(OEt
3
)]
n
(
n
= 1,2) complexes. The complex with two phosphine substituents was chemically anchored on mesoporous silicas, SBA-15 and MCM-41, in order to obtain two hybrid materials characterized by a different localization of the metal centre on the surface of the porous supports. A detailed investigation of the cluster, before and after chemical anchoring on the mesoporous silicas, was pursued. Particular attention was also devoted to the study of the morphological, structural and textural properties of the metal-functionalised silicas (Ru/SBA-15 and Ru/MCM-41) by infrared spectroscopy (FT-IR), scanning electron microscopy, X-ray diffraction and N
2
physisorption analysis. |
| doi_str_mv | 10.1007/s10971-009-2018-y |
| format | Article |
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3
(CO)
12
with 2(diphenylphosphino)ethyl-triethoxysilane (DPTS) in hydrocarbons, leads to the functionalized Ru
3
(CO)
12−
n
[Ph
2
P(CH
2
)
2
Si(OEt
3
)]
n
(
n
= 1,2) complexes. The complex with two phosphine substituents was chemically anchored on mesoporous silicas, SBA-15 and MCM-41, in order to obtain two hybrid materials characterized by a different localization of the metal centre on the surface of the porous supports. A detailed investigation of the cluster, before and after chemical anchoring on the mesoporous silicas, was pursued. Particular attention was also devoted to the study of the morphological, structural and textural properties of the metal-functionalised silicas (Ru/SBA-15 and Ru/MCM-41) by infrared spectroscopy (FT-IR), scanning electron microscopy, X-ray diffraction and N
2
physisorption analysis.</description><identifier>ISSN: 0928-0707</identifier><identifier>EISSN: 1573-4846</identifier><identifier>DOI: 10.1007/s10971-009-2018-y</identifier><language>eng</language><publisher>Boston: Springer US</publisher><subject>Anchoring ; Ceramics ; Chemistry ; Chemistry and Materials Science ; Colloidal gels. Colloidal sols ; Colloidal state and disperse state ; Composites ; Exact sciences and technology ; General and physical chemistry ; Glass ; Infrared analysis ; Infrared spectroscopy ; Inorganic Chemistry ; Materials Science ; Nanotechnology ; Natural Materials ; Optical and Electronic Materials ; Organic chemistry ; Original Paper ; Porous materials ; Scanning electron microscopy ; X-ray diffraction</subject><ispartof>Journal of sol-gel science and technology, 2009-11, Vol.52 (2), p.235-241</ispartof><rights>Springer Science+Business Media, LLC 2009</rights><rights>2009 INIST-CNRS</rights><rights>Journal of Sol-Gel Science and Technology is a copyright of Springer, (2009). All Rights Reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c261y-e8f3ca43411bc3601aa76a152bc15f1b0ce3279bb1c8e01035af233331be8fa3</citedby><cites>FETCH-LOGICAL-c261y-e8f3ca43411bc3601aa76a152bc15f1b0ce3279bb1c8e01035af233331be8fa3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10971-009-2018-y$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10971-009-2018-y$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=22036704$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Carniato, Fabio</creatorcontrib><creatorcontrib>Secco, Andrea</creatorcontrib><creatorcontrib>Gatti, Giorgio</creatorcontrib><creatorcontrib>Marchese, Leonardo</creatorcontrib><creatorcontrib>Sappa, Enrico</creatorcontrib><title>Reaction of the novel Ru3(CO)10[Ph2P(CH2)2Si(OEt3)]2 complex on SBA-15 and MCM-41 mesoporous silicas</title><title>Journal of sol-gel science and technology</title><addtitle>J Sol-Gel Sci Technol</addtitle><description>The reaction of Ru
3
(CO)
12
with 2(diphenylphosphino)ethyl-triethoxysilane (DPTS) in hydrocarbons, leads to the functionalized Ru
3
(CO)
12−
n
[Ph
2
P(CH
2
)
2
Si(OEt
3
)]
n
(
n
= 1,2) complexes. The complex with two phosphine substituents was chemically anchored on mesoporous silicas, SBA-15 and MCM-41, in order to obtain two hybrid materials characterized by a different localization of the metal centre on the surface of the porous supports. A detailed investigation of the cluster, before and after chemical anchoring on the mesoporous silicas, was pursued. Particular attention was also devoted to the study of the morphological, structural and textural properties of the metal-functionalised silicas (Ru/SBA-15 and Ru/MCM-41) by infrared spectroscopy (FT-IR), scanning electron microscopy, X-ray diffraction and N
2
physisorption analysis.</description><subject>Anchoring</subject><subject>Ceramics</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Colloidal gels. Colloidal sols</subject><subject>Colloidal state and disperse state</subject><subject>Composites</subject><subject>Exact sciences and technology</subject><subject>General and physical chemistry</subject><subject>Glass</subject><subject>Infrared analysis</subject><subject>Infrared spectroscopy</subject><subject>Inorganic Chemistry</subject><subject>Materials Science</subject><subject>Nanotechnology</subject><subject>Natural Materials</subject><subject>Optical and Electronic Materials</subject><subject>Organic chemistry</subject><subject>Original Paper</subject><subject>Porous materials</subject><subject>Scanning electron microscopy</subject><subject>X-ray diffraction</subject><issn>0928-0707</issn><issn>1573-4846</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2009</creationdate><recordtype>article</recordtype><sourceid>BENPR</sourceid><recordid>eNp1kE1LAzEQhoMoWD9-gLeACO0hOpNsNrtHXeoHKC3Vm0jIxqyubDc1acX-eyMVPZnLHPI87wwvIUcIpwigziJCqZABlIwDFmy9RQYolWBZkeXbZAAlLxgoULtkL8Y3AJAZqgF5njljl63vqW_o8tXR3n-4js5WYlhNRgiP01c-HVbXfMTv2-FkvBSjJ06tny8690mTdn9xzlBS0z_Tu-qOZUjnLvqFD34VaWy71pp4QHYa00V3-DP3ycPl-KG6ZreTq5vq_JZZnuOauaIR1mQiQ6ytyAGNUblByWuLssEarBNclXWNtnCAIKRpuEgP66QasU-ON7GL4N9XLi71m1-FPm3UnMtSCsyETBRuKBt8jME1ehHauQlrjaC_u9SbLnXqUn93qdfJOflJNtGargmmt238FTkHkSvIEsc3XExf_YsLfxf8H_4FZMN_iA</recordid><startdate>200911</startdate><enddate>200911</enddate><creator>Carniato, Fabio</creator><creator>Secco, Andrea</creator><creator>Gatti, Giorgio</creator><creator>Marchese, Leonardo</creator><creator>Sappa, Enrico</creator><general>Springer US</general><general>Springer</general><general>Springer Nature B.V</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>L6V</scope><scope>M7S</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>PTHSS</scope></search><sort><creationdate>200911</creationdate><title>Reaction of the novel Ru3(CO)10[Ph2P(CH2)2Si(OEt3)]2 complex on SBA-15 and MCM-41 mesoporous silicas</title><author>Carniato, Fabio ; Secco, Andrea ; Gatti, Giorgio ; Marchese, Leonardo ; Sappa, Enrico</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c261y-e8f3ca43411bc3601aa76a152bc15f1b0ce3279bb1c8e01035af233331be8fa3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2009</creationdate><topic>Anchoring</topic><topic>Ceramics</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Colloidal gels. Colloidal sols</topic><topic>Colloidal state and disperse state</topic><topic>Composites</topic><topic>Exact sciences and technology</topic><topic>General and physical chemistry</topic><topic>Glass</topic><topic>Infrared analysis</topic><topic>Infrared spectroscopy</topic><topic>Inorganic Chemistry</topic><topic>Materials Science</topic><topic>Nanotechnology</topic><topic>Natural Materials</topic><topic>Optical and Electronic Materials</topic><topic>Organic chemistry</topic><topic>Original Paper</topic><topic>Porous materials</topic><topic>Scanning electron microscopy</topic><topic>X-ray diffraction</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Carniato, Fabio</creatorcontrib><creatorcontrib>Secco, Andrea</creatorcontrib><creatorcontrib>Gatti, Giorgio</creatorcontrib><creatorcontrib>Marchese, Leonardo</creatorcontrib><creatorcontrib>Sappa, Enrico</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>ProQuest Engineering Collection</collection><collection>Engineering Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>Engineering Collection</collection><jtitle>Journal of sol-gel science and technology</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Carniato, Fabio</au><au>Secco, Andrea</au><au>Gatti, Giorgio</au><au>Marchese, Leonardo</au><au>Sappa, Enrico</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Reaction of the novel Ru3(CO)10[Ph2P(CH2)2Si(OEt3)]2 complex on SBA-15 and MCM-41 mesoporous silicas</atitle><jtitle>Journal of sol-gel science and technology</jtitle><stitle>J Sol-Gel Sci Technol</stitle><date>2009-11</date><risdate>2009</risdate><volume>52</volume><issue>2</issue><spage>235</spage><epage>241</epage><pages>235-241</pages><issn>0928-0707</issn><eissn>1573-4846</eissn><abstract>The reaction of Ru
3
(CO)
12
with 2(diphenylphosphino)ethyl-triethoxysilane (DPTS) in hydrocarbons, leads to the functionalized Ru
3
(CO)
12−
n
[Ph
2
P(CH
2
)
2
Si(OEt
3
)]
n
(
n
= 1,2) complexes. The complex with two phosphine substituents was chemically anchored on mesoporous silicas, SBA-15 and MCM-41, in order to obtain two hybrid materials characterized by a different localization of the metal centre on the surface of the porous supports. A detailed investigation of the cluster, before and after chemical anchoring on the mesoporous silicas, was pursued. Particular attention was also devoted to the study of the morphological, structural and textural properties of the metal-functionalised silicas (Ru/SBA-15 and Ru/MCM-41) by infrared spectroscopy (FT-IR), scanning electron microscopy, X-ray diffraction and N
2
physisorption analysis.</abstract><cop>Boston</cop><pub>Springer US</pub><doi>10.1007/s10971-009-2018-y</doi><tpages>7</tpages></addata></record> |
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| issn | 0928-0707 1573-4846 |
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| subjects | Anchoring Ceramics Chemistry Chemistry and Materials Science Colloidal gels. Colloidal sols Colloidal state and disperse state Composites Exact sciences and technology General and physical chemistry Glass Infrared analysis Infrared spectroscopy Inorganic Chemistry Materials Science Nanotechnology Natural Materials Optical and Electronic Materials Organic chemistry Original Paper Porous materials Scanning electron microscopy X-ray diffraction |
| title | Reaction of the novel Ru3(CO)10[Ph2P(CH2)2Si(OEt3)]2 complex on SBA-15 and MCM-41 mesoporous silicas |
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