Fabrication of UV-curable silicone coating with high transmittance and laser-induced damage threshold for high-power laser system

Third harmonic generating (THG) element is an important component for high-power laser system and its incident side is in need of high transmittance and laser-induced damage threshold (LIDT) at specified wavelengths (1064 nm and 532 nm) to meet the demand of laser-driven inertial confinement fusion....

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Veröffentlicht in:Journal of sol-gel science and technology 2018-10, Vol.88 (1), p.249-254
Hauptverfasser: Deng, Xue-Ran, Yang, Wei, Zhang, Qing-Hua, Hui, Hao-Hao, Wei, Yao-Wei, Wang, Jian, Xu, Qiao, Lei, Xiang-Yang, Chen, Jin-Ju, Zhu, Ji-Liang
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container_issue 1
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container_title Journal of sol-gel science and technology
container_volume 88
creator Deng, Xue-Ran
Yang, Wei
Zhang, Qing-Hua
Hui, Hao-Hao
Wei, Yao-Wei
Wang, Jian
Xu, Qiao
Lei, Xiang-Yang
Chen, Jin-Ju
Zhu, Ji-Liang
description Third harmonic generating (THG) element is an important component for high-power laser system and its incident side is in need of high transmittance and laser-induced damage threshold (LIDT) at specified wavelengths (1064 nm and 532 nm) to meet the demand of laser-driven inertial confinement fusion. An UV-curable organic–inorganic hybrid silicone coating was fabricated for this THG element and its relevant properties have been investigated. Si–O–Si backbone structure in combination with characteristics from a mixture of tripropyleneglycoldiacrylate (TPGDA) as a reactive diluent and Darocur 1173 (HMPP) as a photoinitiator provided qualified adhesion, hardness, transmittance, and laser damage resistance for the UV-cured coating. Based on this design, THG element with both high transmittance and LIDT at specified wavelengths was successfully achieved after the solidification of coatings by means of UV irradiation, which provides an alternate option to cure coatings upon the temperature-sensitive substrates (like potassium dideuterium phosphate (DKDP), ammonium dihydrogen phosphate (ADP), and so on) without heating, and meanwhile greatly reduces the time consumption of curing process. Highlights Photopolymerization of silicone coating is applied in high-power laser system. Qualified optical, mechanical, and laser-resistant property is achieved. The phase transition problem of precious DKDP crystal is solved.
doi_str_mv 10.1007/s10971-018-4807-7
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An UV-curable organic–inorganic hybrid silicone coating was fabricated for this THG element and its relevant properties have been investigated. Si–O–Si backbone structure in combination with characteristics from a mixture of tripropyleneglycoldiacrylate (TPGDA) as a reactive diluent and Darocur 1173 (HMPP) as a photoinitiator provided qualified adhesion, hardness, transmittance, and laser damage resistance for the UV-cured coating. Based on this design, THG element with both high transmittance and LIDT at specified wavelengths was successfully achieved after the solidification of coatings by means of UV irradiation, which provides an alternate option to cure coatings upon the temperature-sensitive substrates (like potassium dideuterium phosphate (DKDP), ammonium dihydrogen phosphate (ADP), and so on) without heating, and meanwhile greatly reduces the time consumption of curing process. Highlights Photopolymerization of silicone coating is applied in high-power laser system. Qualified optical, mechanical, and laser-resistant property is achieved. 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An UV-curable organic–inorganic hybrid silicone coating was fabricated for this THG element and its relevant properties have been investigated. Si–O–Si backbone structure in combination with characteristics from a mixture of tripropyleneglycoldiacrylate (TPGDA) as a reactive diluent and Darocur 1173 (HMPP) as a photoinitiator provided qualified adhesion, hardness, transmittance, and laser damage resistance for the UV-cured coating. Based on this design, THG element with both high transmittance and LIDT at specified wavelengths was successfully achieved after the solidification of coatings by means of UV irradiation, which provides an alternate option to cure coatings upon the temperature-sensitive substrates (like potassium dideuterium phosphate (DKDP), ammonium dihydrogen phosphate (ADP), and so on) without heating, and meanwhile greatly reduces the time consumption of curing process. Highlights Photopolymerization of silicone coating is applied in high-power laser system. Qualified optical, mechanical, and laser-resistant property is achieved. 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An UV-curable organic–inorganic hybrid silicone coating was fabricated for this THG element and its relevant properties have been investigated. Si–O–Si backbone structure in combination with characteristics from a mixture of tripropyleneglycoldiacrylate (TPGDA) as a reactive diluent and Darocur 1173 (HMPP) as a photoinitiator provided qualified adhesion, hardness, transmittance, and laser damage resistance for the UV-cured coating. Based on this design, THG element with both high transmittance and LIDT at specified wavelengths was successfully achieved after the solidification of coatings by means of UV irradiation, which provides an alternate option to cure coatings upon the temperature-sensitive substrates (like potassium dideuterium phosphate (DKDP), ammonium dihydrogen phosphate (ADP), and so on) without heating, and meanwhile greatly reduces the time consumption of curing process. Highlights Photopolymerization of silicone coating is applied in high-power laser system. Qualified optical, mechanical, and laser-resistant property is achieved. The phase transition problem of precious DKDP crystal is solved.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10971-018-4807-7</doi><tpages>6</tpages><orcidid>https://orcid.org/0000-0002-5331-4332</orcidid></addata></record>
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subjects Ammonium dihydrogen phosphate
Ceramics
Chemistry and Materials Science
Coatings
Composites
Glass
High power lasers
Inertial confinement fusion
Inorganic Chemistry
Laser damage
Lasers
Materials Science
Nanotechnology
Natural Materials
Optical and Electronic Materials
Optical properties
Original Paper: Sol-gel and hybrid materials for optical
Phase transitions
photonic and optoelectronic applications
Photopolymerization
Silicon
Solidification
Substrates
Transmittance
Ultraviolet radiation
Wavelengths
Yield point
title Fabrication of UV-curable silicone coating with high transmittance and laser-induced damage threshold for high-power laser system
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