Structural, dielectric and ferromagnetic properties of nano-crystalline Co-doped SnS

Doping-induced tuning of host semiconductors properties offers an efficient way to realize the desired physical properties. In this study, we have synthesized pure and Co-doped SnS-diluted magnetic semiconductors with x Co  = 0.00–0.10, by employing a very simple and low-cost chemical co-precipitati...

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Veröffentlicht in:Journal of materials science 2017-06, Vol.52 (12), p.7369-7381
Hauptverfasser: Parveen, B., Hassan, M., Atiq, S., Riaz, S., Naseem, S., Zaman, Sher
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container_issue 12
container_start_page 7369
container_title Journal of materials science
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creator Parveen, B.
Hassan, M.
Atiq, S.
Riaz, S.
Naseem, S.
Zaman, Sher
description Doping-induced tuning of host semiconductors properties offers an efficient way to realize the desired physical properties. In this study, we have synthesized pure and Co-doped SnS-diluted magnetic semiconductors with x Co  = 0.00–0.10, by employing a very simple and low-cost chemical co-precipitation technique. The structural properties, determined through X-ray diffraction, have confirmed single-phase orthorhombic structure and have depicted nano-crystallites. Near-edge X-ray absorption fine structure spectroscopy has revealed a Co-doping-induced shift in the absorption edge towards lower energy, indicating a change in the Co oxidation state. Surface morphology observed through scanning electron microscopy indicates nano-structured surface. Dielectric properties measured by impedance analyzer (LCR meter) in the frequency range 1 kHz–20 MHz depict that grown materials respond to the electromagnetic radiations suggesting potential device applications. Complex impedance spectroscopy illustrates the dominance of grain resistance. The magnetic properties observed by vibrating sample magnetometer reveal room temperature ferromagnetism, and Co ions inducing tuning of the ferromagnetism suggests potential applications in the data storage devices.
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subjects Analysis
Characterization and Evaluation of Materials
Chemical precipitation
Chemicals
Chemistry and Materials Science
Classical Mechanics
Crystallites
Crystallography and Scattering Methods
Data storage
Dielectric materials
Dielectric properties
Doping
Electrical conductivity
Electromagnetic radiation
Electronic devices
Ferromagnetism
Fine structure
Frequency ranges
Information storage and retrieval
Magnetic properties
Magnetic semiconductors
Materials Science
Morphology
Organic chemistry
Original Paper
Oxidation
Physical properties
Polymer Sciences
Precipitation (Meteorology)
Scanning electron microscopy
Semiconductors
Semiconductors (Materials)
Solid Mechanics
Spectrum analysis
Surface chemistry
Tuning
Valence
X ray absorption
X-ray diffraction
title Structural, dielectric and ferromagnetic properties of nano-crystalline Co-doped SnS
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