Predicting the hydroxymethylation rate of phenols with formaldehyde by molecular orbital calculation

The rates (k) of hydroxymethylation of phenol, resorcinol, phloroglucinol, and several methylphenols in diluted 10% dimethylformamide aqueous alkaline solution were calculated based on the consumption of phenols and formaldehyde. The k values of phloroglucinol and resorcinol relative to that of phen...

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Veröffentlicht in:	Journal of wood science 2002-04, Vol.48 (2), p.153-158
Hauptverfasser:	Mitsunaga, T. (Mie Univ., Tsu (Japan). Faculty of Bioresources), Conner, A.H, Hill, C.G.Jr
Format:	Artikel
Sprache:	eng
Schlagworte:	ADHESIVES Application fields Applied sciences Aromatic compounds CHEMICAL REACTIONS Diphenols Exact sciences and technology FORMALDEHYDE Hydroxyl groups IMPROVED WOOD Mathematical analysis Miscellaneous Molecular orbitals PHENOLIC COMPOUNDS Phenols Phloroglucinol Polymer industry, paints, wood Rate constants Technology of polymers Wood WOOD INDUSTRY Wood. Paper. Non wovens
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