A novel method of direct synthesis of dimethyl carbonate from methanol and carbon dioxide catalyzed by zirconia
Dimethyl carbonate was synthesized from methanol and CO2 with high selectivity using ZrO2 catalysts. In this reaction, the amount of dimethyl ether and CO was below the detection limit. The catalytic activity seems to be related to acid–base pair sites of the ZrO2 surface from the results of tempera...
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| Veröffentlicht in: | Catalysis letters 1999-01, Vol.58 (4), p.225-229 |
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| creator | TOMISHIGE, K SAKAIHORI, T IKEDA, Y FUJIMOTO, K |
| description | Dimethyl carbonate was synthesized from methanol and CO2 with high selectivity using ZrO2 catalysts. In this reaction, the amount of dimethyl ether and CO was below the detection limit. The catalytic activity seems to be related to acid–base pair sites of the ZrO2 surface from the results of temperature‐programmed desorption of NH3 and CO2. |
| doi_str_mv | 10.1023/A:1019098405444 |
| format | Article |
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| fulltext | fulltext |
| identifier | ISSN: 1011-372X |
| ispartof | Catalysis letters, 1999-01, Vol.58 (4), p.225-229 |
| issn | 1011-372X 1572-879X |
| language | eng |
| recordid | cdi_proquest_journals_2259023626 |
| source | SpringerNature Journals |
| subjects | Ammonia Carbon dioxide Catalysis Catalytic activity Catalytic reactions Chemistry Dimethyl ether Exact sciences and technology General and physical chemistry Methanol Selectivity Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry Zirconium dioxide |
| title | A novel method of direct synthesis of dimethyl carbonate from methanol and carbon dioxide catalyzed by zirconia |
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