The transition state for metal-catalyzed dehalogenation

Substituent effects have been used to probe the nature of the transition state to catalytic carbon–halogen bond breaking. Kinetics measurements have determined the activation energies (Eact to C–Cl bond breaking on the Pd(111) surface and C–I bond breaking on the Pd(111) and Ag(111) surfaces. These...

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Veröffentlicht in:	Catalysis letters 1999-01, Vol.59 (1), p.9-13
Hauptverfasser:	BUELOW, M. T, GE ZHOU, GELLMAN, A. J, IMMARAPORN, B
Format:	Artikel
Sprache:	eng
Schlagworte:	Activation energy Breaking Catalysis Chemistry Cleavage Ductile-brittle transition Exact sciences and technology Fluorination Fluorine Fracture mechanics General and physical chemistry Halides Hydrodechlorination Palladium Reaction kinetics Silver Substitution reactions Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
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