N2O Decomposition Catalysed by Transition Metal Ions

N2O Decomposition Catalysed by Transition Metal Ions

The direct N2O decomposition catalysed by 5-coordinated transition metal ions Fe, Co, and Rh was studied using the DFT method. The cluster model has the formula M(OH)3(H2O)2. Energies of intermediates and transition states were computed. The results show that Co and Rh sites are more active than Fe,...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Catalysis letters 2001-08, Vol.75 (1-2), p.45-48
Hauptverfasser: Yakovlev, Alexei L, Zhidomirov, Georgy M, van Santen, Rutger A
Format: Artikel
Sprache:eng
Schlagworte:
Cobalt
Decomposition
Iron
Metal ions
Nitrous oxide
Rhodium
Transition metals
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:The direct N2O decomposition catalysed by 5-coordinated transition metal ions Fe, Co, and Rh was studied using the DFT method. The cluster model has the formula M(OH)3(H2O)2. Energies of intermediates and transition states were computed. The results show that Co and Rh sites are more active than Fe, the former two being very similar.
ISSN:1011-372X
1572-879X
DOI:10.1023/A:1016692419859