Highly stereoselective epoxidation of (-)-α-pinene over chiral transition metal (salen) complexes occluded in zeolitic hosts

Various transition metal complexes of seven different salen ligands have been incorporated in specially modified zeolitic host materials. The thus immobilized sterically demanding complexes have been tested in the diastereoselective epoxidation of (−)-α-pinene in the liquid phase in an autoclave at...

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Veröffentlicht in:	Catalysis letters 2001-01, Vol.74 (1-2), p.69-75
Hauptverfasser:	SCHUSTER, Carmen, MÖLLMANN, Eugen, TOMPOS, Andras, HÖLDERICH, Wolfgang F
Format:	Artikel
Sprache:	eng
Schlagworte:	Autoclaving Catalysis Catalytic reactions Chemistry Computer simulation Coordination compounds Epoxidation Exact sciences and technology General and physical chemistry Liquid phases Stereoselectivity Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry Transition metal compounds
Online-Zugang:	Volltext
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