Selective Hydrogenation of Cinnamaldehyde over (111) Preferentially Oriented Pt Particles Supported on Expanded Graphite
(111) preferentially oriented Pt nanoparticles supported on expanded graphite were prepared by impregnation of the support with an aqueous solution of H₂PtCl₆. The catalyst was characterized by a number of techniques and tested in the liquid-phase hydrogenation of cinnamaldehyde. The preferential su...
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| Veröffentlicht in: | Catalysis letters 2009-12, Vol.133 (3-4), p.267-272 |
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| creator | Ramos-Fernández, E. V Ramos-Fernández, J. M Martínez-Escandell, M Sepúlveda-Escribano, A Rodríguez-Reinoso, F |
| description | (111) preferentially oriented Pt nanoparticles supported on expanded graphite were prepared by impregnation of the support with an aqueous solution of H₂PtCl₆. The catalyst was characterized by a number of techniques and tested in the liquid-phase hydrogenation of cinnamaldehyde. The preferential surface orientation of the metal particles favours a very high selectivity towards the hydrogenation of the carbonyl bond of cinnamaldehyde to yield cinnamyl alcohol. The performance of this catalytic system is comparable to that obtained with similar catalysts prepared by more complex methods. Furthermore, expanded graphite provides a good alternative as support to other graphitic materials such as carbon nanotubes and carbon nanofibres. |
| doi_str_mv | 10.1007/s10562-009-0175-9 |
| format | Article |
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V ; Ramos-Fernández, J. M ; Martínez-Escandell, M ; Sepúlveda-Escribano, A ; Rodríguez-Reinoso, F</creator><creatorcontrib>Ramos-Fernández, E. V ; Ramos-Fernández, J. M ; Martínez-Escandell, M ; Sepúlveda-Escribano, A ; Rodríguez-Reinoso, F</creatorcontrib><description>(111) preferentially oriented Pt nanoparticles supported on expanded graphite were prepared by impregnation of the support with an aqueous solution of H₂PtCl₆. The catalyst was characterized by a number of techniques and tested in the liquid-phase hydrogenation of cinnamaldehyde. The preferential surface orientation of the metal particles favours a very high selectivity towards the hydrogenation of the carbonyl bond of cinnamaldehyde to yield cinnamyl alcohol. The performance of this catalytic system is comparable to that obtained with similar catalysts prepared by more complex methods. Furthermore, expanded graphite provides a good alternative as support to other graphitic materials such as carbon nanotubes and carbon nanofibres.</description><identifier>ISSN: 1011-372X</identifier><identifier>EISSN: 1572-879X</identifier><identifier>DOI: 10.1007/s10562-009-0175-9</identifier><language>eng</language><publisher>Boston: Boston : Springer US</publisher><subject>Aqueous solutions ; Carbon fibers ; Carbon nanotubes ; Carbonyls ; Catalysis ; Catalysts ; Chemistry ; Chemistry and Materials Science ; Cinnamaldehyde ; Colloidal state and disperse state ; Exact sciences and technology ; General and physical chemistry ; Graphite ; Hydrogenation ; Industrial Chemistry/Chemical Engineering ; Liquid phases ; Metal particles ; Nanofibers ; Nanoparticles ; Organometallic Chemistry ; Physical and chemical studies. Granulometry. Electrokinetic phenomena ; Physical Chemistry ; Selectivity ; Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry</subject><ispartof>Catalysis letters, 2009-12, Vol.133 (3-4), p.267-272</ispartof><rights>Springer Science+Business Media, LLC 2009</rights><rights>2015 INIST-CNRS</rights><rights>Catalysis Letters is a copyright of Springer, (2009). All Rights Reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c370t-493c9a1f4d90669f8b8c654cb5f19cd0a068cc2964d52f001325fa274b76e2b53</citedby><cites>FETCH-LOGICAL-c370t-493c9a1f4d90669f8b8c654cb5f19cd0a068cc2964d52f001325fa274b76e2b53</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10562-009-0175-9$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10562-009-0175-9$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=22234699$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Ramos-Fernández, E. V</creatorcontrib><creatorcontrib>Ramos-Fernández, J. M</creatorcontrib><creatorcontrib>Martínez-Escandell, M</creatorcontrib><creatorcontrib>Sepúlveda-Escribano, A</creatorcontrib><creatorcontrib>Rodríguez-Reinoso, F</creatorcontrib><title>Selective Hydrogenation of Cinnamaldehyde over (111) Preferentially Oriented Pt Particles Supported on Expanded Graphite</title><title>Catalysis letters</title><addtitle>Catal Lett</addtitle><description>(111) preferentially oriented Pt nanoparticles supported on expanded graphite were prepared by impregnation of the support with an aqueous solution of H₂PtCl₆. The catalyst was characterized by a number of techniques and tested in the liquid-phase hydrogenation of cinnamaldehyde. The preferential surface orientation of the metal particles favours a very high selectivity towards the hydrogenation of the carbonyl bond of cinnamaldehyde to yield cinnamyl alcohol. The performance of this catalytic system is comparable to that obtained with similar catalysts prepared by more complex methods. Furthermore, expanded graphite provides a good alternative as support to other graphitic materials such as carbon nanotubes and carbon nanofibres.</description><subject>Aqueous solutions</subject><subject>Carbon fibers</subject><subject>Carbon nanotubes</subject><subject>Carbonyls</subject><subject>Catalysis</subject><subject>Catalysts</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Cinnamaldehyde</subject><subject>Colloidal state and disperse state</subject><subject>Exact sciences and technology</subject><subject>General and physical chemistry</subject><subject>Graphite</subject><subject>Hydrogenation</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Liquid phases</subject><subject>Metal particles</subject><subject>Nanofibers</subject><subject>Nanoparticles</subject><subject>Organometallic Chemistry</subject><subject>Physical and chemical studies. Granulometry. Electrokinetic phenomena</subject><subject>Physical Chemistry</subject><subject>Selectivity</subject><subject>Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry</subject><issn>1011-372X</issn><issn>1572-879X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2009</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNp9kF9rHCEUxYfSQtM0HyBPFUqheZj06ow6PpYl_yCQhW0gb-I6141hohOdDdlvX5cJyVuePHjP-ek9VXVM4ZQCyD-ZAhesBlA1UMlr9ak6oFyyupPq7nPRQGndSHb3tfqW8wMUo6TqoHpZ4YB28s9ILnd9ihsMZvIxkOjIwodgHs3Q4_2uRxKfMZHflNITskzoMGGYvBmGHblJvmjsyXIiS5MmbwfMZLUdx5j21wV39jKa0Bd9kcx47yf8Xn1xZsh49HoeVrfnZ_8Wl_X1zcXV4u91bRsJU92qxipDXdsrEEK5bt1ZwVu75o4q24MB0VnLlGh7zhwAbRh3hsl2LQWyNW8Oq58zd0zxaYt50g9xm0J5UjPGO8Wha1lx0dllU8y5bKfH5B9N2mkKel-wngvWpTe9L1irkvn1SjbZmsElE6zPb0HGWNMKtfex2ZfLKGwwvf_gI_iPOeRM1GaTCvh2xcp6ZQ6iUV3zH6GslFc</recordid><startdate>20091201</startdate><enddate>20091201</enddate><creator>Ramos-Fernández, E. V</creator><creator>Ramos-Fernández, J. M</creator><creator>Martínez-Escandell, M</creator><creator>Sepúlveda-Escribano, A</creator><creator>Rodríguez-Reinoso, F</creator><general>Boston : Springer US</general><general>Springer US</general><general>Springer</general><general>Springer Nature B.V</general><scope>FBQ</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope></search><sort><creationdate>20091201</creationdate><title>Selective Hydrogenation of Cinnamaldehyde over (111) Preferentially Oriented Pt Particles Supported on Expanded Graphite</title><author>Ramos-Fernández, E. V ; Ramos-Fernández, J. M ; Martínez-Escandell, M ; Sepúlveda-Escribano, A ; Rodríguez-Reinoso, F</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c370t-493c9a1f4d90669f8b8c654cb5f19cd0a068cc2964d52f001325fa274b76e2b53</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2009</creationdate><topic>Aqueous solutions</topic><topic>Carbon fibers</topic><topic>Carbon nanotubes</topic><topic>Carbonyls</topic><topic>Catalysis</topic><topic>Catalysts</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Cinnamaldehyde</topic><topic>Colloidal state and disperse state</topic><topic>Exact sciences and technology</topic><topic>General and physical chemistry</topic><topic>Graphite</topic><topic>Hydrogenation</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Liquid phases</topic><topic>Metal particles</topic><topic>Nanofibers</topic><topic>Nanoparticles</topic><topic>Organometallic Chemistry</topic><topic>Physical and chemical studies. Granulometry. Electrokinetic phenomena</topic><topic>Physical Chemistry</topic><topic>Selectivity</topic><topic>Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ramos-Fernández, E. V</creatorcontrib><creatorcontrib>Ramos-Fernández, J. M</creatorcontrib><creatorcontrib>Martínez-Escandell, M</creatorcontrib><creatorcontrib>Sepúlveda-Escribano, A</creatorcontrib><creatorcontrib>Rodríguez-Reinoso, F</creatorcontrib><collection>AGRIS</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><jtitle>Catalysis letters</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ramos-Fernández, E. V</au><au>Ramos-Fernández, J. M</au><au>Martínez-Escandell, M</au><au>Sepúlveda-Escribano, A</au><au>Rodríguez-Reinoso, F</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Selective Hydrogenation of Cinnamaldehyde over (111) Preferentially Oriented Pt Particles Supported on Expanded Graphite</atitle><jtitle>Catalysis letters</jtitle><stitle>Catal Lett</stitle><date>2009-12-01</date><risdate>2009</risdate><volume>133</volume><issue>3-4</issue><spage>267</spage><epage>272</epage><pages>267-272</pages><issn>1011-372X</issn><eissn>1572-879X</eissn><abstract>(111) preferentially oriented Pt nanoparticles supported on expanded graphite were prepared by impregnation of the support with an aqueous solution of H₂PtCl₆. The catalyst was characterized by a number of techniques and tested in the liquid-phase hydrogenation of cinnamaldehyde. The preferential surface orientation of the metal particles favours a very high selectivity towards the hydrogenation of the carbonyl bond of cinnamaldehyde to yield cinnamyl alcohol. The performance of this catalytic system is comparable to that obtained with similar catalysts prepared by more complex methods. Furthermore, expanded graphite provides a good alternative as support to other graphitic materials such as carbon nanotubes and carbon nanofibres.</abstract><cop>Boston</cop><pub>Boston : Springer US</pub><doi>10.1007/s10562-009-0175-9</doi><tpages>6</tpages></addata></record> |
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| subjects | Aqueous solutions Carbon fibers Carbon nanotubes Carbonyls Catalysis Catalysts Chemistry Chemistry and Materials Science Cinnamaldehyde Colloidal state and disperse state Exact sciences and technology General and physical chemistry Graphite Hydrogenation Industrial Chemistry/Chemical Engineering Liquid phases Metal particles Nanofibers Nanoparticles Organometallic Chemistry Physical and chemical studies. Granulometry. Electrokinetic phenomena Physical Chemistry Selectivity Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry |
| title | Selective Hydrogenation of Cinnamaldehyde over (111) Preferentially Oriented Pt Particles Supported on Expanded Graphite |
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