Nitric Oxide Reduction Using Hydrogen Over Perovskite Catalysts with Promotional Effect of Platinum on Catalytic Activity

The catalytic activities of strontium substituted La 0.7 Sr 0.3 MnO 3 type perovskite catalysts for NO reduction using H 2 as reducing agent has been studied, which is further improved by incorporation of Pt outside (0.1 wt.%Pt/La 0.7 Sr 0.3 MnO 3 ) and inside (La 0.7 Sr 0.3 Mn 0.97 Pt 0.03 O 3 ) th...

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Veröffentlicht in:Catalysis letters 2008-06, Vol.123 (1-2), p.164-171
Hauptverfasser: Biniwale, Rajesh B., Pande, Jayshri V., Dhakad, Manju, Labhsetwar, Nitin K., Ichikawa, Masaru
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container_end_page 171
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container_title Catalysis letters
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creator Biniwale, Rajesh B.
Pande, Jayshri V.
Dhakad, Manju
Labhsetwar, Nitin K.
Ichikawa, Masaru
description The catalytic activities of strontium substituted La 0.7 Sr 0.3 MnO 3 type perovskite catalysts for NO reduction using H 2 as reducing agent has been studied, which is further improved by incorporation of Pt outside (0.1 wt.%Pt/La 0.7 Sr 0.3 MnO 3 ) and inside (La 0.7 Sr 0.3 Mn 0.97 Pt 0.03 O 3 ) the perovskite lattice structure. Pt shows excellent enhancement in catalytic selectivity towards N 2 when supported on the perovskite. The catalysts were characterized using thermo-gravimetric analysis (TGA), X-ray diffraction (XRD), scanning electron microscopy (SEM) and specific surface area. Catalysts evaluations were carried out using thermo-gravimetric analysis coupled with mass spectra (TG-MS).
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Pt shows excellent enhancement in catalytic selectivity towards N 2 when supported on the perovskite. The catalysts were characterized using thermo-gravimetric analysis (TGA), X-ray diffraction (XRD), scanning electron microscopy (SEM) and specific surface area. 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Pt shows excellent enhancement in catalytic selectivity towards N 2 when supported on the perovskite. The catalysts were characterized using thermo-gravimetric analysis (TGA), X-ray diffraction (XRD), scanning electron microscopy (SEM) and specific surface area. 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subjects Catalysis
Catalysts
Catalytic activity
Chemistry
Chemistry and Materials Science
Exact sciences and technology
General and physical chemistry
Gravimetric analysis
Industrial Chemistry/Chemical Engineering
Mass spectra
Nitric oxide
Organometallic Chemistry
Perovskites
Physical Chemistry
Platinum
Reducing agents
Reduction
Scanning electron microscopy
Selectivity
Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
X-ray diffraction
title Nitric Oxide Reduction Using Hydrogen Over Perovskite Catalysts with Promotional Effect of Platinum on Catalytic Activity
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